Patent US4287002A successfully refreshed from Google Patents.
US4287002A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Nuclear reactor decontamination
Assignee: Atomic Energy of Canada Ltd AECL
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Filing: 1979-04-09
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Granted: 1981-09-01
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Expires: 1999-04-09
Abstract
Abstract Heat transfer and associated surfaces in nuclear reactors are decontaminated by treating the surface with ozone to oxidize acid-insoluble metal oxides to a more soluble state, removing oxidized solubilized metal oxides, and removing other surface oxides using low concentrations of decontaminating reagents. Ozone treatment has been found very effective with alloys having surface metal oxides rendered more easily dissolved by ozone oxidation especially with chromium or chromium-nickel containing alloys.
Inventors
- 👤 John Torok
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 14:13
CPC Classifications
G; G21; G21F; G21F9/00; G21F9/001; G21F9/002; G21F9/004
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
136 words
A method of decontaminating and removing corrosion products at least some of which are radioactive, from nuclear reactor surfaces exposed to coolant or moderator, said surfaces containing acid-insoluble metal oxides, including chromium oxide, rendered more soluble by oxidation, comprising: (a) contacting the contaminated surfaces with ozone to an extent sufficient to oxidize insoluble surface metal oxide or oxides, oxides of said metals being thereby rendered more soluble in water or acidic decontaminating solutions; (b) dissolving the solubilized surface metal oxides in an aqueous liquid; (c) dissolving or detaching the remaining surface oxides into aqueous liquid containing oxide-removing acidic decontaminating reagents; (d) removing insoluble particulate material from the resulting aqueous liquids; (e) removing dissolved metals from the resulting aqueous liquids; and (f) removing both residual dissolved metals and reagents from the reactor system to complete the decontamination.
Claim 2
Independent Claim
136 words
A method of decontaminating and removing corrosion products at least some of which are radioactive, from nuclear reactor surfaces exposed to coolant or moderator, said surfaces containing acid-insoluble metal oxides, including chromium oxide, rendered more soluble by oxidation, comprising: (a) contacting the contaminated surfaces with ozone to an extent sufficient to oxidize insoluble surface metal oxide or oxides, oxides of said metals being thereby rendered more soluble in water or acidic decontaminating solutions; (b) dissolving the solubilized surface metal oxides in an aqueous liquid; (c) dissolving or detaching the remaining surface oxides into aqueous liquid containing oxide-removing acidic decontaminating reagents; (d) removing insoluble particulate material from the resulting aqueous liquids; (e) removing dissolved metals from the resulting aqueous liquids; and (f) removing both residual dissolved metals and reagents from the reactor system to complete the decontamination.
Claim 3
Dependent Claim
14 words
The method of claim 1 wherein the insoluble metal oxide is chromium (III) oxide.
Claim 4
Dependent Claim
15 words
The method of claim 1 wherein the contaminated surfaces include iron-, chromium-, and nickel-containing alloy.
Claim 5
Dependent Claim
13 words
The method of claim 1 wherein ozone-saturated water is used in step (a).
Claim 6
Dependent Claim
23 words
The method of claim 1 wherein a two-phase gas-liquid mixture is used to transport ozone into contact with the surfaces in step (a).
Claim 7
Dependent Claim
17 words
The method of claim 1 wherein an ozone-containing gas or gas-water mist is used in step (a).
Claim 8
Dependent Claim
28 words
The method of claim 1 wherein the completion or sufficiency of the ozone treatment in step (a) is monitored by following the chromium removal rate from the surfaces.
Claim 9
Dependent Claim
22 words
The method of claim 1 wherein water is present during step (a) and the aqueous pH is adjusted to give maximum decontamination.
Claim 10
Dependent Claim
14 words
The method of claim 1 wherein the liquid coolant or moderator is heavy water.
Claim 11
Dependent Claim
19 words
The method of claim 9 wherein the heavy water is used as carrier for ozone, and for decontaminating reagents.
Claim 12
Dependent Claim
38 words
The method of claim 1 wherein relatively non-corrosive decontaminating reagents in low concentrations of the order of about 0.1% wt. are used in steps (c) or (b) plus (c) to minimize corrosion and facilitate reagent removal in (f).
Claim 13
Dependent Claim
22 words
The method of claim 1 wherein cation- and anion-exchange resins are contacted in step (f) for dissolved metal and reagent removal thereon.
Claim 14
Dependent Claim
20 words
The method of claim 12 wherein the ion exchange resins are initially in the H + and OH - form.
Claim 15
Dependent Claim
27 words
The method of claim 12 wherein heavy water is the aqueous liquid and the ion exchange resins are initially in the D + and OD - form.
Claim 16
Dependent Claim
22 words
The method of claim 1 including the step of recycling the treated aqueous liquid from step (e) to step (b) or (c).
Claim 17
Dependent Claim
28 words
The method of claim 2 wherein upon ozone oxidation chromic acid dissolves, and this chromic acid is removed by cycling the Cr-containing water through a chromium removal zone.
Claim 18
Dependent Claim
19 words
The method of claim 1 wherein before step (a) an initial decontamination with acidic decontaminating reagents is carried out.
Claim 19
Dependent Claim
15 words
The method of claim 1 wherein oxygen is utilized with the ozone in step (a).
Claim 20
Dependent Claim
20 words
The method of claim 1 wherein the temperature during the oxone contacting in step (a) is below about 35° C.
References Cited (Backward Citations)
US3013909A
Cited
US3664870A
Cited
US3737373A
Cited
US3873362A
Cited
DE2358683A1
Cited
US4042455A
Cited
US4162229A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-31 | 1985-03-02 | 1985-09-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-31 | 1989-03-02 | 1989-09-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-31 | 1993-03-02 | 1993-09-01 | $7700.00 | Window Closed / Lapsed |