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US4265948A Expired / Lapsed US ⏱️ 0.0 years remaining

Collapsible dispensing tube

Assignee: SPECIALTY ACQUISITION Corp A CORP OF DELAWARE
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Filing: 1978-10-10
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Granted: 1981-05-05
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Expires: 1998-10-10
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Abstract

Abstract A collapsible dispensing container having a laminated tubular body, the laminated tubular body including a metal foil layer, and a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR1## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR2## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR3## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.

Inventors

  • 👤 Thomas H. Hayes
  • 👤 Lewis C. Lo Maglio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 14:16
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; B32B15/085; B32B1/00; B32B1/08; B32B15/18; B32B15/20; B32B7/00; B32B7/04; B32B7/12; B65; B65D; B65D35/00; B65D35/02; B65D35/10; B32B2311/00; B32B2311/16; B32B2311/24; B32B2311/30; B32B2323/00; B32B2439/00; B32B2439/40; B32B2439/80; B32B2597/00; Y; Y10; Y10S; Y10S428/00; Y10S428/911; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355; Y10T428/1359; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696; Y10T428/31699; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31917; Y10T428/31928; Y10T428/31931

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 309 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination and on the outside of said polyolefin layer, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR10## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 2
Dependent Claim 309 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination and on the outside of said polyolefin layer, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR10## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 3
Dependent Claim 307 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR11## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR12## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR13## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 4
Dependent Claim 307 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR11## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR12## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR13## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 5
Dependent Claim 310 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR14## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR15## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR16## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 6
Dependent Claim 310 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR14## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR15## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR16## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 7
Dependent Claim 296 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR17## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR18## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR19## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 8
Dependent Claim 296 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of a mixture of (a) from 70 to 95 percent by weight of acrylonitrile, and (b) from 30 to 5 percent by weight of methyl acrylate in the presence of from 1 to 20 parts by weight of (c) a copolymer of butadiene and acrylonitrile, said copolymer containing from 60 to 80 percent by weight of polymerized butadiene and from 40 to 20 percent by weight of polymerized acrylonitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR17## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR18## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR19## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 9
Dependent Claim 406 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination and on the outside of said polyolefin layer, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR20## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR21## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR22## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing container having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR23## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR24## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR25## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 10
Dependent Claim 406 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination and on the outside of said polyolefin layer, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR20## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR21## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR22## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing container having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR23## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR24## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR25## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 11
Dependent Claim 16 words
The composition of claim 5 wherein the (a) component of the laminated tubular body is methacrylonitrile.
Claim 12
Dependent Claim 22 words
The composition of claim 6 wherein there is employed 100 percent by weight of the (a) component of the laminated tubular body.
Claim 13
Dependent Claim 16 words
The composition of claim 5 wherein the (a) component of the laminated tubular body is acrylonitrile.
Claim 14
Dependent Claim 17 words
The composition of claim 8 wherein the (b) component of the laminated tubular body is ethyl acrylate.
Claim 15
Dependent Claim 17 words
The composition of claim 8 wherein the (b) component of the laminated tubular body is methyl acrylate.
Claim 16
Dependent Claim 34 words
The composition of claim 10 wherein, in the laminated tubular body, there is employed a mixture of 75 percent by weight of the (a) component and 25 percent by weight of the (b) component.
Claim 17
Dependent Claim 398 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR26## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR27## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR28## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR29## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR30## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR31## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 18
Dependent Claim 398 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the outside of said metal foil lamination, and, on the inside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR26## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR27## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR28## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR29## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR30## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR31## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 19
Dependent Claim 16 words
The composition of claim 12 wherein the (a) component of the laminated tubular body is methacrylonitrile.
Claim 20
Dependent Claim 22 words
The composition of claim 13 wherein there is employed 100 percent by weight of the (a) component of the tubular laminated body.
Claim 21
Dependent Claim 16 words
The composition of claim 12 wherein the (a) component of the laminated tubular body is acrylonitrile.
Claim 22
Dependent Claim 17 words
The composition of claim 15 wherein the (b) component of the laminated tubular body is ethyl acrylate.
Claim 23
Dependent Claim 17 words
The composition of claim 15 wherein the (b) component of the laminated tubular body is methyl acrylate.
Claim 24
Dependent Claim 34 words
The composition of claim 17 wherein, in the laminated tubular body, there is employed a mixture of 75 percent by weight of the (a) component and 25 percent by weight of the (b) component.
Claim 25
Dependent Claim 401 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR32## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR33## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR34## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR35## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR36## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR37## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 26
Dependent Claim 401 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, a layer of a polyolefin on the inside and outside of said metal foil lamination, and, on the outside of both of said polyolefin layers, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR32## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR33## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR34## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR35## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR36## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR37## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 27
Dependent Claim 16 words
The composition of claim 19 wherein the (a) component of the laminated tubular body is methacrylonitrile.
Claim 28
Dependent Claim 22 words
The composition of claim 20 wherein there is employed 100 percent by weight of the (a) component of the laminated tubular body.
Claim 29
Dependent Claim 16 words
The composition of claim 19 wherein the (a) component of the laminated tubular body is acrylonitrile.
Claim 30
Dependent Claim 17 words
The composition of claim 22 wherein the (b) component of the laminated tubular body is ethyl acrylate.
Claim 31
Dependent Claim 17 words
The composition of claim 22 wherein the (b) component of the laminated tubular body is methyl acrylate.
Claim 32
Dependent Claim 34 words
The composition of claim 24 wherein, in the laminated tubular body, there is employed a mixture of 75 percent by weight of the (a) component and 25 percent by weight of the (b) component.
Claim 33
Dependent Claim 387 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR38## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR39## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR40## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR41## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR42## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR43## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 34
Dependent Claim 387 words
A collapsible dispensing container having a laminated tubular body, said laminated tubular body including a fluid impervious metal foil lamination, and, on the inside and outside of said metal foil lamination, a layer of a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR38## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR39## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR40## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile, said collapsible dispensing tube having connected thereto headpiece means made from a copolymer resulting from the polymerization of 100 parts by weight of (a) at least 50 percent by weight of at least one nitrile having the structure ##STR41## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (b) up to 50 percent by weight based on the combined weight of (a) and (b) of an ester having the structure ##STR42## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, in the presence of from 1 to 40 parts by weight of (c) a copolymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and an olefinically unsaturated nitrile having the structure ##STR43## wherein R has the foregoing designation containing from 50 to 95 percent by weight of polymerized conjugated diene and from 50 to 5 percent by weight of polymerized olefinically unsaturated nitrile.
Claim 35
Dependent Claim 16 words
The composition of claim 26 wherein the (a) component of the laminated tubular body is methacrylonitrile.
Claim 36
Dependent Claim 22 words
The composition of claim 27 wherein there is employed 100 percent by weight of the (a) component of the laminated tubular body.
Claim 37
Dependent Claim 16 words
The composition of claim 26 wherein the (a) component of the laminated tubular body is acrylonitrile.
Claim 38
Dependent Claim 17 words
The composition of claim 29 wherein the (b) component of the laminated tubular body is ethyl acrylate.
Claim 39
Dependent Claim 17 words
The composition of claim 29 wherein the (b) component of the laminated tubular body is methyl acrylate.
Claim 40
Dependent Claim 34 words
The composition of claim 31 wherein, in the laminated tubular body, there is employed a mixture of 75 percent by weight of the (a) component and 25 percent by weight of the (b) component.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-05-04 1984-11-03 1985-05-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-05-04 1988-11-03 1989-05-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-05-04 1992-11-03 1993-05-05 $7700.00 Window Closed / Lapsed

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