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US4275047A
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Zeolite synthesis
Assignee: Imperial Chemical Industries Ltd
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Filing: 1977-07-21
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Granted: 1981-06-23
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Expires: 1997-07-21
Abstract
Abstract Whereas previously zeolites of the ZSM-5 family have been synthesized in reaction mixtures in which the presence of alkylammonium ions was considered to be essential, the use of such ions can be avoided if the mixture contains a seed zeolite having a port diameter in the range 5.8 to 7.0. The seed zeolite need not be a member of the ZSM-5 family but can be, for example zeolite nu-1 which has a distinctly different structure. The reaction mixture preferably is limited in alkalinity and preferably contains strong acid anions.
Inventors
- 👤 Thomas V. Whittam
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 04:05
CPC Classifications
C; C01; C01B; C01B39/00; C01B39/02; C01B39/36; C01B39/38; C01B39/365; C01B39/42; Y; Y10; Y10S; Y10S423/00; Y10S423/22; Y10S423/29
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
147 words
In a method of making a zeolite of the ZSM-5 family consisting of ZSM-5, ZSM-8, ZSM-11, ZSM-12, zeta-1 and zeta-3, said family further characterized as having a SiO 2 /Al 2 O 3 ratio in the range 5 to 100, a port diameter in the range 6.0 to 6.5 Angstrom units corresponding to rings of 10SiO 4 and AlO 4 and a characteristic X-ray diffraction pattern, by reacting an alkaline mixture comprising an alumina source, a silica source and alkali metal ions until the required zeolite has been formed, the improvement which comprises reacting said mixture in the presence of a seed quantity of a crystallized zeolite having a port diameter in the range 5.8 to 7.0 Angstrom units wherein the concentration of onium compound be such that the ratio of onium ions to (onium+alkali metal) ions is under 0.05 said crystallized zeolite being nu-1 or FU-1.
Claim 2
Dependent Claim
147 words
In a method of making a zeolite of the ZSM-5 family consisting of ZSM-5, ZSM-8, ZSM-11, ZSM-12, zeta-1 and zeta-3, said family further characterized as having a SiO 2 /Al 2 O 3 ratio in the range 5 to 100, a port diameter in the range 6.0 to 6.5 Angstrom units corresponding to rings of 10SiO 4 and AlO 4 and a characteristic X-ray diffraction pattern, by reacting an alkaline mixture comprising an alumina source, a silica source and alkali metal ions until the required zeolite has been formed, the improvement which comprises reacting said mixture in the presence of a seed quantity of a crystallized zeolite having a port diameter in the range 5.8 to 7.0 Angstrom units wherein the concentration of onium compound be such that the ratio of onium ions to (onium+alkali metal) ions is under 0.05 said crystallized zeolite being nu-1 or FU-1.
Claim 3
Dependent Claim
38 words
A method according to claim 1 in which the mixture has the molar composition SiO 2 /Al 2 O 3 : 30 to 120 OH/SiO 2 : 0.1 to 0.4 H 2 O/OH - : 10 to 300
Claim 4
Dependent Claim
25 words
A method according to claim 1 in which the mixture contains 0.1 to 2.0 g of seed zeolite per 100 g of SiO 2 .
Claim 5
Dependent Claim
30 words
A method according to claim 1 in which the mixture contains one or more anions of strong acids in a proportion of up to 10 equivalents per mole of silica.
Claim 6
Dependent Claim
17 words
A method according to claim 4 in which the proportion is in the range 0.3 to 3.0.
Claim 7
Dependent Claim
21 words
A method according to claim 4 wherein said ions are selected from the group consisting of chloride, bromide, iodide and sulphate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-06-22 | 1984-12-22 | 1985-06-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-06-22 | 1988-12-22 | 1989-06-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-06-22 | 1992-12-22 | 1993-06-23 | $7700.00 | Window Closed / Lapsed |