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US4277286A Expired / Lapsed US ⏱️ 0.0 years remaining

Lead-free glasses of high x-ray absorption for cathode ray tubes

Assignee: Corning Glass Works
•
Filing: 1980-02-19
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Granted: 1981-07-07
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Expires: 2000-02-19
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Abstract

Abstract This invention is directed to glasses especially suitable for use as television picture tube faceplates which exhibit linear X-ray absorption coefficients at 0.6 A of at least 35 cm -1 and very little browning from X-radiation and electron impingement thereon. The glasses are essentially free from PbO and other readily-reducible metal oxides and consist essentially, in weight percent on the oxide basis, as calculated from the batch, of: ______________________________________ SiO 2 43-55 Al 2 O 3 0-4 ZnO 5-12 Li 2 O 0.5-3 Na 2 O 4-8 K 2 O 3-8 Li 2 O + Na 2 O + K 2 O 10-18 CaO 0-5 SrO 2-14 BaO 10-20 CaO + SrO + BaO 16-30 CeO 2 0.3-1 ZrO 2 2-8 ______________________________________

Inventors

  • 👤 David C. Boyd
  • 👤 David A. Thompson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 08:11
CPC Classifications
C; C03; C03C; C03C4/00; C03C4/08; C03C4/087; C03C3/00; C03C3/04; C03C3/076; C03C3/078; C03C3/083; C03C3/085; C03C3/087

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 176 words
A glass for the faceplate of a television picture tube essentially free from PbO and other readily-reducible metal oxides exhibiting an electrical resistivity, when measured at 350° C., of at least 10 7 ohm-cm, a coefficient of thermal expansion (0°-300° C.) not in excess of 102×10 -7 /°C., an internal liquidus under 900° C., a strain point not over 500° C., a softening point not over 690° C., a linear X-ray absorption coefficient at 0.6 A of at least 35 cm -1 such that X-ray transmittance therethrough will be less than 0.5 mr/hr when measured at a distance of 5 cm from a faceplate of conventional thickness, and strong resistance of discoloration from X-ray and electron bombardment consisting essentially, expressed in weight percent on the oxide basis as calculated from the batch, of: ______________________________________ SiO.sub.2 43-55 Al.sub.2 O.sub.3 0-4 ZnO 5-12 Li.sub.2 O 0.5-3 Na.sub.2 O 4-8 K.sub.2 O 3-8 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 10-18 CaO 0-5 SrO 2-14 BaO 10-20 CaO + SrO + BaO 16-30 CeO.sub.2 0.3-1 ZrO.sub.2 2-8 ______________________________________
Claim 2
Dependent Claim 176 words
A glass for the faceplate of a television picture tube essentially free from PbO and other readily-reducible metal oxides exhibiting an electrical resistivity, when measured at 350° C., of at least 10 7 ohm-cm, a coefficient of thermal expansion (0°-300° C.) not in excess of 102×10 -7 /°C., an internal liquidus under 900° C., a strain point not over 500° C., a softening point not over 690° C., a linear X-ray absorption coefficient at 0.6 A of at least 35 cm -1 such that X-ray transmittance therethrough will be less than 0.5 mr/hr when measured at a distance of 5 cm from a faceplate of conventional thickness, and strong resistance of discoloration from X-ray and electron bombardment consisting essentially, expressed in weight percent on the oxide basis as calculated from the batch, of: ______________________________________ SiO.sub.2 43-55 Al.sub.2 O.sub.3 0-4 ZnO 5-12 Li.sub.2 O 0.5-3 Na.sub.2 O 4-8 K.sub.2 O 3-8 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 10-18 CaO 0-5 SrO 2-14 BaO 10-20 CaO + SrO + BaO 16-30 CeO.sub.2 0.3-1 ZrO.sub.2 2-8 ______________________________________
Claim 3
Dependent Claim 12 words
A glass according to claim 1 also containing 0.5-2% TiO 2 .
Claim 4
Dependent Claim 67 words
A glass according to claim 2 consisting essentially, expressed in weight percent on the oxide basis as calculated from the batch, of: ______________________________________ SiO.sub.2 48-53 Al.sub.2 O.sub.3 1-2 ZnO 7-11 Li.sub.2 O 1-3 Na.sub.2 O 5-7 K.sub.2 O 5-6 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 11-16 CaO 0-3 SrO 3-7 BaO 14-16 CaO + SrO + BaO 18-24 ZrO.sub.2 2-7 CeO.sub.2 0.4-0.8 TiO.sub.2 0.5-1.0 ______________________________________

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-07-06 1985-01-05 1985-07-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-07-06 1989-01-05 1989-07-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-07-06 1993-01-05 1993-07-07 $7700.00 Window Closed / Lapsed

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