Patent US3523997A successfully refreshed from Google Patents.
Patent US4291135A successfully refreshed from Google Patents.
US4291135A
Expired / Lapsed
US
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Binders for coating compositions
Assignee: Bayer AG
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Filing: 1980-05-22
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Granted: 1981-09-22
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Expires: 2000-05-22
Abstract
Abstract Reaction products of alkyd resins and/or oil-free polyesters, (meth) acrylic acid copolymers and polysiloxans are excellent binders for high quality lacquers particularly for surface lacquers used in the motor car industry.
Inventors
- 👤 Peter Hohlein
- 👤 Michael Sonntag
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 19:02
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/14; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/181; C08G63/46; C09D167/00; C08L; C08L67/00; C08L83/00; C08L83/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31692; Y10T428/31699
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
317 words
Binders for the preparation of coating compositions, obtainable by reacting components A, B and C at 70°-200° C. with elimination of water or alcohol until at least 20% of the theoretically possible quantity of water or alcohol has been eliminated, wherein component A is 1-97 parts by weight of copolymer resins which contain, per molecule, at least two functional hydroxyl, carboxyl, alkoxy and/or epoxide groups, which resins are prepared by copolymerization of a. 0-50 parts by weight of at least one hydroxyalkyl ester of acrylic or methacrylic acid having 2-4 C-atoms in the hydroxyalkyl group, b. 0-60 parts by weight of at least one compound of the group comprising styrene, α-methylstyrene, o-chlorostyrene, p-chlorostyrene, o-, m- or p-methylstyrene, p-tertiary butyl styrene or methyl methacrylate, c. 10-90 parts by weight of at least one acrylic acid ester having 1-12 C atoms in the alcohol group and/or at least one methacrylic acid ester having 2-12 C-atoms in the alcohol group, d. 0-30 parts by weight of at least one α,β-mono-olefinically unsaturated mono- or dicarboxylic acid having 3-5 C-atoms and/or dicarboxylic acid having 3-5 C-atoms and/or at least one maleic acid semi-ester having 2-14 C-atoms in the alcohol group, or reaction products thereof with a monoglycidyl compound, e. 0-50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester, or reaction products thereof with aliphatic and/or aromatic monocarboxylic acids and amino compounds, f. 0-40 parts by weight of an acrylic or methacrylic acid amide having 1-20 C-atoms in the amino group, or alkoxylated hydroxymethyl acrylic acid amides which may also be produced in situ, and g. 0-60 parts by weight of acrylonitrile, with the sum of the parts by weight of reactants (a) through (g) being 100; component B is 97-1 parts by weight of alkyd resins and/or oil-free polyesters; and component C is 0.5-50 parts by weight of at least one polysiloxane having hydroxyl and/or alkoxy groups.
Claim 2
Dependent Claim
317 words
Binders for the preparation of coating compositions, obtainable by reacting components A, B and C at 70°-200° C. with elimination of water or alcohol until at least 20% of the theoretically possible quantity of water or alcohol has been eliminated, wherein component A is 1-97 parts by weight of copolymer resins which contain, per molecule, at least two functional hydroxyl, carboxyl, alkoxy and/or epoxide groups, which resins are prepared by copolymerization of a. 0-50 parts by weight of at least one hydroxyalkyl ester of acrylic or methacrylic acid having 2-4 C-atoms in the hydroxyalkyl group, b. 0-60 parts by weight of at least one compound of the group comprising styrene, α-methylstyrene, o-chlorostyrene, p-chlorostyrene, o-, m- or p-methylstyrene, p-tertiary butyl styrene or methyl methacrylate, c. 10-90 parts by weight of at least one acrylic acid ester having 1-12 C atoms in the alcohol group and/or at least one methacrylic acid ester having 2-12 C-atoms in the alcohol group, d. 0-30 parts by weight of at least one α,β-mono-olefinically unsaturated mono- or dicarboxylic acid having 3-5 C-atoms and/or dicarboxylic acid having 3-5 C-atoms and/or at least one maleic acid semi-ester having 2-14 C-atoms in the alcohol group, or reaction products thereof with a monoglycidyl compound, e. 0-50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester, or reaction products thereof with aliphatic and/or aromatic monocarboxylic acids and amino compounds, f. 0-40 parts by weight of an acrylic or methacrylic acid amide having 1-20 C-atoms in the amino group, or alkoxylated hydroxymethyl acrylic acid amides which may also be produced in situ, and g. 0-60 parts by weight of acrylonitrile, with the sum of the parts by weight of reactants (a) through (g) being 100; component B is 97-1 parts by weight of alkyd resins and/or oil-free polyesters; and component C is 0.5-50 parts by weight of at least one polysiloxane having hydroxyl and/or alkoxy groups.
Claim 3
Dependent Claim
25 words
The binder according to claim 1 wherein the reaction is continued until 30-70% of the theoretically possible amount of water or alcohol has been eliminated.
Claim 4
Dependent Claim
15 words
The binder according to claim 1 wherein the reaction is at 160°-200° C. without solvent.
Claim 5
Dependent Claim
19 words
The binder according to claim 1 wherein the reaction is at 80°-100° C. in the presence of a solvent.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-09-21 | 1985-03-23 | 1985-09-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-09-21 | 1989-03-23 | 1989-09-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-09-21 | 1993-03-23 | 1993-09-22 | $7700.00 | Window Closed / Lapsed |