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US4291135A Expired / Lapsed US ⏱️ 0.0 years remaining

Binders for coating compositions

Assignee: Bayer AG
•
Filing: 1980-05-22
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Granted: 1981-09-22
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Expires: 2000-05-22
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Abstract

Abstract Reaction products of alkyd resins and/or oil-free polyesters, (meth) acrylic acid copolymers and polysiloxans are excellent binders for high quality lacquers particularly for surface lacquers used in the motor car industry.

Inventors

  • 👤 Peter Hohlein
  • 👤 Michael Sonntag

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:02
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/14; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/181; C08G63/46; C09D167/00; C08L; C08L67/00; C08L83/00; C08L83/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31692; Y10T428/31699

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 317 words
Binders for the preparation of coating compositions, obtainable by reacting components A, B and C at 70°-200° C. with elimination of water or alcohol until at least 20% of the theoretically possible quantity of water or alcohol has been eliminated, wherein component A is 1-97 parts by weight of copolymer resins which contain, per molecule, at least two functional hydroxyl, carboxyl, alkoxy and/or epoxide groups, which resins are prepared by copolymerization of a. 0-50 parts by weight of at least one hydroxyalkyl ester of acrylic or methacrylic acid having 2-4 C-atoms in the hydroxyalkyl group, b. 0-60 parts by weight of at least one compound of the group comprising styrene, α-methylstyrene, o-chlorostyrene, p-chlorostyrene, o-, m- or p-methylstyrene, p-tertiary butyl styrene or methyl methacrylate, c. 10-90 parts by weight of at least one acrylic acid ester having 1-12 C atoms in the alcohol group and/or at least one methacrylic acid ester having 2-12 C-atoms in the alcohol group, d. 0-30 parts by weight of at least one α,β-mono-olefinically unsaturated mono- or dicarboxylic acid having 3-5 C-atoms and/or dicarboxylic acid having 3-5 C-atoms and/or at least one maleic acid semi-ester having 2-14 C-atoms in the alcohol group, or reaction products thereof with a monoglycidyl compound, e. 0-50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester, or reaction products thereof with aliphatic and/or aromatic monocarboxylic acids and amino compounds, f. 0-40 parts by weight of an acrylic or methacrylic acid amide having 1-20 C-atoms in the amino group, or alkoxylated hydroxymethyl acrylic acid amides which may also be produced in situ, and g. 0-60 parts by weight of acrylonitrile, with the sum of the parts by weight of reactants (a) through (g) being 100; component B is 97-1 parts by weight of alkyd resins and/or oil-free polyesters; and component C is 0.5-50 parts by weight of at least one polysiloxane having hydroxyl and/or alkoxy groups.
Claim 2
Dependent Claim 317 words
Binders for the preparation of coating compositions, obtainable by reacting components A, B and C at 70°-200° C. with elimination of water or alcohol until at least 20% of the theoretically possible quantity of water or alcohol has been eliminated, wherein component A is 1-97 parts by weight of copolymer resins which contain, per molecule, at least two functional hydroxyl, carboxyl, alkoxy and/or epoxide groups, which resins are prepared by copolymerization of a. 0-50 parts by weight of at least one hydroxyalkyl ester of acrylic or methacrylic acid having 2-4 C-atoms in the hydroxyalkyl group, b. 0-60 parts by weight of at least one compound of the group comprising styrene, α-methylstyrene, o-chlorostyrene, p-chlorostyrene, o-, m- or p-methylstyrene, p-tertiary butyl styrene or methyl methacrylate, c. 10-90 parts by weight of at least one acrylic acid ester having 1-12 C atoms in the alcohol group and/or at least one methacrylic acid ester having 2-12 C-atoms in the alcohol group, d. 0-30 parts by weight of at least one α,β-mono-olefinically unsaturated mono- or dicarboxylic acid having 3-5 C-atoms and/or dicarboxylic acid having 3-5 C-atoms and/or at least one maleic acid semi-ester having 2-14 C-atoms in the alcohol group, or reaction products thereof with a monoglycidyl compound, e. 0-50 parts by weight of at least one acrylic or methacrylic acid glycidyl ester, or reaction products thereof with aliphatic and/or aromatic monocarboxylic acids and amino compounds, f. 0-40 parts by weight of an acrylic or methacrylic acid amide having 1-20 C-atoms in the amino group, or alkoxylated hydroxymethyl acrylic acid amides which may also be produced in situ, and g. 0-60 parts by weight of acrylonitrile, with the sum of the parts by weight of reactants (a) through (g) being 100; component B is 97-1 parts by weight of alkyd resins and/or oil-free polyesters; and component C is 0.5-50 parts by weight of at least one polysiloxane having hydroxyl and/or alkoxy groups.
Claim 3
Dependent Claim 25 words
The binder according to claim 1 wherein the reaction is continued until 30-70% of the theoretically possible amount of water or alcohol has been eliminated.
Claim 4
Dependent Claim 15 words
The binder according to claim 1 wherein the reaction is at 160°-200° C. without solvent.
Claim 5
Dependent Claim 19 words
The binder according to claim 1 wherein the reaction is at 80°-100° C. in the presence of a solvent.

References Cited (Backward Citations)

US3677810A Cited
US3644566A Cited
US3970709A Cited
US4032494A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-09-21 1985-03-23 1985-09-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-09-21 1989-03-23 1989-09-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-09-21 1993-03-23 1993-09-22 $7700.00 Window Closed / Lapsed

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