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US4273676A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing methacrylic acid and a catalyst

Assignee: Nippon Kayaku Co Ltd
•
Filing: 1978-10-05
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Granted: 1981-06-16
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Expires: 1998-10-05
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Abstract

Abstract A catalyst having a heteropoly-acid structure and the general formula: Mo.sub.a V.sub.b P.sub.c Cu.sub.d X.sub.e O.sub.f wherein Mo, V, P, Cu and O represent respectively molybdenum, vanadium, phosphorus, copper and oxygen, X represents one or more elements selected from the group consisting of tin, thorium, germanium, nickel, iron, cobalt, magnesium, zinc, titanium, lead, rhenium, zirconium and chromium and a, b, c, d, e and f represent the atomic ratio of the elements where, a is 10 b is a number of 3 or less than 3 excluding 0, c is a number of 0.5 to 3, d is a number of 3 or less than 3 excluding 0, e is a number of 3 or less than 3 excluding 0, f is a number determined depending on the valency and atomic ratio of other elements. There is also provided a process for producing methacrylic acid by oxidizing methacrolein with molecular oxygen or molecular oxygen-containing gas in the presence of the catalyst defined above.

Inventors

  • 👤 Mutsumi Matsumoto
  • 👤 Hideki Sugi
  • 👤 Atsushi Sudo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:05
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J23/887; B01J23/8875; B01J23/002; B01J23/8877; B01J27/00; B01J27/14; B01J27/186; B01J27/195; B01J27/198; B01J27/199; C; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/25; C07C51/252; B01J2523/00

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 135 words
A catalyst having a heteropoly-acid structure and the general formula: Mo.sub.a V.sub.b P.sub.c Cu.sub.d X.sub.e O.sub.f wherein Mo, V, P, Cu and O represent respectively molybdenum, vanadium, phosphorus, copper and oxygen, X represents one or more elements selected from the group consisting of tin, thorium, germanium, nickel, iron, cobalt, magnesium, zinc, titanium, lead, rhenium, zirconium and chromium and a, b, c, d, e and f represent the atomic ratio of the elements where, a is 10 b is a number of 3 or less than 3 excluding 0, c is a number of 0.5 to 3, d is a number of 3 or less than 3 excluding 0, e is a number of 3 or less than 3 excluding 0, f is a number determined depending on the valency and atomic ratio of other elements.
Claim 2
Dependent Claim 135 words
A catalyst having a heteropoly-acid structure and the general formula: Mo.sub.a V.sub.b P.sub.c Cu.sub.d X.sub.e O.sub.f wherein Mo, V, P, Cu and O represent respectively molybdenum, vanadium, phosphorus, copper and oxygen, X represents one or more elements selected from the group consisting of tin, thorium, germanium, nickel, iron, cobalt, magnesium, zinc, titanium, lead, rhenium, zirconium and chromium and a, b, c, d, e and f represent the atomic ratio of the elements where, a is 10 b is a number of 3 or less than 3 excluding 0, c is a number of 0.5 to 3, d is a number of 3 or less than 3 excluding 0, e is a number of 3 or less than 3 excluding 0, f is a number determined depending on the valency and atomic ratio of other elements.
Claim 3
Dependent Claim 41 words
The catalyst of claim 1, where a is 10, b is a number of 0.5 to 2, c is a number of 0.5 to 2, d is a number of 0.01 to 1, e is a number of 0.01 to 0.5.
Claim 4
Dependent Claim 27 words
The catalyst of claim 1, wherein X represents one or more elements selected from the group consisting of tin, thorium, germanium, nickel, iron, cobalt, titanium and zirconium.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-15 1984-12-15 1985-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-15 1988-12-15 1989-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-15 1992-12-15 1993-06-16 $7700.00 Window Closed / Lapsed

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