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US4263362A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating composition for glass fibers and coated glass fibers made from same

Assignee: PPG Industries Inc
•
Filing: 1979-11-23
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Granted: 1981-04-21
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Expires: 1999-11-23
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Abstract

Abstract A coating composition for producing coated glass fiber strands and the coated glass fiber strands are provided, where the coated strands have good knot tensile strength and improved processability. The coating composition has a carboxylated elastomeric latex, an elastomeric plasticizer, a hydrophilic/lipophilic agent, an antioxidant, wax emulsion, anti-foaming agent, tertiary amine, polyhydroxylated glycol, and a pH in the range of about 8.7 to about 9.5. The coated glass fiber strand has the aforementioned coating in an amount of about 10 to about 20 (LOI) loss on ignition.

Inventors

  • 👤 Daniel C. Straka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:07
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; D; D03; D03D; D03D15/00; D03D15/20; D03D15/242; D03D15/267; D21; D21F; D21F1/00; D21F1/0027; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2915; Y10T428/2933; Y10T428/2938; Y10T428/2964; Y10T428/2967; Y10T442/00; Y10T442/30; Y10T442/3049

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 96 words
An elastomeric coating composition for glass fibers to produce weaveable coated glass fiber strands with improved processability, having in weight percent on an aqueous basis: (a) about 1 to about 15 elastomeric plasticizer, (b) about 10 to about 40 carboxylated elastomeric latex, (c) about 0.1 to about 2 hydrophilic/lipophilic agent, (d) about 0.05 to about 0.5 antioxidant, (e) about 0.1 to about 2 wax emulsion, (f) about 0.05 to about 0.5 amine, (g) about 0.05 to about 2 polyhydroxylated glycol wherein the coating composition has a pH in the range of about 8.7 to about 9.5.
Claim 2
Dependent Claim 96 words
An elastomeric coating composition for glass fibers to produce weaveable coated glass fiber strands with improved processability, having in weight percent on an aqueous basis: (a) about 1 to about 15 elastomeric plasticizer, (b) about 10 to about 40 carboxylated elastomeric latex, (c) about 0.1 to about 2 hydrophilic/lipophilic agent, (d) about 0.05 to about 0.5 antioxidant, (e) about 0.1 to about 2 wax emulsion, (f) about 0.05 to about 0.5 amine, (g) about 0.05 to about 2 polyhydroxylated glycol wherein the coating composition has a pH in the range of about 8.7 to about 9.5.
Claim 3
Dependent Claim 13 words
The composition of claim 1, wherein the elastomeric latex plasticizer is polybutadiene homopolymer.
Claim 4
Dependent Claim 15 words
The coating composition of claim 1, wherein the carboxylated elastomeric latex is carboxylated styrene-butadiene copolymer.
Claim 5
Dependent Claim 12 words
The composition of claim 1, wherein the hydrophilic/lipophilic agent is a phenoxypoly(ethyleneoxy)ethanol.
Claim 6
Dependent Claim 14 words
The composition of claim 1, wherein the antioxidant is a styrene phenol reaction product.
Claim 7
Dependent Claim 13 words
The composition of claim 1, wherein the wax emulsion is a microcrystalline wax.
Claim 8
Dependent Claim 10 words
The composition of claim 1, wherein the amine is triethanolamine.
Claim 9
Dependent Claim 11 words
The composition of claim 1, wherein the polyhydroxylated glycol is glycerol.
Claim 10
Dependent Claim 21 words
The composition of claim 1 having aqueous ammonia to adjust the pH within the range of about 8.7 to about 9.5.
Claim 11
Dependent Claim 11 words
Coated glass fiber strand having the coating composition of claim 1.
Claim 12
Dependent Claim 27 words
The composition of claim 1 wherein the carboxylated elastomeric latex is replaced in an amount of up to one-half the amount present by a non-carboxylated elastomeric latex.
Claim 13
Dependent Claim 22 words
The composition of claim 1 having present an organic dye in an amount in the range of about 0.25 to about 0.75.
Claim 14
Dependent Claim 9 words
Glass fibers coated with the composition of claim 1.
Claim 15
Dependent Claim 112 words
A coated, sized, glass fiber strand produced in a facile operation and having good weaveability having a coating comprised of the dried residue of a composition, comprising in weight percent on an aqueous basis: (a) about 5 to about 15 of polybutadiene, (b) about 10 to about 40 of carboxylated styrene butadiene copolymer latex, (c) about 0.25 to about 1 octylphenoxypoly(ethyleneoxy) ethanol, (d) about 0.05 to about 0.3 styrene phenol reaction product antioxidant, (e) about 0.5 to about 1 microcrystalline wax emulsion, (f) about 0.1 to about 0.25 triethanolamine, (g) about 0.1 to about 0.2 glycerol wherein the composition is adjusted to a pH of 8.7 to about 9.5 with aqueous ammonia.
Claim 16
Dependent Claim 112 words
A coated, sized, glass fiber strand produced in a facile operation and having good weaveability having a coating comprised of the dried residue of a composition, comprising in weight percent on an aqueous basis: (a) about 5 to about 15 of polybutadiene, (b) about 10 to about 40 of carboxylated styrene butadiene copolymer latex, (c) about 0.25 to about 1 octylphenoxypoly(ethyleneoxy) ethanol, (d) about 0.05 to about 0.3 styrene phenol reaction product antioxidant, (e) about 0.5 to about 1 microcrystalline wax emulsion, (f) about 0.1 to about 0.25 triethanolamine, (g) about 0.1 to about 0.2 glycerol wherein the composition is adjusted to a pH of 8.7 to about 9.5 with aqueous ammonia.
Claim 17
Dependent Claim 20 words
Woven carpet wherein the weft yarn is composed of the coated glass fiber strands of claim 13 or claim 14.
Claim 18
Dependent Claim 30 words
Drier belt for use in conveying wet material through a drier wherein the weft and warp yarn are composed of coated glass fiber strands of claim 13 or claim 14.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-20 1984-10-20 1985-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-20 1988-10-20 1989-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-20 1992-10-20 1993-04-21 $7700.00 Window Closed / Lapsed

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