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US4000088A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxidation catalyst for the manufacture of methacrylic acid

Assignee: Nippon Kayaku Co Ltd
•
Filing: 1974-06-03
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Granted: 1976-12-28
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Expires: 1994-06-03
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Abstract

Abstract This invention relates to a catalyst for the oxidation of methacrolein to produce methacrylic acid. The catalyst has the following composition: Mo a P b Sb c Cu d Cr e O f (NH 4 ) g where a is fixed at 12, b assumes a value of 1 to 4, c a value of 0.1 to 7, d a value of 0.1 to 5, e a value of 0 to 6, g a value of 0 to 3.5 and f a value, usually 35 to 80, which is automatically determined by the valence of the other atoms.

Inventors

  • 👤 Hitoshi Shimizu
  • 👤 Kazuo Ishimi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 04:40
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J23/887; B01J23/8875; B01J23/8876; B01J23/8878; B01J27/00; B01J27/14; B01J27/186; B01J27/188; B01J27/19; C; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/25; C07C51/252; B01J2523/00

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 152 words
A catalyst for oxidizing unsaturated aldehydes to the corresponding unsaturated carboxylic acids having the following composition: Mo.sub.a P.sub.b Sb.sub.c Cu.sub.d Cr.sub.e O.sub.f (NH.sub.4).sub.g (wherein, the subscripts a, b, c, d, e, and f denote the numbers respectively of molybdenum, phosphorus, antimony, copper, chromium and oxygen atoms and the subscript g denotes the number of ammonium groups and, where a is fixed at 12, b assumes a value of 1 to 4, c a value of 0.1 to 7, d a value of 0.1 to 5, e a value of 0 to 6 and g a value of 0 to 3.5 respectively and f a value, from 35 to 80, which is automatically determined by the valence of the other atoms), said catalyst being prepared by mixing starting materials containing the component elements, where necessary, in conjunction with aqueous ammonia water, drying the resulting mixture and calcining the dried mass between 300°-500° C.
Claim 2
Dependent Claim 152 words
A catalyst for oxidizing unsaturated aldehydes to the corresponding unsaturated carboxylic acids having the following composition: Mo.sub.a P.sub.b Sb.sub.c Cu.sub.d Cr.sub.e O.sub.f (NH.sub.4).sub.g (wherein, the subscripts a, b, c, d, e, and f denote the numbers respectively of molybdenum, phosphorus, antimony, copper, chromium and oxygen atoms and the subscript g denotes the number of ammonium groups and, where a is fixed at 12, b assumes a value of 1 to 4, c a value of 0.1 to 7, d a value of 0.1 to 5, e a value of 0 to 6 and g a value of 0 to 3.5 respectively and f a value, from 35 to 80, which is automatically determined by the valence of the other atoms), said catalyst being prepared by mixing starting materials containing the component elements, where necessary, in conjunction with aqueous ammonia water, drying the resulting mixture and calcining the dried mass between 300°-500° C.
Claim 3
Dependent Claim 41 words
The oxidation catalyst of claim 1, wherein a is 12, b is 1.5 to 3.5, c is 0.5 to 6, d is 0.3 to 4.5, e is 0.1 to 4, f is 40 to 70 and g is 1 to 3.5.
Claim 4
Dependent Claim 41 words
The oxidation catalyst of claim 1, wherein a is 12, b is 2 to 3, c is 2 to 4, d is 0.5 to 2.5, e is 0.5 to 1.5, f is 45 to 57 and g is 2 to 3.

References Cited (Backward Citations)

US2881212A Cited
US2904580A Cited
US3265635A Cited
US3342849A Cited
US3668147A Cited
US3761516A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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