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US4283302A Expired / Lapsed US ⏱️ 0.0 years remaining

Particulate bleach compositions

Assignee: Lever Brothers Co
•
Filing: 1980-07-07
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Granted: 1981-08-11
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Expires: 2000-07-07
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Abstract

Abstract Particulate bleach (and detergent) compositions with improved bleach efficiency are disclosed comprising a particulate peroxybleach compound and tetraacetyl ethylene diamine (TAED), said TAED having the following particle size distribution as determined by sieve analysis: 0-20%>150 μm 10-100%>100 μm<150 μm 0-50%<75 μm 0-20%<50 μm, and being contained in granules in combination with a granulating agent, said granules having particle size ranging from 100-2000 μm and comprising 10-99% by weight of TAED. The particulate bleach composition does not suffer from significant sedimentation and/or dissolution problems and does not suffer from significant decomposition problems during storage.

Inventors

  • 👤 Roger Foret
  • 👤 Philippus C. van der Hoeven

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:51
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3907; C11D3/3917; C11D17/00; C11D17/0039; C11D3/3935

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 88 words
A particulate bleach composition comprising 3-99.5% by weight of a particulate inorganic peroxybleach compound, and 0.25-50% by weight of tetraacetyl ethylene diamine (TAED), said TAED having the following particle size distribution as determined by sieve analysis: 0-20%<150 μm 10-100%>100 μm<150 μm 0-50%<75 μm 0-20%<50 μm and being contained in granules in combination with a granulating agent selected from the group consisting of an organic and inorganic carrier material said granules having a particle size ranging from 100 to 2000 μm and comprising 10-99% by weight of said TAED.
Claim 2
Dependent Claim 88 words
A particulate bleach composition comprising 3-99.5% by weight of a particulate inorganic peroxybleach compound, and 0.25-50% by weight of tetraacetyl ethylene diamine (TAED), said TAED having the following particle size distribution as determined by sieve analysis: 0-20%<150 μm 10-100%>100 μm<150 μm 0-50%<75 μm 0-20%<50 μm and being contained in granules in combination with a granulating agent selected from the group consisting of an organic and inorganic carrier material said granules having a particle size ranging from 100 to 2000 μm and comprising 10-99% by weight of said TAED.
Claim 3
Dependent Claim 26 words
A particulate bleach composition according to claim 1, wherein said granules contain tetraacetyl ethylene diamine of particle size distribution: 0-10%>150μ 15-82%>100μ<150 μm 0-30%<75 μm 0-10%<50 μm.
Claim 4
Dependent Claim 41 words
A particulate bleach composition according to claim 1, which further contains a stabilising agent selected from the group consisting of ethylene diamine tetra(methylene phosphonic acid), diethylene triamine penta(methylene phosphonic acid) and water-soluble salts thereof, in an amount of 0.05-5% by weight.
Claim 5
Dependent Claim 16 words
A particulate bleach composition according to claim 1, wherein said peroxy bleach compound is sodium perborate.
Claim 6
Dependent Claim 21 words
A particulate bleach composition according to claim 1, wherein said granulating agent is a mixture of sodium triphosphate and potassium triphosphate.
Claim 7
Dependent Claim 180 words
A particulate bleach composition consisting essentially of: (a) 2-20% by weight of a detergent active compound, selected from the group consisting of alkali metal salts of long chain C 8 -C 22 fatty acids, anionic sulphonate or sulphate detergent compounds and nonionic alkylene oxide condensation products and mixtures thereof; (b) 10-60% by weight of a detergency builder material, selected from the group consisting of inorganic phosphates, carbonates, silicates, zeolites and organic non-phosphate builders, and mixtures thereof; (c) 3-30% by weight of an inorganic peroxy bleach compound: (d) 0.25-15% by weight of tetraacetyl ethylene diamine (TAED), said TAED having the following particle size distribution as determined by sieve analysis: 0-20%>150 μm 10-100%>100 μm<150 μm 0-50%<75 μm 0-20%<50 μm and being contained in granules with an organic and/or inorganic carrier material as granulating agent, said granules having a particle size ranging from 100 to 2000 μm and comprising 10-99% by weight of TAED; and (e) 0-5% by weight of a stabilizing agent selected from the group consisting of ethylene diamine tetra-(methylene phosphonic acid), diethylene triamine penta-(methylene phosphonic acid) and water-soluble salts thereof.
Claim 8
Dependent Claim 180 words
A particulate bleach composition consisting essentially of: (a) 2-20% by weight of a detergent active compound, selected from the group consisting of alkali metal salts of long chain C 8 -C 22 fatty acids, anionic sulphonate or sulphate detergent compounds and nonionic alkylene oxide condensation products and mixtures thereof; (b) 10-60% by weight of a detergency builder material, selected from the group consisting of inorganic phosphates, carbonates, silicates, zeolites and organic non-phosphate builders, and mixtures thereof; (c) 3-30% by weight of an inorganic peroxy bleach compound: (d) 0.25-15% by weight of tetraacetyl ethylene diamine (TAED), said TAED having the following particle size distribution as determined by sieve analysis: 0-20%>150 μm 10-100%>100 μm<150 μm 0-50%<75 μm 0-20%<50 μm and being contained in granules with an organic and/or inorganic carrier material as granulating agent, said granules having a particle size ranging from 100 to 2000 μm and comprising 10-99% by weight of TAED; and (e) 0-5% by weight of a stabilizing agent selected from the group consisting of ethylene diamine tetra-(methylene phosphonic acid), diethylene triamine penta-(methylene phosphonic acid) and water-soluble salts thereof.

References Cited (Backward Citations)

US4009113A Cited
US4064062A Cited
US4087369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-08-10 1985-02-09 1985-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-08-10 1989-02-09 1989-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-08-10 1993-02-09 1993-08-11 $7700.00 Window Closed / Lapsed

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