Patent US4264370A successfully refreshed from Google Patents.
US4264370A
Expired / Lapsed
US
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Method for preparing aluminum-based air drying compositions
Assignee: Manchem Ltd
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Filing: 1978-02-21
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Granted: 1981-04-28
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Expires: 1998-02-21
Abstract
Abstract Method for preparing storage-stable air-drying compositions containing a combination of an aluminum alkoxide with a labile monofunctional reactant such as an alkanol, alkoxyalkanol, keto ester, water, hydrogen peroxide, organic hydroperoxide or mixtures thereof.
Inventors
- 👤 John H. W. Turner
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 04:03
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/05; C08K5/057
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
186 words
In a method for forming a storage-stable composition by addition of an alkoxyaluminum compound to a drying oil resin or ester containing hydroxyl or carboxyl groups, the improvement which comprises adding to and reacting under ambient conditions with said alkoxyaluminum compound at least one gram mole of a labile monofunctional reactant per gram atom of aluminum in said alkoxyaluminum compound prior to addition of said alkoxyaluminum compound to said drying oil resin or ester, thereby forming a fluid, storage-stable mixture which is resistant to gelation until said labile monofunctional reactant is released from said mixture by evaporation or hydrolysis, wherein said labile monofunctional reactant is selected from the group consisting of lower alkanols having up to about eight carbon atoms, tert-butyl hydroperoxide, cumenyl hydroperoxide, water, hydrogen peroxide, and mixtures thereof and wherein said alkoxyaluminum compound has the formula ##STR4## in which R is selected from the group consisting of lower alkyl, lower cycloalkyl, and lower alkoxyalkyl, and each of said A and B is selected from the group consisting of OR and 2-ethylhexoate, 3,5,5-trimethylhexoate, versatate, naphthenate, acid monoisopropyl phthalate, acid monoethoxyethoxyl maleate, ethyl acetoacetate, and acetylacetone.
Claim 2
Dependent Claim
186 words
In a method for forming a storage-stable composition by addition of an alkoxyaluminum compound to a drying oil resin or ester containing hydroxyl or carboxyl groups, the improvement which comprises adding to and reacting under ambient conditions with said alkoxyaluminum compound at least one gram mole of a labile monofunctional reactant per gram atom of aluminum in said alkoxyaluminum compound prior to addition of said alkoxyaluminum compound to said drying oil resin or ester, thereby forming a fluid, storage-stable mixture which is resistant to gelation until said labile monofunctional reactant is released from said mixture by evaporation or hydrolysis, wherein said labile monofunctional reactant is selected from the group consisting of lower alkanols having up to about eight carbon atoms, tert-butyl hydroperoxide, cumenyl hydroperoxide, water, hydrogen peroxide, and mixtures thereof and wherein said alkoxyaluminum compound has the formula ##STR4## in which R is selected from the group consisting of lower alkyl, lower cycloalkyl, and lower alkoxyalkyl, and each of said A and B is selected from the group consisting of OR and 2-ethylhexoate, 3,5,5-trimethylhexoate, versatate, naphthenate, acid monoisopropyl phthalate, acid monoethoxyethoxyl maleate, ethyl acetoacetate, and acetylacetone.
Claim 3
Dependent Claim
14 words
The method according to claim 1 in which said labile monofunctional reactant is ethoxyethanol.
Claim 4
Dependent Claim
14 words
The method according to claim 1 in which said labile monofunctional reactant is isopropanol.
Claim 5
Dependent Claim
20 words
The method according to claim 1 in which said labile monofunctional reactant is a mixture of hydrogen peroxide and ethoxyethanol.
Claim 6
Dependent Claim
15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoisopropoxide monoversatate(monoisopropyl)phthalate.
Claim 7
Dependent Claim
15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum diethoxyethoxide monoversatate.
Claim 8
Dependent Claim
14 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum triethoxyethoxide.
Claim 9
Dependent Claim
16 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoisopropoxide monoethyoxyethoxide monoethylacetoacetate.
Claim 10
Dependent Claim
15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum diethoxyethoxide monoacetylacetonate.
Claim 11
Dependent Claim
15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoethoxyethoxide diacetylacetonate.
Claim 12
Dependent Claim
18 words
The method according to claim 1 in which said drying oil resin or ester is an alkyd resin.
References Cited (Backward Citations)
US2613162A
Cited
FR1041465A
Cited
GB720176A
Cited
FR1047465A
Cited
GB734675A
Cited
GB740251A
Cited
GB804981A
Cited
US2871135A
Cited
GB848270A
Cited
US3196118A
Cited
US3242196A
Cited
US3755189A
Cited
US4090886A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-27 | 1984-10-27 | 1985-04-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-27 | 1988-10-27 | 1989-04-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-27 | 1992-10-27 | 1993-04-28 | $7700.00 | Window Closed / Lapsed |