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US4287166A
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Zeolite ZSM-39
Assignee: Mobil Oil AS
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Filing: 1980-06-06
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Granted: 1981-09-01
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Expires: 2000-06-06
Abstract
Abstract A new porous zeolite, a method of making same and the use thereof in catalytic conversion of organic compounds. The new product has a composition, expressed in terms of moles of anhydrous oxides per 100 moles of silica as follows: (0-2.5)M2/nO: (0-2.5)Al2O3: (100)SiO2 wherein M is at least one cation having a valence n and wherein the zeolite is characterized by the distinctive X-ray powder diffraction pattern as shown in Table 1 herein. The new zeolite is prepared from a reaction mixture comprising a source of silica, a source of organic compounds of Group VB, alkali metal cations, water and with or without a source of alumina.
Inventors
- 👤 Francis G. Dwyer
- 👤 Edwin E. Jenkins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 17:08
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/70; C; C01; C01B; C01B37/00; C01B37/02; C01B39/00; C01B39/02; C01B39/46; C01B39/48
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
63 words
A porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M 2/n O: (0-2.5)Al 2 O 3 : (100)SiO 2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.
Claim 2
Dependent Claim
63 words
A porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M 2/n O: (0-2.5)Al 2 O 3 : (100)SiO 2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.
Claim 3
Dependent Claim
117 words
A porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R 2 O: (0-2.5)M 2/n O: (0-2.5)Al 2 O 3 : 100 SiO 2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.
Claim 4
Dependent Claim
117 words
A porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R 2 O: (0-2.5)M 2/n O: (0-2.5)Al 2 O 3 : 100 SiO 2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.
Claim 5
Dependent Claim
30 words
A zeolite according to claim 1 wherein M is selected from the group consisting of hydrogen, ammonium, or a metal of Groups II-VIII of the Periodic Chart or mixtures thereof.
Claim 6
Dependent Claim
29 words
A zeolite according to claim 2 wherein the Group VB element of the R 2 O compound is nitrogen or phosphorus and the organic group is an alkyl group.
Claim 7
Dependent Claim
26 words
A zeolite according to claim 2 wherein R 2 O comprises a tetraethylammonium compound and M is selected from the group consisting of sodium and potassium.
Claim 8
Dependent Claim
17 words
The zeolite produced by thermal treatment of the composition of claim 1, 2, 3, 4 or 5.
Claim 9
Dependent Claim
12 words
A zeolite according to claim 1 wherein substantially no alumina is present.
Claim 10
Dependent Claim
40 words
The ion exchanged product of the zeolite of claim 1 or 2 wherein cations originally present in said zeolite are replaced with other ions selected from hydrogen, ammonium, and the metals of Groups I through VIII of the Periodic Chart.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-31 | 1985-03-02 | 1985-09-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-31 | 1989-03-02 | 1989-09-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-31 | 1993-03-02 | 1993-09-01 | $7700.00 | Window Closed / Lapsed |