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Vinyl chloride resin and alkyl methacrylate resin processing aid composition

Assignee: Kureha Corp
•
Filing: 1979-10-17
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Granted: 1981-07-07
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Expires: 1999-10-17
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Abstract

Abstract A vinyl chloride resin composition comprises: (1) 100 parts of vinyl chloride polymer; and (2) 0.1 to 30 parts of a polymer processing aid comprising: (A) 40 to 90 parts of a copolymer comprising 80 to 100% of an alkyl methacrylate, and 0 to 20% of a monomer copolymerizable therewith; and (B) 60 to 10 parts of a copolymer comprising 20 to 79% of an alkyl methacrylate, 20 to 79% of an aromatic vinyl monomer, 1 to 49% of diolefin, and 0 to 20% of a monomer copolymerizable therewith, the copolymers (A) and (B) having been wet-blended to provide 100 parts of the polymer processing aid, all quantities expressed in parts and percentages being by weight. This vinyl chloride resin composition comprising a novel polymer processing aid not only shows an increased gelation rate, yields less ungelled particles and possesses excellent processability such as an increased elongation at a high temperature, but particularly possesses excellent mechanical properties because the impact strength of the composition is not appreciably lowered by the addition of the polymer processing aid.

Inventors

  • 👤 Yo Iizuka
  • 👤 Susumu Midorikawa, deceased
  • 👤 heir Kiyoshi Midorikawa
  • 👤 heir Yumi Midorikawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 07:04
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/14; C08L33/00; C08L33/04; C08L33/06; C08L33/10

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 136 words
A vinyl chloride resin composition comprising: (1) 100 parts of a vinyl chloride polymer; and (2) 0.1 to 30 parts of a polymer processing aid comprising: (A) 40 to 90 parts of a copolymer comprising 80 to 100% of an alkyl methacrylate, and 0 to 20% of a monomer copolymerizable therewith; and (B) 60 to 10 parts of a copolymer comprising 20 to 79% of an alkyl methacrylate, 20to 79% of an aromatic vinyl monomer, 1 to 49% of a diolefin, and 0 to 20% of a monomer copolymerizable therewith, 100 parts of said polymer processing aid having been obtained by polymerizing 60 to 10 parts of the constituent monomers of the copolymer (B) in the presence of 40 to 90 parts of the copolymer (A), all quantities expressed in parts and percentages being by weight.
Claim 2
Dependent Claim 136 words
A vinyl chloride resin composition comprising: (1) 100 parts of a vinyl chloride polymer; and (2) 0.1 to 30 parts of a polymer processing aid comprising: (A) 40 to 90 parts of a copolymer comprising 80 to 100% of an alkyl methacrylate, and 0 to 20% of a monomer copolymerizable therewith; and (B) 60 to 10 parts of a copolymer comprising 20 to 79% of an alkyl methacrylate, 20to 79% of an aromatic vinyl monomer, 1 to 49% of a diolefin, and 0 to 20% of a monomer copolymerizable therewith, 100 parts of said polymer processing aid having been obtained by polymerizing 60 to 10 parts of the constituent monomers of the copolymer (B) in the presence of 40 to 90 parts of the copolymer (A), all quantities expressed in parts and percentages being by weight.
Claim 3
Dependent Claim 37 words
A vinyl chloride resin composition as claimed in claim 1, wherein the copolymer (B) comprises 30 to 69% of an alkyl methacrylate, 30 to 69% of an aromatic vinyl monomer, and 1 to 30% of a diolefin.
Claim 4
Dependent Claim 59 words
A vinyl chloride resin composition as claimed in claim 1, wherein the composition further comprises 1 to 30 parts by weight of an impact strength modifier selected from the group consisting of acrylonitrile/butadiene/styrene copolymers, and methyl methacrylate/butadiene/styrene copolymers which are different from the copolymer (B) present in the composition, per 100 parts by weight of the vinyl chloride polymer.
Claim 5
Dependent Claim 26 words
A vinyl chloride resin composition as claimed in claim 1 or 2, wherein the alkyl methacrylate has an alkyl group of 1 to 8 carbon atoms.
Claim 6
Dependent Claim 17 words
A vinyl chloride resin composition as claimed in claim 4, wherein the alkyl methacrylate is methyl methacrylate.
Claim 7
Dependent Claim 24 words
A vinyl chloride resin composition as claimed in claim 1, wherein the diolefin is selected from the group consisting of butadiene, isoprene, and chloroprene.
Claim 8
Dependent Claim 15 words
A vinyl chloride resin composition as claimed in claim 6, wherein the diolefin is butadiene.
Claim 9
Dependent Claim 27 words
A vinyl chloride resin composition as claimed in claim 1, wherein the aromatic vinyl monomer is selected from the group consisting of styrene, α-methyl styrene, and chlorostyrene.
Claim 10
Dependent Claim 17 words
A vinyl chloride resin composition as claimed in claim 8, wherein the aromatic vinyl monomer is styrene.
Claim 11
Dependent Claim 56 words
A vinyl chloride resin composition as claimed in claim 1, wherein the constituent monomers of the copolymer (A) or (B) are selected from the group consisting of methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate, acrylonitrile, methacrylonitrile, methyl vinyl ether, ethyl vinyl ether, methyl vinyl ketone, ethyl vinyl ketone, vinyl acetate, divinylbenzene, and ethylene glycol dimethacrylate.

References Cited (Backward Citations)

GB850947A Cited
US3689598A Cited
US3660529A Cited
US3971835A Cited
US4052482A Cited
US3969469A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-06 1985-01-05 1985-07-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-06 1989-01-05 1989-07-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-06 1993-01-05 1993-07-07 $7700.00 Window Closed / Lapsed

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