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US4154616A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic emulsion

Assignee: Fujifilm Holdings Corp
•
Filing: 1977-05-12
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Granted: 1979-05-15
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Expires: 1997-05-12
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Abstract

Abstract A silver halide photographic emulsion containing at least one sensitizing dye represented by the following general formula (I), <IMAGE> (I) in which Z represents an atomic group necessary for forming a benzoxazole nucleus or a naphthoxazole nucleus; R1 represents an aliphatic group; R2 represents an alkyl group, an allyl group or an aryl group; R3 represents a 2-(2-hydroxyethoxy)-ethyl group, a 2-(2-acyloxyethyoxy)-ethyl group, an N-(N,N-dialkylaminoalkyl)carbamoylalkyl group, an N-(N,N,N-trialkylammoniumalkyl)carbamoylalkyl group or an N,N,N-trialkylammoniumalkyl group; X represents an acid anion; and n represents 0 or 1.

Inventors

  • 👤 Akira Sato
  • 👤 Akira Ogawa
  • 👤 Masanao Hinata
  • 👤 Haruo Takei

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 23:09
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C1/22

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 116 words
A silver halide photographic emulsion containing at least one sensitizing dye represented by the following general formula (I): ##STR30## in which Z represents an atomic group necessary for forming a benzoxazole nucleus or a naphthoxazole nucleus; R 1 represents a member selected from the group consisting of an unsubstituted alkyl group; an alkyl group substituted with a hydroxy group, an alkoxy group, an acyloxy group, a carboxy group, an alkoxycarbonyl group, a sulfo group, or an aryl group; or an allyl group; R 2 represents an alkyl group, an allyl group or an aryl group; R 3 represents a 2-(2-hydroxyethoxy)-ethyl group, or a 2-(2-acyloxyethoxy)-ethyl group; X represents an acid anion; and n represents 0 or 1.
Claim 2
Dependent Claim 116 words
A silver halide photographic emulsion containing at least one sensitizing dye represented by the following general formula (I): ##STR30## in which Z represents an atomic group necessary for forming a benzoxazole nucleus or a naphthoxazole nucleus; R 1 represents a member selected from the group consisting of an unsubstituted alkyl group; an alkyl group substituted with a hydroxy group, an alkoxy group, an acyloxy group, a carboxy group, an alkoxycarbonyl group, a sulfo group, or an aryl group; or an allyl group; R 2 represents an alkyl group, an allyl group or an aryl group; R 3 represents a 2-(2-hydroxyethoxy)-ethyl group, or a 2-(2-acyloxyethoxy)-ethyl group; X represents an acid anion; and n represents 0 or 1.
Claim 3
Dependent Claim 28 words
The silver halide photographic emulsion of claim 1, wherein Z is 5-fluorobenzoxazole, 5-chlorobenzoxazole, 5-chlorobenzoxazole, 5-bromobenzoxazole, 5-methylbenzoxazole, 5-methoxybenzoxazole, 5-hydroxybenzoxazole, 5-trifluoromethylbenzoxazole, 5-methoxycarbonylbenzoxazole, 5-acetylbenzoxazole, 5-phenylbenzoxazole, 6-methylbenzoxazole, 6-methoxybenzoxazole, 6-hydroxybenzoxazole, 5,6-dimethylbenzoxazole, or 5-chloro-6-methylbenzoxazole.
Claim 4
Dependent Claim 28 words
The silver halide photographic emulsion of claim 1, wherein said silver halide is silver chloride, silver bromide, silver iodide, silver chlorobromide, silver bromiodide, silver chloroiodide, or silver chlorobromoiodide.
Claim 5
Dependent Claim 26 words
The silver halide photographic emulsion of claim 1, wherein the grains of said silver halide have an average diameter ranging from about 0.04 to 2 microns.
Claim 6
Dependent Claim 34 words
The silver halide photographic emulsion of claim 1, wherein said silver halide emulsion contains at least one of a chemical sensitizer, a hardener, an antifoggant, a stabilizer, a coating aid, and a color coupler.
Claim 7
Dependent Claim 21 words
A silver halide photographic element comprising a support having thereon a layer of the silver halide photographic emulsion of claim 1.
Claim 8
Dependent Claim 15 words
The silver halide photographic emulsion of claim 1, wherein R 2 represents an alkyl group.
Claim 9
Dependent Claim 19 words
The silver halide photographic emulsion of claim 1, wherein R 2 represents a methyl, ethyl, propyl or butyl group.
Claim 10
Dependent Claim 15 words
The silver halide photographic emulsion of claim 1, wherein R 2 represents an allyl group.
Claim 11
Dependent Claim 15 words
The silver halide photographic emulsion of claim 1, wherein R 2 represents an aryl group.
Claim 12
Dependent Claim 17 words
The silver halide photographic emulsion of claim 1, wherein R 2 represents a phenyl or p-sulfophenyl group.
Claim 13
Dependent Claim 15 words
The silver halide photographic emulsion of claim 1, wherein R 3 represents said 2-(2-hydroxyethoxy)-ethyl group.
Claim 14
Dependent Claim 15 words
The silver halide photographic emulsion of claim 1, wherein R 3 represents said 2-(2-acyloxyethoxy)-ethyl group.

References Cited (Backward Citations)

US3698910A Cited
US3736145A Cited
US3765900A Cited
US4014702A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-14 1982-11-13 1983-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-14 1986-11-13 1987-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-14 1990-11-13 1991-05-15 $7700.00 Window Closed / Lapsed

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