Polyvinyl alcohol-styrylpyridinium photosensitive resins and method for manufacture thereof

Claim 1

A photosensitive resin, comprising: a polyvinyl alcohol or a partially hydrolyzed polyvinyl acetate polymeric backbone containing units of the formula: ##STR12## wherein A is a photosensitive substituent selected from the group consisting of (A) a group of the generic formula: ##STR13## wherein, R represents one member selected from the class consisting of a hydrogen atom, alkyl groups and lower hydroxyalkyl groups, R' one member selected from the class consisting of a hydrogen atom and alkyl groups and (B) a group of the generic formula: ##STR14## wherein, R 1 represents one member selected from the class consisting of a hydrogen atom, alkyl groups and aralkyl groups, R 2 one member selected from the class consisting of a hydrogen atom and alkyl groups, n an integer having a value between 1 and 6 inclusive and X - a strongly acidic ion, and wherein the molar ratio of said photosensitive substituent to the vinyl alcohol or vinyl acetate units of said polyvinyl alcohol or partially hydrolyzed polyvinyl acetate polymeric backbone ranges from 0.5:99.5 to 10:90, said polyvinyl alcohol or partially hydrolyzed polyvinyl acetate polymeric backbone having a degree of polymerization of 400 to 3000.

Claim 5

A method for the manufacture of a photosensitive resin comprising a polyvinyl alcohol or a partially hydrolyzed polyvinyl acetate polymeric backbone containing units of the formula: ##STR15## wherein A is a photosensitive substituent selected from the group consisting of (A) a group of the generic formula: ##STR16## wherein, R represents one member selected from the class consisting of a hydrogen atom, alkyl groups and lower hydroxyalkyl groups, R' one member selected from the class consisting of a hydrogen and alkyl groups and X - a strongly acidic ion, and (B) a group of the generic formula: ##STR17## wherein, R 1 represents one member selected from the class consisting of a hydrogen atom, alkyl groups and aralkyl groups, R 2 one member selected from the class consisting of a hydrogen atom and alkyl groups, n an integer having a value between 1 and 6 inclusive and X - a strongly acidic ion, which method comprises: reacting one member selected from the group consisting of polyvinyl alcohols and partially saponified polyvinyl acetates in the presence of an acid catalyst with a photosensitive compound selected from the group consisting of (1) styrylpyridinium salts possessing a formyl group and represented by the generic formula: ##STR18## wherein, R represents one member selected from the class consisting of a hydrogen atom, alkyl groups and lower hydroxyalkyl groups, R' one member selected from the class consisting of a hydrogen and alkyl groups and X - a strongly acidic ion, and (2) styrylpyridinium salts possessing an acetal group and represented by the generic formula: ##STR19## wherein, R 1 represents one member selected from the class consisting of a hydrogen atom, alkyl groups and aralkyl groups, R 2 one member selected from the class consisting of a hydrogen atom and alkyl groups, two R 3 's one member selected from the class consisting of an alkyl group and a phenyl group in their respective forms and in a combined form an alkenyl group, n an integer having a value between 1 and 6 inclusive and X - a strongly acidic ion.

Claim 6

A method for the manufacture of a photosensitive resin comprising a polyvinyl alcohol or a partially hydrolyzed polyvinyl acetate polymeric backbone containing units of the formula: ##STR15## wherein A is a photosensitive substituent selected from the group consisting of (A) a group of the generic formula: ##STR16## wherein, R represents one member selected from the class consisting of a hydrogen atom, alkyl groups and lower hydroxyalkyl groups, R' one member selected from the class consisting of a hydrogen and alkyl groups and X - a strongly acidic ion, and (B) a group of the generic formula: ##STR17## wherein, R 1 represents one member selected from the class consisting of a hydrogen atom, alkyl groups and aralkyl groups, R 2 one member selected from the class consisting of a hydrogen atom and alkyl groups, n an integer having a value between 1 and 6 inclusive and X - a strongly acidic ion, which method comprises: reacting one member selected from the group consisting of polyvinyl alcohols and partially saponified polyvinyl acetates in the presence of an acid catalyst with a photosensitive compound selected from the group consisting of (1) styrylpyridinium salts possessing a formyl group and represented by the generic formula: ##STR18## wherein, R represents one member selected from the class consisting of a hydrogen atom, alkyl groups and lower hydroxyalkyl groups, R' one member selected from the class consisting of a hydrogen and alkyl groups and X - a strongly acidic ion, and (2) styrylpyridinium salts possessing an acetal group and represented by the generic formula: ##STR19## wherein, R 1 represents one member selected from the class consisting of a hydrogen atom, alkyl groups and aralkyl groups, R 2 one member selected from the class consisting of a hydrogen atom and alkyl groups, two R 3 's one member selected from the class consisting of an alkyl group and a phenyl group in their respective forms and in a combined form an alkenyl group, n an integer having a value between 1 and 6 inclusive and X - a strongly acidic ion.