US4266003A
Expired / Lapsed
US
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Silver halide photographic emulsions
Assignee: Fujifilm Holdings Corp
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Filing: 1979-09-25
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Granted: 1981-05-05
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Expires: 1999-09-25
Abstract
Abstract A silver halide photographic emulsion which comprises at least one compound represented by the formula (I): ##STR1## where Z represents an atomic group necessary to complete an oxazole nucleus, a benzoxazole nucleus or a naphthoxazole nucleus, R 1 represents a substituted or unsubstituted alkyl group, R 2 represents an alkoxycarbonylalkyl group, a hydroxyalkyl group, a hydroxyalkoxyalkyl group, a carbamoylalkyl group, a hydroxyphenyl group or a hydroxyalkylphenyl group, and R 3 and R 4 which may be the same or different each represents a hydrogen atom, an alkyl group, an alkoxy group, a chlorine atom or a carboxyl group, and a lithographic silver halide material containing the same.
Inventors
- 👤 Tadashi Ikeda
- 👤 Takeo Sakai
- 👤 Haruo Takei
- 👤 Noriyuki Inoue
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 19:56
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C1/22; C; C09; C09B; C09B23/00; C09B23/10; C09B23/105; Y; Y10; Y10S; Y10S430/00; Y10S430/15
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
130 words
A silver halide photographic emulsion which compares at least one compound represented by the formula (II): ##STR7## wherein R 5 represents a hydrogen atom, a chlorine atom, a hydroxyl group, an alkylcarbonyloxy group having up to 3 carbon atoms, an unsubstituted alkyl group having up to 4 carbon atoms, or an unsubstituted alkoxy group having up to 4 carbon atoms; R 6 represents a sulfoalkyl group having 2 to 4 carbon atoms: R 7 represents a hydroxyalkoxyalkyl group having 2 to 6 carbon atoms, or a hydroxyalkyl group having 2 to 4 carbon atoms; R 8 represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group, or an ethoxy group; and R 9 represents a hydrogen atom, a methyl group, or a methoxy group.
Claim 2
Dependent Claim
130 words
A silver halide photographic emulsion which compares at least one compound represented by the formula (II): ##STR7## wherein R 5 represents a hydrogen atom, a chlorine atom, a hydroxyl group, an alkylcarbonyloxy group having up to 3 carbon atoms, an unsubstituted alkyl group having up to 4 carbon atoms, or an unsubstituted alkoxy group having up to 4 carbon atoms; R 6 represents a sulfoalkyl group having 2 to 4 carbon atoms: R 7 represents a hydroxyalkoxyalkyl group having 2 to 6 carbon atoms, or a hydroxyalkyl group having 2 to 4 carbon atoms; R 8 represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group, or an ethoxy group; and R 9 represents a hydrogen atom, a methyl group, or a methoxy group.
Claim 3
Dependent Claim
17 words
The silver halide emulsion layer of claim 1, wherein said emulsion additionally contains a polyalkylene oxide compound.
Claim 4
Dependent Claim
29 words
The silver halide emulsion layer of claim 2, wherein said polyalkylene oxide compound is present in an amount of about 0.01 to 10 g per mol of silver halide.
Claim 5
Dependent Claim
35 words
The silver halide emulsion of claim 1, wherein said silver halide is a silver chlorobromide or a silver chloroiodobromide containing at least about 60 mol% silver chloride and about 0 to 5 mol% silver iodide.
Claim 6
Dependent Claim
13 words
The silver halide emulsion of claim 1, wherein said emulsion is chemically sensitized.
Claim 7
Dependent Claim
156 words
A lithographic silver halide photographic material comprising a support having thereon a silver halide emulsion layer containing at least one compound represented by the formula (II): ##STR8## wherein R 5 represents a hydrogen atom, a chlorine atom, a hydroxyl group, an alkylcarbonyloxy group having up to 3 carbon atoms, an unsubstituted alkyl group having up to 4 carbon atoms, or an unsubstituted alkoxy group having up to 4 carbon atoms; R 6 represents a sulfoalkyl group having 2 to 4 carbon atoms; R 7 represents a hydroxyalkoxyalkyl group having 2 to 6 carbon atoms, or a hydroxyalkyl group having 2 to 4 carbon atoms; R 8 represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group, or an ethoxy group; and R 9 represents a hydrogen atom, a methyl group, or a methoxy group; and said emulsion layer and optionally an adjacent hydrophilic colloid layer contains a polyalkylene oxide compound.
Claim 8
Dependent Claim
156 words
A lithographic silver halide photographic material comprising a support having thereon a silver halide emulsion layer containing at least one compound represented by the formula (II): ##STR8## wherein R 5 represents a hydrogen atom, a chlorine atom, a hydroxyl group, an alkylcarbonyloxy group having up to 3 carbon atoms, an unsubstituted alkyl group having up to 4 carbon atoms, or an unsubstituted alkoxy group having up to 4 carbon atoms; R 6 represents a sulfoalkyl group having 2 to 4 carbon atoms; R 7 represents a hydroxyalkoxyalkyl group having 2 to 6 carbon atoms, or a hydroxyalkyl group having 2 to 4 carbon atoms; R 8 represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group, or an ethoxy group; and R 9 represents a hydrogen atom, a methyl group, or a methoxy group; and said emulsion layer and optionally an adjacent hydrophilic colloid layer contains a polyalkylene oxide compound.
Claim 9
Dependent Claim
26 words
The lithographic material of claim 6, wherein said polyalkylene oxide compound is present in an amount of 0.01 to 10 g per mol of silver halide.
Claim 10
Dependent Claim
35 words
The lithographic material of claim 6, wherein said polyalkylene oxide compound is a condensate of a polyalkylene oxide containing at least 10 alkylene oxide units and a compound having at least one active hydrogen atom.
Claim 11
Dependent Claim
31 words
The lithographic material of claim 8, wherein said compound having at least one active hydrogen is water, an aliphatic alcohol, an aromatic alcohol, an aliphatic acid, an organic amine or hexitol.
Claim 12
Dependent Claim
51 words
The lithographic material of claim 6, wherein said polyalkylene oxide is selected from the group consisting of polyalkylene glycol, polyalkylene glycol alkyl ethers, polyalkylene glycol aryl ethers, polyalkylene glycol alkylaryl ethers, polyalkylene glycol esters, polyalkylene glycol aliphatic acid amides, polyalkylene glycol amines, polyalkylene glycol block copolymers and polyalkylene glycol graft copolymers.
Claim 13
Dependent Claim
18 words
The lithographic material of claim 6, wherein said polyalkylene oxide compound contains 14 to 100 alkylene oxide units.
Claim 14
Dependent Claim
20 words
The lithographic material of claim 6, wherein said polyalkylene oxide compound has a molecular weight of about 300 to 1,500.
Claim 15
Dependent Claim
32 words
The lithographic material of claim 6, wherein said silver halide is silver chlorobromide or silver chloroiodobromide containing at least about 60 mol% silver chloride and about 0 to 5 mol% silver iodide.
Claim 16
Dependent Claim
19 words
A method for forming images which comprises exposing the lithographic material of claim 6 and infectiously developing said material.
Claim 17
Dependent Claim
25 words
The process of claim 14, wherein said infectious developing solution contains an o- or p-dihydroxybenzene, an alkali, free sulfite and a sulfurous acid ion buffer.
Claim 18
Dependent Claim
12 words
The process of claim 14, wherein said developing solution additionally contains diethanolamine.
Claim 19
Dependent Claim
18 words
The silver halide emulsion of claim 1, wherein R 5 represents a hydrogen atom or a chloride atom.
Claim 20
Dependent Claim
17 words
The lithographic material of claim 6, wherein R 5 represents a hydrogen atom or a chlorine atom.
Claim 21
Dependent Claim
12 words
The silver halide emulsion of claim 1, wherein R 5 is hydrogen.
Claim 22
Dependent Claim
11 words
The lithographic material of claim 6, wherein R 5 is hydrogen.
Claim 23
Dependent Claim
23 words
The silver halide emulsion of claim 1, wherein R 8 and R 9 are selected from the group consisting of hydrogen and methyl.
Claim 24
Dependent Claim
22 words
The lithographic material of claim 6, wherein R 8 and R 9 are selected from the group consisting of hydrogen and methyl.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-05-04 | 1984-11-03 | 1985-05-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-05-04 | 1988-11-03 | 1989-05-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-05-04 | 1992-11-03 | 1993-05-05 | $7700.00 | Window Closed / Lapsed |