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US4269735A Expired / Lapsed US ⏱️ 0.0 years remaining

Magnesium oxide catalyst

Assignee: ConocoPhillips Co
•
Filing: 1980-01-21
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Granted: 1981-05-26
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Expires: 2000-01-21
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Abstract

Abstract Amorphorus titanium, uranium, chromium ions and zirconium together with sulfate ions are effective promoters for magnesium oxide catalysts. These catalysts are active for the ortho methylation of phenols in the vapor phase to yield 2,6-xylenol.

Inventors

  • 👤 Bruce E. Leach

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:47
CPC Classifications
B; B01; B01J; B01J21/00; B01J21/06; B01J21/066; B01J21/063; B01J21/10; B01J23/00; B01J23/12; B01J23/16; B01J23/24; B01J23/26; B01J27/00; B01J27/02; B01J27/053; B01J27/20; C; C07; C07C; C07C37/00; C07C37/11; C07C37/16

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 58 words
A catalyst for the alkylation of phenol and phenolic material, comprising magnesium oxide promoted with from about 0.5% to about 15.0% by weight of amorphous titanium, uranium, zirconium and chromium ions or mixtures of these, together with from about 0.50% to about 15% by weight of sulfate ion, all based on the total weight of the final catalyst.
Claim 2
Dependent Claim 58 words
A catalyst for the alkylation of phenol and phenolic material, comprising magnesium oxide promoted with from about 0.5% to about 15.0% by weight of amorphous titanium, uranium, zirconium and chromium ions or mixtures of these, together with from about 0.50% to about 15% by weight of sulfate ion, all based on the total weight of the final catalyst.
Claim 3
Dependent Claim 15 words
A catalyst as described in claim 1 wherein titanium is used together with magnesium sulfate.
Claim 4
Dependent Claim 23 words
A catalyst as described in claim 2 wherein the catalyst contains in addition from about 1% to about 5% by weight of silica.
Claim 5
Dependent Claim 18 words
A catalyst as described in claim 3 wherein the catalyst contains from about 1% to about 3% graphite.
Claim 6
Dependent Claim 29 words
A catalyst as described in claim 4 wherein the titanium is present in an amount from about 0.5% to about 10% by weight together with equivalent amounts of sulfate.

References Cited (Backward Citations)

US3446856A Cited
US3479410A Cited
US3873628A Cited
US3893948A Cited
US3968172A Cited
US4060560A Cited
US4060561A Cited
US4110253A Cited
US4125736A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-25 1984-11-24 1985-05-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-25 1988-11-24 1989-05-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-25 1992-11-24 1993-05-26 $7700.00 Window Closed / Lapsed

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