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US4283326A Expired / Lapsed US ⏱️ 0.0 years remaining

PBT Molding compositions containing mica and a composite polymer

Assignee: Hoechst Celanese Chemical Co
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Filing: 1979-12-26
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Granted: 1981-08-11
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Expires: 1999-12-26
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Abstract

Abstract Poly (C 2 -C 4 alkylene terephthalate) molding composition containing mica and a multiphase composite polymer. The multiphase polymer has a first elastomeric phase polymerized from a monomer system including C 1 -C 6 alkyl acrylate as well as crosslinking and graftlinking monomers and has a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase. Preferred compositions also include thermally stable reinforcing fibers such as glass fibers.

Inventors

  • 👤 John J. Charles
  • 👤 Robert C. Gasman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 11:57
CPC Classifications
C; C08; C08K; C08K7/00; C08K7/02; C08K3/00; C08K3/34; C08L; C08L51/00; C08L67/00; C08L67/02; C08K7/04; C08K7/14; C08L51/04

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 253 words
Polyester molding composition consisting essentially of at least about 40 wt% poly (C 2 -C 4 alkylene terephthalate) with at least about 50 wt% of such poly (C 2 -C 4 alkylene terephthalate) being polybutylene terephthalate having an intrinsic viscosity between about 0.5 and about 2.0 dl/g, such composition containing: (a) between about 1 and about 40 wt% based on total molding composition of phlogophite mica flakes having an average particle size between about 40 and 325 mesh with at least 90% of all mica flakes present in the composition having particle sizes between about 40 and about 200 mesh; and (b) between about 5 and about 30 wt% based on total molding composition of a multiphase composite polymer comprising; (1) about 25 to about 95 wt% of a first elastomeric phase polymerized from a monomer system comprising about 75 to 99.8% by weight C 1 to C 6 alkyl acrylate, 0.1 to 5% by weight crosslinking monomer, and 0.1 to 5% by weight graftlinking monomer, said crosslinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups all of which polymerize at substantially the same rate of reaction, and said graftlinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups, at least one of which polymerizes at a substantially different rate of polymerization from at least one other of said reactive groups; and (2) about 75 to 5 wt% of a final, rigid thermoplastic phase polymerized in the presence of said elastomeric phase.
Claim 2
Dependent Claim 253 words
Polyester molding composition consisting essentially of at least about 40 wt% poly (C 2 -C 4 alkylene terephthalate) with at least about 50 wt% of such poly (C 2 -C 4 alkylene terephthalate) being polybutylene terephthalate having an intrinsic viscosity between about 0.5 and about 2.0 dl/g, such composition containing: (a) between about 1 and about 40 wt% based on total molding composition of phlogophite mica flakes having an average particle size between about 40 and 325 mesh with at least 90% of all mica flakes present in the composition having particle sizes between about 40 and about 200 mesh; and (b) between about 5 and about 30 wt% based on total molding composition of a multiphase composite polymer comprising; (1) about 25 to about 95 wt% of a first elastomeric phase polymerized from a monomer system comprising about 75 to 99.8% by weight C 1 to C 6 alkyl acrylate, 0.1 to 5% by weight crosslinking monomer, and 0.1 to 5% by weight graftlinking monomer, said crosslinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups all of which polymerize at substantially the same rate of reaction, and said graftlinking monomer being a polyethylenically unsaturated monomer having a plurality of addition polymerizable reactive groups, at least one of which polymerizes at a substantially different rate of polymerization from at least one other of said reactive groups; and (2) about 75 to 5 wt% of a final, rigid thermoplastic phase polymerized in the presence of said elastomeric phase.
Claim 3
Dependent Claim 23 words
Molding composition according to claim 1 which contains between about 1% and about 40% wt% based on total molding composition of polyethylene terephthalate.
Claim 4
Dependent Claim 25 words
Molding composition according to claim 2 which also contains between about 0.01 and about 10% wt% based on total molding composition of a nucleating agent.
Claim 5
Dependent Claim 67 words
Molding composition according to claim 1 which also contains between about 3 and about 50 wt% based on total molding composition of thermally stable reinforcing fibers having diameters between about 5 and about 20 microns and aspect ratios of at least about 5 and wherein at least a majority of the mica flakes present in the composition have particle sizes between about 40 and about 100 mesh.
Claim 6
Dependent Claim 13 words
Molding composition according to claim 4 wherein the reinforcing fibers are glass fibers.
Claim 7
Dependent Claim 27 words
Molding composition according to claim 5 wherein the glass fibers have diameters between about 10 and about 15 microns and aspect ratios of at least about 20.
Claim 8
Dependent Claim 18 words
Composition according to claim 1 wherein the final rigid thermoplastic phase of the multiphase polymer contains epoxy groups.
Claim 9
Dependent Claim 17 words
Composition according to claim 7 wherein the epoxy groups are derived from glycidyl acrylate or glycidyl methacrylate.
Claim 10
Dependent Claim 15 words
Composition according to claim 1 wherein said graftlinking monomer is allyl methacrylate or diallyl maleate.
Claim 11
Dependent Claim 12 words
Composition according to claim 1 wherein the crosslinking monomer is butylene diacrylate.
Claim 12
Dependent Claim 37 words
Composition according to claim 1 wherein the final rigid thermoplastic phase of the multiphase polymer is polymerized from a monomer system comprising from about 50 to 100 wt% of a C 1 to C 4 alkyl methacrylate.
Claim 13
Dependent Claim 37 words
Composition according to claim 1 wherein the final phase monomer system is free of acid, hydroxyl, amino and amide groups and wherein the glass transition temperature of the final thermoplastic phase is at least about 20° C.
Claim 14
Dependent Claim 153 words
Composition according to claim 1 which also contains between about 3 and about 50 wt% based on total molding composition of glass reinforcing fibers having diameters between about 5 and about 20 microns and aspect ratios of at least about 5, and wherein at least a majority of the mica flakes present in the composition have particle sizes between about 40 and about 100 mesh and wherein said first phase of the multiphase polymer comprises between about 60 and about 95 wt% of said multiphase polymer, said first phase is polymerized from a monomer system comprising between 95 and about 99.8 percent by weight butyl acrylate, between about 0.1 and about 2.5 wt% butylene diacylate as a crosslinking agent, and between about 0.1 and about 2.5% allyl methacrylate or diallyl maleate as a graftlinking agent and said final phase of said multiphase polymer is polymerized from about 60 to 100 wt% methyl methacrylate.
Claim 15
Dependent Claim 18 words
Composition according to claim 1 wherein the poly (C 2 -C 4 alkylene terephthalate) is essentially polybutylene terephthalate.
Claim 16
Dependent Claim 41 words
Composition according to claim 14 which also includes between about 3 and about 50 wt% based on total molding composition of glass reinforcing fibers having diameters between about 5 and about 20 microns and aspect ratios of at least about 5.
Claim 17
Dependent Claim 11 words
An injection molded article molded from molding composition of claim 1.
Claim 18
Dependent Claim 11 words
An injection molded article molded from molding composition of claim 2.
Claim 19
Dependent Claim 11 words
An injection molded article molded from molding composition of claim 4.
Claim 20
Dependent Claim 11 words
An injection molded article molded from molding composition of claim 5.
Claim 21
Dependent Claim 11 words
An injection molded article molded from molding composition of claim 13.

References Cited (Backward Citations)

US3814725A Cited
US4066607A Cited
US4034013A Cited
US4096202A Cited
US4096202B1 Cited
US4123415A Cited
US4123415B1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-10 1985-02-09 1985-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-10 1989-02-09 1989-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-10 1993-02-09 1993-08-11 $7700.00 Window Closed / Lapsed

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