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US4277596A Expired / Lapsed US ⏱️ 0.0 years remaining

Calcined polyhydroxysilicate polymer reaction product

Assignee: Societe Nationale de lAmiante
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Filing: 1980-04-08
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Granted: 1981-07-07
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Expires: 2000-04-08
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Abstract

Abstract There is provided a molded shaped structure made by molding the reaction product of an organic resin and a modified magnesium silicate obtained by calcining chrysotile asbestos tailings. The new product is characterized by the absence of any fibers.

Inventors

  • 👤 Jean M. Lalancette

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 12:13
CPC Classifications
C; C04; C04B; C04B28/00; C04B28/003; C08; C08G; C08G59/00; C08G59/14; C08G59/1405; C08G8/00; C08G8/28

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 119 words
A shaped structure formed from the reaction of a non fibrous calcined residue of chrysotile asbestos derived from chrysotile asbestos tailings having a particle size extending from fibrous to -325 mesh and a hydroxy-containing polymer selected from the group consisting of a phenol-formaldehyde polymer, a resorcinol-formaldehyde polymer, a phenol-resorcinol-formaldehyde polymer and an epoxy resin, said shaped structure being characterized by the total absence of any fibrous material, the new product representing a characteristic repeating magnesium oxide-resin bond of the formula: ##STR8## wherein in R is the residue of said hydroxy-containing polymer, the amount of calcined residue of chrysotile asbestos tailings being from 5 to 90% by weight and the amount of polymer being from 90 to 5% by weight.
Claim 2
Dependent Claim 119 words
A shaped structure formed from the reaction of a non fibrous calcined residue of chrysotile asbestos derived from chrysotile asbestos tailings having a particle size extending from fibrous to -325 mesh and a hydroxy-containing polymer selected from the group consisting of a phenol-formaldehyde polymer, a resorcinol-formaldehyde polymer, a phenol-resorcinol-formaldehyde polymer and an epoxy resin, said shaped structure being characterized by the total absence of any fibrous material, the new product representing a characteristic repeating magnesium oxide-resin bond of the formula: ##STR8## wherein in R is the residue of said hydroxy-containing polymer, the amount of calcined residue of chrysotile asbestos tailings being from 5 to 90% by weight and the amount of polymer being from 90 to 5% by weight.
Claim 3
Dependent Claim 13 words
The shaped structure of claim 1, wherein the polymer is a phenol-formaldehyde polymer.
Claim 4
Dependent Claim 13 words
The shaped structure of claim 1, wherein the polymer is an epoxy resin.
Claim 5
Dependent Claim 13 words
The shaped structure of claim 1, wherein the polymer is a resorcinol-formaldehyde polymer.
Claim 6
Dependent Claim 16 words
The shaped structure of claim 1, wherein the polymer is a mixture of phenol-formaldehyde and resorcinol-formaldehyde.
Claim 7
Dependent Claim 94 words
A process which comprises calcining chrysotile asbestos tailings having a particle size of from -28 to -325 mesh at a temperature within the range of from 700° to 900° C., mixing the calcined residue with a hydroxy-containing polymer selected from the group consisting of phenol-formaldehyde polymers, resorcinol-formaldehyde polymers, phenol-resorcinol-formaldehyde polymers and epoxy resins, and shaping said reaction mixture in a mold under pressure at a temperature ranging from 100° to 170° C. when the hydroxy-containing polymer is other than an epoxy resin and at room temperature when the hydroxy-containing resin is an epoxy resin.
Claim 8
Dependent Claim 94 words
A process which comprises calcining chrysotile asbestos tailings having a particle size of from -28 to -325 mesh at a temperature within the range of from 700° to 900° C., mixing the calcined residue with a hydroxy-containing polymer selected from the group consisting of phenol-formaldehyde polymers, resorcinol-formaldehyde polymers, phenol-resorcinol-formaldehyde polymers and epoxy resins, and shaping said reaction mixture in a mold under pressure at a temperature ranging from 100° to 170° C. when the hydroxy-containing polymer is other than an epoxy resin and at room temperature when the hydroxy-containing resin is an epoxy resin.
Claim 9
Dependent Claim 56 words
The process of claim 6, which comprises calcining a chrysotile asbestos tailing having a -200 mesh at a temperature of about 900° C., mixing said calcined material with a phenol-formaldehyde resin, shaping the mixture thus obtained in a mold heated to a temperature of from 135° to 160° C. under a pressure of about 800 psi.
Claim 10
Dependent Claim 51 words
The process of claim 6, which comprises calcining a chrysotile asbestos tailing having a -200 mesh at a temperature of about 900° C., mixing said calcined material with an epoxy resin, shaping the mixture thus obtained in a mold at room temperature under a pressure of from 50 to 100 psi.
Claim 11
Dependent Claim 146 words
A process for preparing a shaped structure which comprises calcining chrysotile asbestos tailings having a particle size of from -28 to -325 mesh thereby to obtain a basic anhydrous oxide of the formula: ##STR9## mixing said basic anhydrous oxide with an acidic hydroxy-containing polymer selected from phenol-formaldehyde polymers, resorcinol-formaldehyde polymers, phenol-resorcinol-formaldehyde polymers and epoxy resins, reacting said mixture in a mold at a temperature of from 100° to 170° C. and under a pressure of from 700 to 900 psi when the hydroxy-containing polymer is other than an epoxy resin and at room temperature and a pressure of from 50 to 100 psi when the hydroxy-containing polymer is an epoxy resin whereby there is obtained a shaped structure devoid of any fibrous material and characterized by a repeating unit of magnesium oxide-resin bond of the formula: ##STR10## wherein R is the residue of the hydroxy-containing polymer.
Claim 12
Dependent Claim 146 words
A process for preparing a shaped structure which comprises calcining chrysotile asbestos tailings having a particle size of from -28 to -325 mesh thereby to obtain a basic anhydrous oxide of the formula: ##STR9## mixing said basic anhydrous oxide with an acidic hydroxy-containing polymer selected from phenol-formaldehyde polymers, resorcinol-formaldehyde polymers, phenol-resorcinol-formaldehyde polymers and epoxy resins, reacting said mixture in a mold at a temperature of from 100° to 170° C. and under a pressure of from 700 to 900 psi when the hydroxy-containing polymer is other than an epoxy resin and at room temperature and a pressure of from 50 to 100 psi when the hydroxy-containing polymer is an epoxy resin whereby there is obtained a shaped structure devoid of any fibrous material and characterized by a repeating unit of magnesium oxide-resin bond of the formula: ##STR10## wherein R is the residue of the hydroxy-containing polymer.

References Cited (Backward Citations)

US2999833A Cited
US3061577A Cited
US3215494A Cited
US3470128A Cited
US3478300A Cited
US3755067A Cited
US4192707A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-06 1985-01-05 1985-07-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-06 1989-01-05 1989-07-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-06 1993-01-05 1993-07-07 $7700.00 Window Closed / Lapsed

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