Patent US4277426A successfully refreshed from Google Patents.
US4277426A
Expired / Lapsed
US
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Method for production of coagulated synthetic polymer latex
Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1979-11-27
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Granted: 1981-07-07
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Expires: 1999-11-27
Abstract
Abstract A method for coagulating a latex of a synthetic polymer having a coagulated latex particle formation temperature to form substantially spherical particles, the method comprising: forming substantially spherical latex particles by dispersing substantially spherical drops of the latex into a vessel or chamber containing a coagulating atmosphere which can be (i) a gaseous coagulant or (ii) a liquid coagulant in the form of a mist of drops having diameters such that the terminal settling velocity of the drops under free-falling conditions is in accordance with Stokes' Law, while maintaining the coagulant at the coagulated latex particle formation temperature and while causing water at the coagulated latex particle formation temperature to flow downward over the inner surface of the coagulation vessel to cause pluralities of polymer particles in a drop of the latex to coagulate to form substantially spherical coagulated latex particles. Contact is maintained between the spherical drops of latex and the coagulating atmosphere for a time effective to permit said drops to absorb about 0.36 to 8% by weight of coagulant based on the weight of the polymer, to stabilize said drops. The substantially spherical particles are separated and recovered.
Inventors
- 👤 Shingi Kato
- 👤 Nobuo Ogawa
- 👤 Norio Kawanami
- 👤 Takashi Onda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 07:17
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/12; C08J3/16; B; B01; B01J; B01J2/00; B01J2/02; B01J2/04; C08C; C08C1/00; C08C1/14
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
251 words
A method for coagulating a latex of a synthetic polymer at a coagulated latex particle formation temperature at which pluralities of polymer particles coagulate in droplets of the latex to form coagulated latex particles, without causing agglomeration of the coagulated latex particles to form substantially spherical particles, the method which comprises coagulating said latex by dispersing substantially spherical droplets of it, the droplets having a size distribution such that not more than 20% have a diameter smaller than 53 microns and the remainder have a diameter of 2 mm or less, into a coagulating atmosphere selected from the group consisting of: (i) a gaseous coagulant; and (ii) a liquid coagulant in the form of a mist comprising liquid drops having diameters such that the terminal settling velocity of the drops under free-falling conditions is in accordance with Stokes' Law, said coagulation atmosphere being maintained at the coagulated latex particle formation temperature and being contained in a vertically disposed coagulation chamber having side walls with inner surfaces, while causing water to flow downward over the inner surfaces as a liquid recovery medium, the water being maintained at the coagulated latex particle formation temperature to recover the coagulated latex particles having a substantially spherical shape, contact being maintained between the droplets of latex and the coagulating atmosphere for a period between 0.6 to 3 seconds effective to permit said droplets to absorb about 0.36 to 8% by weight of coagulant based on the weight of the polymer to stabilize said coagulated latex particles.
Claim 2
Independent Claim
251 words
A method for coagulating a latex of a synthetic polymer at a coagulated latex particle formation temperature at which pluralities of polymer particles coagulate in droplets of the latex to form coagulated latex particles, without causing agglomeration of the coagulated latex particles to form substantially spherical particles, the method which comprises coagulating said latex by dispersing substantially spherical droplets of it, the droplets having a size distribution such that not more than 20% have a diameter smaller than 53 microns and the remainder have a diameter of 2 mm or less, into a coagulating atmosphere selected from the group consisting of: (i) a gaseous coagulant; and (ii) a liquid coagulant in the form of a mist comprising liquid drops having diameters such that the terminal settling velocity of the drops under free-falling conditions is in accordance with Stokes' Law, said coagulation atmosphere being maintained at the coagulated latex particle formation temperature and being contained in a vertically disposed coagulation chamber having side walls with inner surfaces, while causing water to flow downward over the inner surfaces as a liquid recovery medium, the water being maintained at the coagulated latex particle formation temperature to recover the coagulated latex particles having a substantially spherical shape, contact being maintained between the droplets of latex and the coagulating atmosphere for a period between 0.6 to 3 seconds effective to permit said droplets to absorb about 0.36 to 8% by weight of coagulant based on the weight of the polymer to stabilize said coagulated latex particles.
Claim 3
Dependent Claim
36 words
The method of claim 1 in which said latex is dispersed into the coagulating atmosphere by a nozzle at a rate of 5.7 to 20 liters/min M 2 of horizontal cross-section area of the coagulation chamber.
Claim 4
Dependent Claim
37 words
The method of claim 1 in which said latex is dispersed into the coagulating atmosphere by a centrifugal disc a a rate of 0.5 to 2.0 liters/min M 2 of horizontal cross-section area of the coagulation chamber.
Claim 5
Dependent Claim
113 words
The method of claim 1 in which said polymer latex is the product of the polymerization of 20 to 80 parts by weight of monomers consisting essentially of 0 to 50 weight percent acrylic ester, 0 to 100 weight percent methacrylic ester, 0 to 90 weight percent aromatic vinyl compound and 0 to 90 weight cyano vinyl compound in the presence of 20 to 80 parts by weight of an elastomer latex consisting essentially of 0 to 50 weight percent styrene and 50 to 100 weight percent butadiene, in which said coagulated latex particle formation temperature is between the Vicat softening temperature of said polymer and 30° C. below the Vicat softening temperature.
Claim 6
Dependent Claim
166 words
The method of claim 1 in which said polymer latex is the product resulting from the mixing of 0 to 50 parts by weight of a graft copolymer (A) which is the product of the polymerization of 10 to 90 parts by weight of one or more monomers selected from aromatic vinyl compound, methacrylic ester, acrylic ester or cyano vinyl compound in the presence of 10 to 90 parts by weight of butadiene elastomer latex consisting of 0 to 50 weight percent of styrene and 50 to 100 weight percent of butadiene and 50 to 100 parts by weight of a polymer (B) which is the product of the copolymerization of monomers containing 0 to 70 mol percent of α-methylstyrene and 30 to 100 mol percent of one or more monomers selected from aromatic vinyl compound, methacrylic ester, acrylic ester, acrylic acid or cyano vinyl compound, in which said coagulated latex particle formation temperature is between 70° C. and the Vicat softening temperature of said polymer.
Claim 7
Dependent Claim
29 words
The method of claim 1 in which said coagulant is supplied in an amount of from 0.4 to 10 weight percent based on the weight of polymeric latex dispersed.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-07-06 | 1985-01-05 | 1985-07-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-07-06 | 1989-01-05 | 1989-07-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-07-06 | 1993-01-05 | 1993-07-07 | $7700.00 | Window Closed / Lapsed |