US4280940A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thermoplastic composition comprising vinyl chloride polymer and two chlorinated polyethylenes
Assignee: Vinnolit Monomer GmbH and Co KG
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Filing: 1980-09-12
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Granted: 1981-07-28
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Expires: 2000-09-12
Abstract
Abstract The present invention relates to transparent thermoplastic compositions on the basis of vinyl chloride polymers which can easily be processed and simultaneously have a good viscosity and good resistance to light and weather. They consist of a mixture of a special vinyl chloride polymer and two different, differently chlorinated chloropolyethylenes.
Inventors
- 👤 Helmut Klug
- 👤 Hans-Helmut Frey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:18
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L2205/00; C08L2205/02; C08L23/00; C08L23/26; C08L23/28; C08L23/286
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
307 words
Thermoplastic composition consisting essentially of (A) 95-80% by weight of vinyl chloride polymer and (B) 5-20% by weight of chlorinated polyethylenes, each time calculated on the thermoplastic composition, wherein component (A) is a vinyl chloride polymer with a K value of from 55-65, and component B is a mixture of (B 1 ) 2.5-15 parts by weight of a chlorinated low pressure polyethylene, having a chlorine content of from 37-42% by weight, a residue value of from 0-30% (measured by extraction with toluene/acetone 1:1) and a swelling value of from 10-70% (measured in methyl cyclohexane) and which has been prepared by chlorination of a low pressure polyethylene of a density of from 0.940-0.955 g/cm 3 and a melt flow index MFI 190/5 of from 0.1-5 g/10 min in suspension in water or in 10-35% hydrochloric acid in the presence of 0-2% by weight of silicic acid and 0-1% by weight of silicone oil, relative, each time, to the polyethylene used, at temperatures between 50° and 130° C., with at least 10% of chlorine being introduced at temperatures between 120° and 130° C. and (B 2 ) 2.5-15 parts by weight of a chlorinated low pressure polyethylene with a chlorine content of from 37-42% by weight, a residue value of 50-70% and a swelling value below 1% and which has been prepared from a low pressure polyethylene with a density between 0.955 and 0.965 g/cm 3 and a melt flow index MFI 190/5 of from 20-65 g/10 min by chlorination in suspension in water or in 10-35% hydrochloric acid in the presence of 0-2% by weight of silicic acid and 0-1% by weight of silicone oil, each time calculated on the polyethylene used, at temperatures between 50° and 120° C., while introducing at least the last 10% of chlorine at a temperature of from 110° to 120° C.
Claim 2
Dependent Claim
307 words
Thermoplastic composition consisting essentially of (A) 95-80% by weight of vinyl chloride polymer and (B) 5-20% by weight of chlorinated polyethylenes, each time calculated on the thermoplastic composition, wherein component (A) is a vinyl chloride polymer with a K value of from 55-65, and component B is a mixture of (B 1 ) 2.5-15 parts by weight of a chlorinated low pressure polyethylene, having a chlorine content of from 37-42% by weight, a residue value of from 0-30% (measured by extraction with toluene/acetone 1:1) and a swelling value of from 10-70% (measured in methyl cyclohexane) and which has been prepared by chlorination of a low pressure polyethylene of a density of from 0.940-0.955 g/cm 3 and a melt flow index MFI 190/5 of from 0.1-5 g/10 min in suspension in water or in 10-35% hydrochloric acid in the presence of 0-2% by weight of silicic acid and 0-1% by weight of silicone oil, relative, each time, to the polyethylene used, at temperatures between 50° and 130° C., with at least 10% of chlorine being introduced at temperatures between 120° and 130° C. and (B 2 ) 2.5-15 parts by weight of a chlorinated low pressure polyethylene with a chlorine content of from 37-42% by weight, a residue value of 50-70% and a swelling value below 1% and which has been prepared from a low pressure polyethylene with a density between 0.955 and 0.965 g/cm 3 and a melt flow index MFI 190/5 of from 20-65 g/10 min by chlorination in suspension in water or in 10-35% hydrochloric acid in the presence of 0-2% by weight of silicic acid and 0-1% by weight of silicone oil, each time calculated on the polyethylene used, at temperatures between 50° and 120° C., while introducing at least the last 10% of chlorine at a temperature of from 110° to 120° C.
Claim 3
Dependent Claim
12 words
Thermoplastic composition according to claim 1, which additionally contains other known additives.
Claim 4
Dependent Claim
85 words
Thermoplastic composition according to claim 2, which contains as additives 2-8% by weight relative to the thermoplastic composition of a mixture of stabilizers, consisting of 0.75-2 parts by weight of complex Ba/Cd benzoate, 0-2 parts by weight of complex Ba/Cd-soap of a fatty acid with 12-18 carbon atoms 0.3-1 part by weight of phenylalkyl phosphite with 8 to 12 carbon atoms in the alkyl group, 0.5-3 parts by weight of epoxidized fat 0-1 part by weight of UV-absorber and 0.5-1 part by weight of lubricant.
Claim 5
Dependent Claim
28 words
Thermoplastic composition according to any one of claims 1 to 3, wherein the amount of component (A) is 92-86% by weight and of component (B) 8-14% by weight.
Claim 6
Dependent Claim
30 words
Thermoplastic composition according to any one of claims 1 to 4, wherein the amount of components (B 1 ) and (B 2 ) is from 4-10 parts by weight each.
Claim 7
Dependent Claim
26 words
Thermoplastic composition according to any one of claims 1-5, wherein components (B 1 ) and (B 2 ) are prepared in 10 to 35% hydrochloric acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-27 | 1985-01-26 | 1985-07-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-27 | 1989-01-26 | 1989-07-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-27 | 1993-01-26 | 1993-07-28 | $7700.00 | Window Closed / Lapsed |