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US4262083A Expired / Lapsed US ⏱️ 0.0 years remaining

Positive resist for electron beam and x-ray lithography and method of using same

Assignee: Intersil Corp
•
Filing: 1979-09-18
•
Granted: 1981-04-14
•
Expires: 1999-09-18
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Abstract

Abstract Copolymers of an aziridine and sulfur dioxide are disclosed which are useful as positive radiation resists for use in electron beam and x-ray lithography.

Inventors

  • 👤 Thomas R. Pampalone
  • 👤 Nitin V. Desai
  • 👤 Eugene S. Poliniak

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:49
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/30; G; G03; G03F; G03F7/00; G03F7/004; G03F7/039; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/122; Y10S430/123; Y10S430/167; Y10S430/168; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 123 words
The method of forming a predetermined surface relief pattern in a film of a resist material, said method comprising the steps of (a) providing a film of a positive resist material which is comprised of a copolymer of (1) an aziridine monomer of the formula ##STR3## wherein R 1 -R 5 are the same or different and are members selected from the group consisting of hydrogen, alkyl, aralkyl and aryl, and (2) sulfur dioxide on a substrate, (b) exposing a portion of the film corresponding to said predetermined pattern to radiation which changes the solubility of the exposed portion with respect to the unexposed portion, and (c) dissolving the more soluble portion of the film in a developer to provide said relief pattern.
Claim 2
Independent Claim 123 words
The method of forming a predetermined surface relief pattern in a film of a resist material, said method comprising the steps of (a) providing a film of a positive resist material which is comprised of a copolymer of (1) an aziridine monomer of the formula ##STR3## wherein R 1 -R 5 are the same or different and are members selected from the group consisting of hydrogen, alkyl, aralkyl and aryl, and (2) sulfur dioxide on a substrate, (b) exposing a portion of the film corresponding to said predetermined pattern to radiation which changes the solubility of the exposed portion with respect to the unexposed portion, and (c) dissolving the more soluble portion of the film in a developer to provide said relief pattern.
Claim 3
Dependent Claim 26 words
The method according to claim 1 wherein the alkyl has 1-12 carbon atoms, the aralkyl has 7-12 carbon atoms and the aryl has 6-12 carbon atoms.
Claim 4
Dependent Claim 26 words
The method according to claim 1 wherein R 1 -R 5 are selected from the group consisting of hydrogen and lower alkyl having 1-4 carbon atoms.
Claim 5
Dependent Claim 34 words
The method according to claim 3 wherein said radiation is an x-ray radiation and at least one of the substituents R 1 -R 5 is a lower alkyl which is substituted with a halogen.
Claim 6
Dependent Claim 11 words
The method according to claim 4 wherein the halogen is chlorine.
Claim 7
Dependent Claim 18 words
The method according to claim 1 wherein said radiation is in the form of a beam of electrons.
Claim 8
Dependent Claim 11 words
The method according to claim 1 wherein the radiation is x-rays.
Claim 9
Dependent Claim 13 words
The exposed developed film prepared in accordance with the process of claim 1.

References Cited (Backward Citations)

US3893127A Cited
US3884696A Cited
US3898350A Cited
US3935332A Cited
US3935331A Cited
US4061829A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-04-13 1984-10-13 1985-04-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-04-13 1988-10-13 1989-04-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-04-13 1992-10-13 1993-04-14 $7700.00 Window Closed / Lapsed

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