← Back to Patent Explorer
US4264370A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for preparing aluminum-based air drying compositions

Assignee: Manchem Ltd
•
Filing: 1978-02-21
•
Granted: 1981-04-28
•
Expires: 1998-02-21
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Method for preparing storage-stable air-drying compositions containing a combination of an aluminum alkoxide with a labile monofunctional reactant such as an alkanol, alkoxyalkanol, keto ester, water, hydrogen peroxide, organic hydroperoxide or mixtures thereof.

Inventors

  • 👤 John H. W. Turner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:43
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/05; C08K5/057

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 186 words
In a method for forming a storage-stable composition by addition of an alkoxyaluminum compound to a drying oil resin or ester containing hydroxyl or carboxyl groups, the improvement which comprises adding to and reacting under ambient conditions with said alkoxyaluminum compound at least one gram mole of a labile monofunctional reactant per gram atom of aluminum in said alkoxyaluminum compound prior to addition of said alkoxyaluminum compound to said drying oil resin or ester, thereby forming a fluid, storage-stable mixture which is resistant to gelation until said labile monofunctional reactant is released from said mixture by evaporation or hydrolysis, wherein said labile monofunctional reactant is selected from the group consisting of lower alkanols having up to about eight carbon atoms, tert-butyl hydroperoxide, cumenyl hydroperoxide, water, hydrogen peroxide, and mixtures thereof and wherein said alkoxyaluminum compound has the formula ##STR4## in which R is selected from the group consisting of lower alkyl, lower cycloalkyl, and lower alkoxyalkyl, and each of said A and B is selected from the group consisting of OR and 2-ethylhexoate, 3,5,5-trimethylhexoate, versatate, naphthenate, acid monoisopropyl phthalate, acid monoethoxyethoxyl maleate, ethyl acetoacetate, and acetylacetone.
Claim 2
Dependent Claim 186 words
In a method for forming a storage-stable composition by addition of an alkoxyaluminum compound to a drying oil resin or ester containing hydroxyl or carboxyl groups, the improvement which comprises adding to and reacting under ambient conditions with said alkoxyaluminum compound at least one gram mole of a labile monofunctional reactant per gram atom of aluminum in said alkoxyaluminum compound prior to addition of said alkoxyaluminum compound to said drying oil resin or ester, thereby forming a fluid, storage-stable mixture which is resistant to gelation until said labile monofunctional reactant is released from said mixture by evaporation or hydrolysis, wherein said labile monofunctional reactant is selected from the group consisting of lower alkanols having up to about eight carbon atoms, tert-butyl hydroperoxide, cumenyl hydroperoxide, water, hydrogen peroxide, and mixtures thereof and wherein said alkoxyaluminum compound has the formula ##STR4## in which R is selected from the group consisting of lower alkyl, lower cycloalkyl, and lower alkoxyalkyl, and each of said A and B is selected from the group consisting of OR and 2-ethylhexoate, 3,5,5-trimethylhexoate, versatate, naphthenate, acid monoisopropyl phthalate, acid monoethoxyethoxyl maleate, ethyl acetoacetate, and acetylacetone.
Claim 3
Dependent Claim 14 words
The method according to claim 1 in which said labile monofunctional reactant is ethoxyethanol.
Claim 4
Dependent Claim 14 words
The method according to claim 1 in which said labile monofunctional reactant is isopropanol.
Claim 5
Dependent Claim 20 words
The method according to claim 1 in which said labile monofunctional reactant is a mixture of hydrogen peroxide and ethoxyethanol.
Claim 6
Dependent Claim 15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoisopropoxide monoversatate(monoisopropyl)phthalate.
Claim 7
Dependent Claim 15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum diethoxyethoxide monoversatate.
Claim 8
Dependent Claim 14 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum triethoxyethoxide.
Claim 9
Dependent Claim 16 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoisopropoxide monoethyoxyethoxide monoethylacetoacetate.
Claim 10
Dependent Claim 15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum diethoxyethoxide monoacetylacetonate.
Claim 11
Dependent Claim 15 words
The method according to claim 1 in which said alkoxyaluminum compound is aluminum monoethoxyethoxide diacetylacetonate.
Claim 12
Dependent Claim 18 words
The method according to claim 1 in which said drying oil resin or ester is an alkyd resin.

References Cited (Backward Citations)

US2613162A Cited
FR1041465A Cited
GB720176A Cited
FR1047465A Cited
GB734675A Cited
GB740251A Cited
GB804981A Cited
US2871135A Cited
GB848270A Cited
US3196118A Cited
US3242196A Cited
US3755189A Cited
US4090886A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-27 1984-10-27 1985-04-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-27 1988-10-27 1989-04-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-27 1992-10-27 1993-04-28 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag