Patent US4281294A successfully refreshed from Google Patents.
US4281294A
Expired / Lapsed
US
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Direct solar pumped laser
Assignee: Individual
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Filing: 1979-04-16
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Granted: 1981-07-28
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Expires: 1999-04-16
Abstract
Abstract A direct solar pumped laser operates on emission from the phosphorescent T1->So transition of a suitable dye molecule used in liquid or solid solution. The first excited singlet electronic state S1 is excited from the ground state So by light from solar concentrators absorbed in the absorption bands of the strong spin-allowed transitions Sp<-So, p>/=1, where the primary absorption band is usually p=1. Excitation of dye molecules to the first triplet state T1 occurs via intersystem crossing from S1 to the triplet state manifold.
Inventors
- 👤 Howard C. Volkin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 23:07
CPC Classifications
H; H01; H01S; H01S3/00; H01S3/02; H01S3/022; H01S3/09; H01S3/091; H01S3/0915; H01S3/14; H01S3/16; H01S3/168; H01S3/20; H01S3/213
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
132 words
A direct solar-pumped laser having a power output and comprising in combination: (a) means for collecting and concentrating solar energy into a laser medium, said medium consisting of an active heavy-atom substituted dye molecule in solution, the said solar laser operation occurring on the phosphorescence transition of the active dye molecule, (b) said active dye molecule having an intersystem crossing rate from its first excited singlet electronic state and a phosphorescence band intensity maximum that are enhanced over that of an unsubstituted dye molecule, and having relatively little triplet-triplet absorption occurring from its first triplet state at wavelengths in the spectral region of the phosphorescence intensity maximum, and (c) a low-powered input laser at a desired frequency whose laser beam provides a driver signal for amplifier operation of the said solar-pumped laser.
Claim 2
Dependent Claim
132 words
A direct solar-pumped laser having a power output and comprising in combination: (a) means for collecting and concentrating solar energy into a laser medium, said medium consisting of an active heavy-atom substituted dye molecule in solution, the said solar laser operation occurring on the phosphorescence transition of the active dye molecule, (b) said active dye molecule having an intersystem crossing rate from its first excited singlet electronic state and a phosphorescence band intensity maximum that are enhanced over that of an unsubstituted dye molecule, and having relatively little triplet-triplet absorption occurring from its first triplet state at wavelengths in the spectral region of the phosphorescence intensity maximum, and (c) a low-powered input laser at a desired frequency whose laser beam provides a driver signal for amplifier operation of the said solar-pumped laser.
Claim 3
Dependent Claim
43 words
The laser medium of claim 1 in which the said medium is a solid solution of at least one active heavy-atom substituted dye molecule selected from the class consisting of rhodamine 6G, DTDC iodide, acridine orange, tetracene, and fluorescein, dissolved in polymethyl methacrylate.
Claim 4
Dependent Claim
22 words
The laser medium of claim 2 in which the solid solution of a dye molecule is rhodamine 6G dissolved in polymethyl methacrylate.
Claim 5
Dependent Claim
44 words
The means for collecting and concentrating the solar energy of claim 1 in which the means consists of one or more planar-solar concentrators containing active dye molecules in a plastic matrix and positioned so that their luminescent emission illuminates and excites the laser medium.
Claim 6
Dependent Claim
39 words
The input laser of claim 1 in which said laser is a CW tunable dye laser operating with at least one dye-laser molecule selected from the class consisting of cresyl violet, xenocyanine, rhodamine 101, IR 140, and rhodamine B.
Claim 7
Dependent Claim
65 words
The laser medium of claim 1 in which the said medium is a liquid solution of at least one heavy atom substituted dye molecule selected from the class consisting of rhodamine 6G dissolved in propyl alcohol plus 20% by volume CHBr 3 , DTDC iodide dissolved in ethylene glycol, acridine orange dissolved in ethyl alcohol/ether, tetracene dissolved in benzene, and fluorescein dissolved in ethyl alcohol/ether.
Claim 8
Dependent Claim
19 words
The laser medium of claim 6 in which the selected solvent for each dye molecule has been heavy-atom substituted.
Claim 9
Dependent Claim
39 words
The laser medium of claim 6 or 7 in which the medium is situated above and below a divider and a reflector means for directing the said power output back through the laser medium situated below the said divider.
Claim 10
Dependent Claim
25 words
The laser medium of claim 6 in which the liquid solution is rhodamine 6G dissolved in propyl alcohol plus 20% by volume CHBr 3 .
Claim 11
Dependent Claim
14 words
The laser medium of claim 9 in which the propyl alcohol is heavy-atom substituted.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-27 | 1985-01-26 | 1985-07-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-27 | 1989-01-26 | 1989-07-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-27 | 1993-01-26 | 1993-07-28 | $7700.00 | Window Closed / Lapsed |