Patent US4261880A successfully refreshed from Google Patents.
US4261880A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyolefin resin compositions
Assignee: Mitsubishi Chemical Corp
•
Filing: 1978-11-24
•
Granted: 1981-04-14
•
Expires: 1998-11-24
Abstract
Abstract Improvement in the weathering properties of polyolefin resins has been achieved by intimate compositions comprising Ziegler-process crystalline polyolefins containing halogen-magnesium compounds as catalytic carrier residues, and organic phosphorus compounds such as organic phosphites. The compositions may contain auxiliary components normally used in polyolefin resins; antioxidants and/or ultraviolet absorbers are especially useful.
Inventors
- 👤 Masaki Fujii
- 👤 Akiyoshi Onishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 19:22
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/52; C08K5/524; C08K5/5398
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
355 words
A polyolefin resin composition improved in weathering properties, comprising, as an intimate admixture: (1) a crystalline polyolefin resin which has been produced in the presence of a Ziegler type complex catalyst supported on a halogen-containing magnesium compound and has not yet been subjected to a catalyst residue-removal step; and (2) an organic phosphorus compound in the amount of from 0.1 to 1,000 times the weight of the halogen-containing magnesium compound contained in the crystalline polyolefin resin, the organic phosphorus compound being selected from the group consisting of: (i) a compound of the formula (R 1 O) 3 P, wherein R 1 is hydrogen, an alkyl group having from 1 to 20 carbon atoms, an aryl or alkaryl group having from 6 to 20 carbon atoms, an aralkyl group having from 7 to 30 carbon atoms, or hydroxy-, halo- or alkylthio-substituted derivatives thereof wherein the alkyl moiety has 1 to 30 carbon atoms, and wherein the three R 1 groups are the same or different; (ii) a compound of the formula, (R 2 O) 2 P--O--L--O--P(OR 2 ) 2 , wherein R 2 has the same definition as the above-mentioned R 1 , the four R 2 s being the same or different, and L is a divalent hydrocarbon residue having from 2 to 30 carbon atoms with or without an ether linkage contained therein; (iii) a compound of the formula ##STR7## wherein R 3 has the same definition as the above-mentioned R 1 , the six R 3 s being the same or different, and X is a trivalent hydrocarbon residue having from 3 to 40 carbon atoms with or without an ether linkage contained therein; (iv) a compound of the formula ##STR8## wherein R 4 has the same definition as the above-mentioned R 1 , to two R 4 s being the same or different, and Y is a tetravalent hydrocarbon residue having 5 carbon atoms; (v) a compound of the formula (R 5 S) 3 P, wherein R 5 has the same definition as the above-mentioned R 1 , the three R 5 s being the same or different; and (vi) mixtures thereof.
Claim 2
Dependent Claim
355 words
A polyolefin resin composition improved in weathering properties, comprising, as an intimate admixture: (1) a crystalline polyolefin resin which has been produced in the presence of a Ziegler type complex catalyst supported on a halogen-containing magnesium compound and has not yet been subjected to a catalyst residue-removal step; and (2) an organic phosphorus compound in the amount of from 0.1 to 1,000 times the weight of the halogen-containing magnesium compound contained in the crystalline polyolefin resin, the organic phosphorus compound being selected from the group consisting of: (i) a compound of the formula (R 1 O) 3 P, wherein R 1 is hydrogen, an alkyl group having from 1 to 20 carbon atoms, an aryl or alkaryl group having from 6 to 20 carbon atoms, an aralkyl group having from 7 to 30 carbon atoms, or hydroxy-, halo- or alkylthio-substituted derivatives thereof wherein the alkyl moiety has 1 to 30 carbon atoms, and wherein the three R 1 groups are the same or different; (ii) a compound of the formula, (R 2 O) 2 P--O--L--O--P(OR 2 ) 2 , wherein R 2 has the same definition as the above-mentioned R 1 , the four R 2 s being the same or different, and L is a divalent hydrocarbon residue having from 2 to 30 carbon atoms with or without an ether linkage contained therein; (iii) a compound of the formula ##STR7## wherein R 3 has the same definition as the above-mentioned R 1 , the six R 3 s being the same or different, and X is a trivalent hydrocarbon residue having from 3 to 40 carbon atoms with or without an ether linkage contained therein; (iv) a compound of the formula ##STR8## wherein R 4 has the same definition as the above-mentioned R 1 , to two R 4 s being the same or different, and Y is a tetravalent hydrocarbon residue having 5 carbon atoms; (v) a compound of the formula (R 5 S) 3 P, wherein R 5 has the same definition as the above-mentioned R 1 , the three R 5 s being the same or different; and (vi) mixtures thereof.
Claim 3
Dependent Claim
47 words
The polyolefin resin composition as set forth in claim 1, in which the crystalline polyolefin resin is selected from crystalline homopolyolefins, crystalline olefin copolymers consisting essentially of at least two olefin monomers, and crystalline olefin copolymers consisting essentially of an olefin monomer and a monomer copolymerizable therewith.
Claim 4
Dependent Claim
30 words
The polyolefin resin composition as set forth in claim 2, in which the crystalline polyolefin resin is selected from the group consisting of polyethylene, polypropylene, polybutene-1, poly-4-methylpentene-1, and ethylene-propylene copolymers.
Claim 5
Dependent Claim
66 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the halogen-containing magnesium compound is selected from the group consisting of magnesium dihalides, oxymagnesium halides, derivatives of oxymagnesium halides wherein the halide has been partly converted to a magnesium dihalide by treating the halide with an alkylaluminium dihalide, and magnesium dihalide complexes obtained by treating the dihalide with an electron-donor compound.
Claim 6
Dependent Claim
22 words
The polyolefin resin composition as set forth in claim 1, 2, or 3, in which the halogen-containing magnesium compound is magnesium dichloride.
Claim 7
Dependent Claim
61 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the organic phosphorus compound is one having said formula (R 1 O) 3 P and is selected from the group consisting of trimethylphosphite, tri-n-butylphosphite, tridecylphosphite, tris(2-ethylhexyl)phosphite, trinonylphosphite, tricetylphosphite, dilauryl hydrogen phosphite, tricyclohexylphosphite, triphenylphosphite, tribenzylphosphite, tricresylphosphite, tri-p-nonylphenylphosphite, diphenyldecylphosphite, tris(dinonylphenyl)phosphite, tris(2,4-di-t-butylphenyl)phosphite, tris(4-α-methylbenzylphenyl)phosphite, tris(octylthioethyl)phosphite, tris(octylthiopropyl)phosphite, tris(cresylthiopropyl)phosphite, and mixtures thereof.
Claim 8
Dependent Claim
45 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the organic phosphorus compound is one having said formula (R 2 O) 2 P--O--L--O--P(OR 2 ) 2 and is selected from the group consisting of tetraphenyldipropyleneglycoldiphosphite, 1,1-bis{3-t-butyl-4-[bis(tridecyloxy)phosphino-oxy]-6-methylphenyl}butane, and mixtures thereof.
Claim 9
Dependent Claim
28 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the organic phosphorus compound is one having said formula ##STR9## and is 1,1,3-tris{3-t-butyl-4[bis(tridecyloxy)phosphino-oxy]-6-methylphenyl}butane.
Claim 10
Dependent Claim
39 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the organic phosphorus compound is one having said formula ##STR10## and is selected from the group consisting of bis(2-chloropropyl)pentaerythritoldiphosphite, bisphenylpentaerythritoldiphosphite, bisstearylpentaerythritoldiphosphite, and mixtures thereof.
Claim 11
Dependent Claim
32 words
The polyolefin resin composition as set forth in claim 1, 2 or 3, in which the organic phosphorus compound is one having said formula (R 5 S) 3 P and is trilauryltrithiophosphite.
Claim 12
Dependent Claim
28 words
The polyolefin resin composition as set forth in claim 1, 2 or 3 in which the molecular weight of the organic phosphorus compound is more than about 230.
Claim 13
Dependent Claim
43 words
The polyolefin resin composition as set forth in claim 1, 2 or 3 in which the quantity of the organic phosphorus compound is about 0.5 to about 100 times the quantity by weight of the halogen-containing magnesium compound contained in the polyolefin resin.
Claim 14
Dependent Claim
40 words
The polyolefin resin composition as set forth in claim 1, 2 or 3 in which the composition further contains one or more auxiliary additives selected from antioxidants, ultraviolet absorbers, antistatic agents, slip agents, flame retardants, anti-blocking agents, fillers and pigments.
Claim 15
Dependent Claim
32 words
The polyolefin resin composition as set forth in claim 13, in which the antioxidant is selected from the group consisting of 2,6-di-t-butyl-p-cresol, tetrakis[methylene-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate]methane, 4,4'-butylidene-bis(6-t-butyl-m-cresol), 1,1,3-tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane, 4,4'-thio-bis(2-t-butyl-m-cresol); dilauryl-thio-dipropionate, laurylstearyl-thio-dipropionate, distearyl-thio-dipropionate, dimyristyl-thio-dipropionate; and 2,2,4-trimethyl-1,2-dihydroquinoline.
Claim 16
Dependent Claim
21 words
The polyolefin resin composition as set forth in claim 13, in which the ultraviolet absorber is selected from 2-(2'-hydroxy-3',5'-di-t-butylphenyl)-5-chlorobenzotriazole, and 2-hydroxy-4-n-octoxy-benzophenone.
Claim 17
Independent Claim
354 words
A method for improving the weathering properties of a crystalline polyolefin resin, wherein said polyolefin resin has been prepared in the presence of a Ziegler-type complex catalyst supported on a halogen-containing magnesium compound which comprises intimately mixing said crystalline polyolefin resin, without subjecting said resin to a catalyst residue-removal step, with an organic phosphorus compound in the amount of from 0.1 to 1,000 times the weight of the halogen-containing magnesium compound contained in the crystalline polyolefin resin, the organic phosphorus compound being selected from the group consisting of: (i) a compound of the formula (R 1 O) 3 P, wherein R 1 is hydrogen, an alkyl group having from 1 to 20 carbon atoms, an aryl or alkaryl group having from 6 to 20 carbon atoms, an aralkyl group having from 7 to 30 carbon atoms, or hydroxy-, halo- or alkylthio-substituted derivatives thereof wherein the alkyl moiety has 1 to 30 carbon atoms, the three R 1 groups being the same or different; (ii) a compound of the formula, (R 2 O) 2 P--O--L--O--P(OR 2 ) 2 , wherein R 2 has the same definition as the above-mentioned R 1 , the four R 2 s being the same or different, and L is a divalent hydrocarbon residue having from 2 to 30 carbon atoms with or without an ether linkage contained therein, (iii) a compound of the formula, ##STR11## wherein R 3 has the same definition as the above-mentioned R 1 , the six R 3 s being the same or different, and X is a trivalent hydrocarbon residue having from 3 to 40 carbon atoms with or without an ether linkage contained therein; (iv) a compound of the formula ##STR12## wherein R 4 has the same definition as the above-mentioned R 1 , the two R 4 s being the same or different, and Y is a tetravalent hydrocarbon residue having 5 carbon atoms; (v) a compound of the formula (R 5 S) 3 P, wherein R 5 has the same definition as the above-mentioned R 1 , the three R 5 s being the same or different; and (vi) mixtures thereof.
Claim 18
Independent Claim
354 words
A method for improving the weathering properties of a crystalline polyolefin resin, wherein said polyolefin resin has been prepared in the presence of a Ziegler-type complex catalyst supported on a halogen-containing magnesium compound which comprises intimately mixing said crystalline polyolefin resin, without subjecting said resin to a catalyst residue-removal step, with an organic phosphorus compound in the amount of from 0.1 to 1,000 times the weight of the halogen-containing magnesium compound contained in the crystalline polyolefin resin, the organic phosphorus compound being selected from the group consisting of: (i) a compound of the formula (R 1 O) 3 P, wherein R 1 is hydrogen, an alkyl group having from 1 to 20 carbon atoms, an aryl or alkaryl group having from 6 to 20 carbon atoms, an aralkyl group having from 7 to 30 carbon atoms, or hydroxy-, halo- or alkylthio-substituted derivatives thereof wherein the alkyl moiety has 1 to 30 carbon atoms, the three R 1 groups being the same or different; (ii) a compound of the formula, (R 2 O) 2 P--O--L--O--P(OR 2 ) 2 , wherein R 2 has the same definition as the above-mentioned R 1 , the four R 2 s being the same or different, and L is a divalent hydrocarbon residue having from 2 to 30 carbon atoms with or without an ether linkage contained therein, (iii) a compound of the formula, ##STR11## wherein R 3 has the same definition as the above-mentioned R 1 , the six R 3 s being the same or different, and X is a trivalent hydrocarbon residue having from 3 to 40 carbon atoms with or without an ether linkage contained therein; (iv) a compound of the formula ##STR12## wherein R 4 has the same definition as the above-mentioned R 1 , the two R 4 s being the same or different, and Y is a tetravalent hydrocarbon residue having 5 carbon atoms; (v) a compound of the formula (R 5 S) 3 P, wherein R 5 has the same definition as the above-mentioned R 1 , the three R 5 s being the same or different; and (vi) mixtures thereof.
References Cited (Backward Citations)
US3013003A
Cited
US3119783A
Cited
US3039993A
Cited
US3188298A
Cited
US3244667A
Cited
US3476699A
Cited
US3322718A
Cited
US3405089A
Cited
US3256237A
Cited
GB1146379A
Cited
US3830787A
Cited
US4184987A
Cited
US3962203A
Cited
US4120820A
Cited
US4130503A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-13 | 1984-10-13 | 1985-04-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-13 | 1988-10-13 | 1989-04-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-13 | 1992-10-13 | 1993-04-14 | $7700.00 | Window Closed / Lapsed |