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US4268262A Expired / Lapsed US ⏱️ 0.0 years remaining

Clear, cold-stable liquid washing agent concentrates

Assignee: Henkel AG and Co KGaA
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Filing: 1979-10-19
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Granted: 1981-05-19
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Expires: 1999-10-19
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Abstract

Abstract A clear, cold-stable liquid washing agent concentrate consisting essentially of: (A) from 22.5% to 35% by weight of a potassium soap of fatty acids having 12 to 18 carbon atoms and a melting point of below 55° C., (B) from 5% to 9% by weight of an ethoxylated primary alcohol having 5 to 10 oxyethylene units, (C) from 4% to 10% by weight of a sodium C 10 -C 14 alkylbenzenesulfonate, (D) from 0.05% to 1% by weight of at least one optical brightener, (E) from 0.1% to 5% by weight of potassium hydroxide. (F) from 0 to 6% by weight of triethanolamine, (G) from 8% to 20% by weight of at least one C 1-3 alcohol, and (H) the remainder up to 100% of water, wherein the amount of water is at least 30% by weight and the concentration of the total of components (A) to (E) does not exceed 50% by weight of the concentrate. The washing agent concentrate can be employed in all type of washings of textiles in soft or hard waters, preferably in amounts of from 3 to 10 gm per kg of dry wash.

Inventors

  • 👤 Wolfgang Bechstedt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:36
CPC Classifications
C; C11; C11D; C11D10/00; C11D10/04; C11D3/00; C11D3/16; C11D3/20; C11D3/2003; C11D3/2006; C11D3/201; C11D3/40; C11D3/42; C11D1/00; C11D1/02; C11D1/12; C11D1/22; C11D1/66; C11D1/72

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 289 words
A clear, cold-stable liquid washing agent concentrate consisting essentially of: (A) from 25% to 30% by weight of a potassium soap of C 12-18 -fatty acids having from 60% to 100% of the fatty acid of acids selected from the group consisting of C 12-14 -alkanoic acids, oleic acid, and mixture thereof, wherein the amount of saturated C 16-18 -fatty acids is from 1% to 15% by weight of the fatty acids and the amount of stearic acid does not exceed 3% by weight of the fatty acids, (B) from 5% to 9% by weight of an ethoxylate of from 6 to 8 ethoxylate units onto a primary alcohol selected from the group consisting of linear C 9-12 -alkanols and C 9-12 -2-methylated alkanols, (C) from 6% to 8% by weight of a sodium C 10-14 -alkyl-benzenesulfonate, (D) from 0.1% to 0.7% by weight of an alkali metal salt of substituted stilbenesulfonic acid optical brighteners, (E) from 0.7% to 4% by weight of potassium hydroxide, (F) from 0 to 6% by weight of triethanolamine, (G) from 12% to 18% by weight of alcohols selected from the group consisting of C 1-3 -alkanols and mixtures of C 1-3 -alkanols with up to 35% by weight of the mixture of hydrotropes selected from the group consisting of C 1-4 -alkoxy-C 2-3 -alkanols, C 1-4 -alkoxy-C 2-3 -alkoxy-C 2-3 -alkanols and alkali metal salts of alkylbenzenesulfonates having from 1 to 2 alkyl groups with a total of 1 to 3 carbon atoms, and (H) the remainder up to 100% of water, where the amount of water is from 30% to 50% by weight and the concentration of the total compounds A to E does not exceed 50% by weight of the concentrate.
Claim 2
Dependent Claim 289 words
A clear, cold-stable liquid washing agent concentrate consisting essentially of: (A) from 25% to 30% by weight of a potassium soap of C 12-18 -fatty acids having from 60% to 100% of the fatty acid of acids selected from the group consisting of C 12-14 -alkanoic acids, oleic acid, and mixture thereof, wherein the amount of saturated C 16-18 -fatty acids is from 1% to 15% by weight of the fatty acids and the amount of stearic acid does not exceed 3% by weight of the fatty acids, (B) from 5% to 9% by weight of an ethoxylate of from 6 to 8 ethoxylate units onto a primary alcohol selected from the group consisting of linear C 9-12 -alkanols and C 9-12 -2-methylated alkanols, (C) from 6% to 8% by weight of a sodium C 10-14 -alkyl-benzenesulfonate, (D) from 0.1% to 0.7% by weight of an alkali metal salt of substituted stilbenesulfonic acid optical brighteners, (E) from 0.7% to 4% by weight of potassium hydroxide, (F) from 0 to 6% by weight of triethanolamine, (G) from 12% to 18% by weight of alcohols selected from the group consisting of C 1-3 -alkanols and mixtures of C 1-3 -alkanols with up to 35% by weight of the mixture of hydrotropes selected from the group consisting of C 1-4 -alkoxy-C 2-3 -alkanols, C 1-4 -alkoxy-C 2-3 -alkoxy-C 2-3 -alkanols and alkali metal salts of alkylbenzenesulfonates having from 1 to 2 alkyl groups with a total of 1 to 3 carbon atoms, and (H) the remainder up to 100% of water, where the amount of water is from 30% to 50% by weight and the concentration of the total compounds A to E does not exceed 50% by weight of the concentrate.
Claim 3
Dependent Claim 46 words
The clear, cold-stable liquid washing agent concentrate of claim 1, wherein the fatty acids of the potassium soap component A consists of 65% to 95% by weight of oleic acid and does not contain more than 3% by weight of the fatty acids of stearic acid.
Claim 4
Dependent Claim 46 words
The clear, cold-stable liquid washing agent concentrate of claim 1, wherein the fatty acids of the potassium soap component A consists of 75% to 95% by weight of a mixture of lauric acid and myristic acid, of which at least half the mixture is lauric acid.
Claim 5
Dependent Claim 21 words
The clear, cold-stable liquid washing agent concentrate of claim 3 wherein at least two thirds of said mixture is lauric acid.
Claim 6
Dependent Claim 34 words
The clear, cold-stable liquid washing agent concentrate of claims 1, 2 or 3 wherein the ethoxylate component B is an ethoxylate of from 6 to 8 ethoxylate units onto a linear C 9-12 -alkanol.
Claim 7
Dependent Claim 20 words
The clear, cold-stable liquid washing agent concentrate of claims 1, 2 or 3 wherein said component C is sodium dodecylbenzenesulfonate.
Claim 8
Dependent Claim 138 words
The clear, cold-stable liquid washing agent concentrate of claims 1, 2 or 3 wherein said optical brightener component D is a compound of the formula selected from the group consisting of ##STR3## wherein Me is a member selected from the group consisting of sodium and potassium, R 1 and R 2 are members selected from the group consisting of --NHCH 3 , --NCH 3 (CH 2 CH 2 OH), --N(CH 2 CH 2 OH) 2 , ##STR4## R 3 and R 4 are members selected from the group consisting of H, --CH 3 , --CL, --OCH 3 , --COOCH 3 , --CN, --SO 2 NR 5 R 6 , and --CONR 5 R 6 , R 5 and R 6 are members selected from the group consisting of hydrogen and alkyl having from 1 to 3 carbon atoms.
Claim 9
Dependent Claim 28 words
The clear, cold-stable liquid washing agent concentrate of claim 7 wherein R 1 and R 2 are members selected from the group consisting of morpholino, diethanolamino and anilino.
Claim 10
Dependent Claim 30 words
The clear, cold-stable liquid washing agent concentrate of claim 1 wherein the triethanolamine component F is present in an amount of from 2% to 5% by weight of the concentrate.
Claim 11
Dependent Claim 17 words
The clear, cold-stable liquid washing agent concentrate of claim 1, wherein said alcohol component G is isopropanol.
Claim 12
Dependent Claim 22 words
The clear, cold-stable liquid washing agent concentrate of claim 1 wherein the amount of water is from 30% to 50% by weight.
Claim 13
Independent Claim 312 words
A method of washing soiled textiles consisting of the steps of adding a clear, cold-stable liquid washing agent concentrate consisting essentially of: (A) from 22.5% to 35% by weight of a potassium soap of C 12-18 -fatty acids having from 60% to 100% of the fatty acid of acids selected from the group consisting of C 12-14 -alkanoic acids, oleic acid, and mixtures thereof, (B) from 5% to 9% by weight of an ethoxylate of from 5 to 10 ethoxylate units onto a primary alcohol selected from the group consisting of linear C 8-14 -alkanols and C 8-14 -2-methylated alkanols, (C) from 4% to 10% by weight of a sodium C 10-14 -alkylbenzenesulfonate, (D) from 0.05% to 1% by weight of an alkali metal salt of substituted stilbenesulfonic acid optical brighteners, (E) from 0.1% to 5% by weight of potassium hydroxide, (F) from 0 to 6% by weight of triethaolamine, (G) from 8% to 20% by weight of alcohols selected from the group consisting of C 1-3 -alkanols and mixtures of C 1-3 -alkanols with up to 35% by weight of the mixture of hydrotropes selected from the group consisting of C 1-4 -alkoxy-C 2-3 -alkanols, C 1-4 -alkoxy-C 2-3 -alkoxy-C 2-3 -alkanols and alkali metal salts of alkylbenzenesulfonates having from 1 to 2 alkyl groups with a total of 1 to 3 carbon atoms, and (H) the remainder up to 100% by water, where the amount of water is at least 30% by weight and the concentration of the total of components A to E does not exceed 50% by weight of the concentrate, to softened water containing soiled textiles in an automatic washer in such amounts that from 3 to 10 gm of said concentrate are present per kilo-gram of dry textiles, agitating said textiles in said concentrate-containing softened water, draining, rinsing and mangling said textiles and recovering clean textiles.
Claim 14
Independent Claim 312 words
A method of washing soiled textiles consisting of the steps of adding a clear, cold-stable liquid washing agent concentrate consisting essentially of: (A) from 22.5% to 35% by weight of a potassium soap of C 12-18 -fatty acids having from 60% to 100% of the fatty acid of acids selected from the group consisting of C 12-14 -alkanoic acids, oleic acid, and mixtures thereof, (B) from 5% to 9% by weight of an ethoxylate of from 5 to 10 ethoxylate units onto a primary alcohol selected from the group consisting of linear C 8-14 -alkanols and C 8-14 -2-methylated alkanols, (C) from 4% to 10% by weight of a sodium C 10-14 -alkylbenzenesulfonate, (D) from 0.05% to 1% by weight of an alkali metal salt of substituted stilbenesulfonic acid optical brighteners, (E) from 0.1% to 5% by weight of potassium hydroxide, (F) from 0 to 6% by weight of triethaolamine, (G) from 8% to 20% by weight of alcohols selected from the group consisting of C 1-3 -alkanols and mixtures of C 1-3 -alkanols with up to 35% by weight of the mixture of hydrotropes selected from the group consisting of C 1-4 -alkoxy-C 2-3 -alkanols, C 1-4 -alkoxy-C 2-3 -alkoxy-C 2-3 -alkanols and alkali metal salts of alkylbenzenesulfonates having from 1 to 2 alkyl groups with a total of 1 to 3 carbon atoms, and (H) the remainder up to 100% by water, where the amount of water is at least 30% by weight and the concentration of the total of components A to E does not exceed 50% by weight of the concentrate, to softened water containing soiled textiles in an automatic washer in such amounts that from 3 to 10 gm of said concentrate are present per kilo-gram of dry textiles, agitating said textiles in said concentrate-containing softened water, draining, rinsing and mangling said textiles and recovering clean textiles.

References Cited (Backward Citations)

US2097737A Cited
US2792347A Cited
GB1116966A Cited
US4065398A Cited
US4079078A Cited
DE2609752A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-18 1984-11-17 1985-05-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-18 1988-11-17 1989-05-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-18 1992-11-17 1993-05-19 $7700.00 Window Closed / Lapsed

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