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US4272336A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for forming nitric oxide from ammonia

Assignee: Massachusetts Institute of Technology
•
Filing: 1979-07-27
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Granted: 1981-06-09
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Expires: 1999-07-27
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Abstract

Abstract Nitric oxide is formed by the oxidation of ammonia. An ammonia containing gas is contacted with an oxidation catalyst deposited on a surface of a solid electrolyte while an oxygen containing gas is contacted with a second catalyst capable of dissociating oxygen gas to oxygen ion deposited upon a second surface of the solid electrolyte. Oxygen ion is transported through the solid electrolyte to react with ammonia to form nitric oxide under simultaneous production of electric energy.

Inventors

  • 👤 Costas G. Vayenas
  • 👤 David E. Ortman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 17:52
CPC Classifications
C; C25; C25B; C25B5/00; B; B01; B01J; B01J23/00; B01J23/38; C01; C01B; C01B21/00; C01B21/20; C01B21/24; C01B21/26; C01B21/265; C01B21/28; H; H01; H01M; H01M8/00; H01M8/10; H01M8/12; H01M8/1231; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50; Y10; Y10S; Y10S204/00; Y10S204/03

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 107 words
The process for oxidizing ammonia to form nitric oxide which comprises passing an ammonia-containing feed gas at a temperature between about 500° C. and about 1000° C. in contact with a first catalyst deposited on a first surface of a solid electrolyte and passing an oxygen-containing gas in contact with a second catalyst deposited on a second surface of said solid electrolyte, said first catalyst being capable of promoting the oxidation of ammonia to nitric oxide, said second catalyst being capable of dissociating oxygen gas to form oxygen ions, said solid electrolyte being capable of transporting said oxygen ions to contact said ammonia to form nitric oxide.
Claim 2
Dependent Claim 107 words
The process for oxidizing ammonia to form nitric oxide which comprises passing an ammonia-containing feed gas at a temperature between about 500° C. and about 1000° C. in contact with a first catalyst deposited on a first surface of a solid electrolyte and passing an oxygen-containing gas in contact with a second catalyst deposited on a second surface of said solid electrolyte, said first catalyst being capable of promoting the oxidation of ammonia to nitric oxide, said second catalyst being capable of dissociating oxygen gas to form oxygen ions, said solid electrolyte being capable of transporting said oxygen ions to contact said ammonia to form nitric oxide.
Claim 3
Dependent Claim 13 words
The process of claim 1 wherein said solid electrolyte comprises yttria stabilized zirconia.
Claim 4
Dependent Claim 19 words
The process of any one of claims 1 or 2 wherein said first catalyst comprises a platinum-containing metal composition.
Claim 5
Dependent Claim 19 words
The process of any one of claims 1 or 2 wherein said second catalyst comprises a platinum-containing metal composition.
Claim 6
Dependent Claim 24 words
The process of any one of claims 1 or 2 wherein said first catalyst and said second catalyst each comprise a platinum-containing metal composition.
Claim 7
Dependent Claim 13 words
The process of claim 1 wherein said solid electrolyte comprises calcia stabilized zirconia.
Claim 8
Dependent Claim 14 words
The process of claim 6 wherein said first catalyst comprises a platinum-containing metal composition.
Claim 9
Dependent Claim 14 words
The process of claim 6 wherein said second catalyst comprises a platinum-containing metal composition.
Claim 10
Dependent Claim 19 words
The process of claim 1 wherein said first catalyst and said second catalyst each comprise a platinum-containing metal composition.
Claim 11
Dependent Claim 28 words
The process of any one of claims 1, 2, 6, 7, 8 or 9 wherein the temperature of said ammonia is between about 600° C. and 850° C.

References Cited (Backward Citations)

US3103474A Cited
US3103473A Cited
US3350230A Cited
US3300344A Cited
US3368922A Cited
US3931051A Cited
US4175165A Cited
DE2851821A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-06-08 1984-12-08 1985-06-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-06-08 1988-12-08 1989-06-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-06-08 1992-12-08 1993-06-09 $7700.00 Window Closed / Lapsed

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