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US4292402A
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Light-sensitive silver halide materials containing fluorine-containing surfactants
Assignee: Agfa Gevaert NV
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Filing: 1980-02-08
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Granted: 1981-09-29
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Expires: 2000-02-08
Abstract
Abstract Fluorine-containing surfactants according to formula (Rf--X) n --A--L--Z wherein Rf is a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, X is --O--, --S--, or --SO 2 --, n is at least 2, the Rf groups being same or different, L is a monovalent bond or a bivalent bridging group such as --COO--alkylene, --CONR 1 --alkylene, or --SO 2 NR 1 --alkylene, wherein R 1 is hydrogen or C 1 -C 5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group such as ##STR1## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R 3 is alkyl; A is an aliphatic, aromatic, or aliphatic-aromatic group. These surfactants can be used in hydrophilic colloid layers, which may form part of light-sensitive silver halide materials.
Inventors
- 👤 Robert J. Pollet
- 👤 Hendrik E. Kokelenberg
- 👤 Rafael P. Samijn
- 👤 Francis J. Sels
- 👤 Frans J. Ville
- 👤 Nikolaas C. De Jaeger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 10:50
CPC Classifications
C; C07; C07C; C07C309/00; C07C59/00; C07C59/125; C07C59/135; C07C65/00; C07C65/21; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C11; C11D; C11D1/00; C11D1/004; C11D1/006; G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/38; G03C1/385; Y; Y10; Y10S; Y10S430/00; Y10S430/151; Y10S430/162
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
219 words
Light-sensitive silver halide material comprising a support and one or more hydrophilic colloid layers including at least one light-sensitive silver halide emulsion layer, wherein at least one hydrophilic colloid layer comprises at least one surface-active agent corresponding to the general formula: (Rf--X).sub.n --A--L--Z wherein Rf represents a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, such short-chain group corresponding to one of the formulae Y--HCF--CF 2 --, Y--CF═CF--, and F 2 C═CF--CF 2 -- wherein Y represents chlorine or trifluoromethyl, X represents oxygen, sulphur, or sulphonyl, n represents an integer of at least 2, the Rf groups being same or different, L represents a monovalent bond or a bivalent group selected from --COO--alkylene--, --CONR 1 --alkylene--, and --SO 2 NR 1 --alkylene--, wherein R 1 is hydrogen or C 1 -C 5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group selected from the group consisting of --SO 3 M, --OSO 3 M, --COOM, ##STR22## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R 3 is alkyl, A represents a straight-chain or branched-chain aliphatic hydrocarbon group, an aromatic hydrocarbon group or a mixed aliphatic-aromatic hydrocarbon group which groups may be substituted or not; A being an aromatic hydrocarbon group when L is a monovalent bond and Z is a hydrophilic polyoxyethylene group.
Claim 2
Dependent Claim
219 words
Light-sensitive silver halide material comprising a support and one or more hydrophilic colloid layers including at least one light-sensitive silver halide emulsion layer, wherein at least one hydrophilic colloid layer comprises at least one surface-active agent corresponding to the general formula: (Rf--X).sub.n --A--L--Z wherein Rf represents a short-chain fluorine-containing group derived from hexafluoropropylene or trifluorochloroethylene, such short-chain group corresponding to one of the formulae Y--HCF--CF 2 --, Y--CF═CF--, and F 2 C═CF--CF 2 -- wherein Y represents chlorine or trifluoromethyl, X represents oxygen, sulphur, or sulphonyl, n represents an integer of at least 2, the Rf groups being same or different, L represents a monovalent bond or a bivalent group selected from --COO--alkylene--, --CONR 1 --alkylene--, and --SO 2 NR 1 --alkylene--, wherein R 1 is hydrogen or C 1 -C 5 alkyl, and Z represents a hydrophilic polyoxyethylene group or a hydrophilic group selected from the group consisting of --SO 3 M, --OSO 3 M, --COOM, ##STR22## wherein M is hydrogen, an alkali metal, ammonium, or organic ammonium, and R 3 is alkyl, A represents a straight-chain or branched-chain aliphatic hydrocarbon group, an aromatic hydrocarbon group or a mixed aliphatic-aromatic hydrocarbon group which groups may be substituted or not; A being an aromatic hydrocarbon group when L is a monovalent bond and Z is a hydrophilic polyoxyethylene group.
Claim 3
Dependent Claim
54 words
A light-sensitive silver halide material according to claim 1, wherein said surface-active agent has been prepared by addition reaction between hexafluoropropylene or trifluorochloroethylene and hydroxy- or mercapto-substituted aliphatic or aromatic compounds containing (a) said hydrophilic group(s), or hydroxy- or mercapto-substituted aliphatic or aromatic compounds in which (a) said hydrophilic group(s) is (are) introduced subsequently.
Claim 4
Dependent Claim
159 words
A light-sensitive silver halide material according to claim 1, wherein A is phenylene, n is 2 or 3 and L--Z together are --COR wherein R is (a) OM wherein M is hydrogen, alkali metal, ammonium, organic ammonium, or (CH 2 CH 2 O) p R 4 wherein R 4 is hydrogen or C 1 -C 5 alkyl, which may be substituted by carboxy, sulpho, or sulphato in acid or salt form, and p is a positive integer, or (b) ##STR23## wherein R 5 is hydrogen or C 1 -C 5 alkyl or has the same significance as R 6 , R 6 is C 1 -C 10 alkyl substituted by carboxy or sulpho in acid or salt form, or (CH 2 CH 2 O) z R 7 , wherein R 7 is hydrogen or C 1 -C 5 alkyl, which may be substituted by carboxy, sulpho, or sulphato in acid or salt form, and z is a positive integer.
Claim 5
Dependent Claim
43 words
A light-sensitive silver material according to claim 3, wherein the said surface-active agent has been prepared by addition reaction between hexafluoropropylene or trifluorochloroethylene and a di- or trihydroxy-substituted benzoic acid, by subsequent alkaline hydrolysis, and optionally by further conversion of the carboxy group.
Claim 6
Dependent Claim
23 words
A light-sensitive silver halide material according to claim 1, wherein said surface-active agent is present in a surface coating of the light-sensitive material.
Claim 7
Dependent Claim
17 words
A light-sensitive silver halide material according to claim 5, wherein the surface coating comprises a matting agent.
Claim 8
Dependent Claim
15 words
A light-sensitive silver halide material according to claim 6, wherein the matting agent is polytetrafluoroethylene.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-09-28 | 1985-03-30 | 1985-09-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-09-28 | 1989-03-30 | 1989-09-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-09-28 | 1993-03-30 | 1993-09-29 | $7700.00 | Window Closed / Lapsed |