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US4286072A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel polyisocyanurate catalysts

Assignee: Huntsman Corp
•
Filing: 1980-07-21
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Granted: 1981-08-25
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Expires: 2000-07-21
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Abstract

Abstract Polyisocyanurate catalysts are disclosed which have the formula: ##STR1## where R 1 and R 2 are independently selected from alkyl groups of less than about 3 carbon atoms or where R 1 and R 2 together comprise cycloalkyl or morpholino groups and where R 3 is hydrogen or alkyl groups containing less than about 3 carbon atoms. Said catalysts are useful in promoting the reaction between a polyol and an aromatic polyisocyanate to prepare a polymer containing recurring isocyanurate and urethane linkages.

Inventors

  • 👤 Edward E. McEntire
  • 👤 Robert L. Zimmerman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 20:10
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/18; C08G18/1825; C08G18/1858; C08G2115/00; C08G2115/02

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 99 words
In a process for preparing a polymer containing recuring isocyanurate and urethane linkages, which polymer comprises the reaction product of a polyol and an aromatic polyisocyanate, while utilizing an isocyanurate group formation catalyst; the improvement which comprises employing as said isocyanurate catalyst a compound falling within the following structural formula: ##STR3## where R 1 and R 2 are independently selected from alkyl groups of less than about 3 carbon atoms or where R 1 and R 2 together comprise cycloalkyl or morpholino groups and where R 3 is hydrogen or alkyl groups containing less than about 3 carbon atoms.
Claim 2
Dependent Claim 99 words
In a process for preparing a polymer containing recuring isocyanurate and urethane linkages, which polymer comprises the reaction product of a polyol and an aromatic polyisocyanate, while utilizing an isocyanurate group formation catalyst; the improvement which comprises employing as said isocyanurate catalyst a compound falling within the following structural formula: ##STR3## where R 1 and R 2 are independently selected from alkyl groups of less than about 3 carbon atoms or where R 1 and R 2 together comprise cycloalkyl or morpholino groups and where R 3 is hydrogen or alkyl groups containing less than about 3 carbon atoms.
Claim 3
Dependent Claim 14 words
The process of claim 1 where said polyol is a polyether or polyester polyol.
Claim 4
Dependent Claim 27 words
The process of claim 1 wherein said polymer is a cellular polymer obtained by reacting said polyols in said polyisocyanate in the presence of a blowing agent.
Claim 5
Dependent Claim 11 words
The process of claim 3 wherein a rigid polyisocyanurate is produced.
Claim 6
Dependent Claim 43 words
In a process for preparing a polymer containing recurring isocyanurate and urethane linkages, which polymer comprises the reaction product of a polyol and an aromatic polyisocyanate, while utilizing an isocyanurate group formation catalyst; the improvement which comprises employing as said isocyanurate catalyst 1-(2,2-dimethylhydrazono)-2-hydroxyethane.
Claim 7
Dependent Claim 43 words
In a process for preparing a polymer containing recurring isocyanurate and urethane linkages, which polymer comprises the reaction product of a polyol and an aromatic polyisocyanate, while utilizing an isocyanurate group formation catalyst; the improvement which comprises employing as said isocyanurate catalyst 1-(2,2-dimethylhydrazono)-2-hydroxyethane.
Claim 8
Dependent Claim 14 words
The process of claim 5 where said polyol is a polyether or polyester polyol.
Claim 9
Dependent Claim 27 words
The process of claim 5 wherein said polymer is a cellular polymer obtained by reacting said polyols in said polyisocyanate in the presence of a blowing agent.
Claim 10
Dependent Claim 12 words
The process of claim 5 wherein a rigid polyisocyanurate foam is produced.

References Cited (Backward Citations)

US3516950A Cited
US3625872A Cited
US3580868A Cited
US3620986A Cited
US3745133A Cited
US3635848A Cited
US3725319A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-24 1985-02-23 1985-08-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-24 1989-02-23 1989-08-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-24 1993-02-23 1993-08-25 $7700.00 Window Closed / Lapsed

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