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US4258208A
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Preparation of esters from organic bromo alkyl tellurium compounds
Assignee: Lyondell Chemical Technology LP
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Filing: 1979-07-23
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Granted: 1981-03-24
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Expires: 1999-07-23
Abstract
Abstract A process for the preparation of 2-bromoalkyl esters and vicinal glycol esters which comprises thermally decomposing at temperatures of from 100° C. to 200° C. an organic bromoalkyl tellurium compound selected from 2-bromoalkyltellurium tribromide or bis(2-bromoalkyl)tellurium dibromide, wherein the alkyl group is ethyl, propyl or butyl, in a carboxylic acid having from 1 to 4 carbon atoms which is employed as solvent as well as to supply the ester moiety to the esters produced. The esters may be converted to the respective glycol with water or an aqueous base.
Inventors
- 👤 Jar-Lin Kao
- 👤 Ming N. Sheng
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:52
CPC Classifications
C; C07; C07C; C07C67/00
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
100 words
A process for the preparation of 2-bromoalkyl esters which comprises thermally decomposing, at a temperature in the range of from about 100° C. to 200° C., an organic bromo alkyltellurium compound selected from 2-bromoalkyltellurium tribromide having the formula ##STR4## and bis(2-bromoalkyl)tellurium dibromide having the formula ##STR5## or mixtures thereof, wherein R is hydrogen or a methyl group, at least one R being hydrogen, in the presence of a lower aliphatic monocarboxylic acid selected from the group consisting of formic, acetic, propionic, butyric and isobutyric acid and in the absence of oxygen or an oxygen-containing gas and recovering the desired ester.
Claim 2
Dependent Claim
100 words
A process for the preparation of 2-bromoalkyl esters which comprises thermally decomposing, at a temperature in the range of from about 100° C. to 200° C., an organic bromo alkyltellurium compound selected from 2-bromoalkyltellurium tribromide having the formula ##STR4## and bis(2-bromoalkyl)tellurium dibromide having the formula ##STR5## or mixtures thereof, wherein R is hydrogen or a methyl group, at least one R being hydrogen, in the presence of a lower aliphatic monocarboxylic acid selected from the group consisting of formic, acetic, propionic, butyric and isobutyric acid and in the absence of oxygen or an oxygen-containing gas and recovering the desired ester.
Claim 3
Dependent Claim
23 words
A process according to claim 1 wherein the organic bromoalkyltellurium compound is selected from 2-bromoethyltellurium tribromide, bis(2-bromoethyl)tellurium dibromide, bis(2-bromopropyl)tellurium dibromide and bis(2-bromobutyl)-tellurium dibromide.
Claim 4
Dependent Claim
25 words
A process according to claim 1 wherein the reaction is carried out in the presence of acetonitrile as solvent in addition to the monocarboxylic acid.
Claim 5
Dependent Claim
27 words
A process according to claim 1 wherein the decomposition reaction is carried out at a temperature in the range of from about 135° C. to 175° C.
Claim 6
Dependent Claim
38 words
A process for the preparation of 2-bromoethylacetate which comprises thermally decomposing at a temperature of between about 135° C. to 175° C. 2-bromoethyltellurium tribromide in an acetic acid medium in the absence of oxygen or an oxygen-containing gas.
Claim 7
Dependent Claim
38 words
A process for the preparation of 2-bromoethylacetate which comprises thermally decomposing at a temperature of between about 135° C. to 175° C. 2-bromoethyltellurium tribromide in an acetic acid medium in the absence of oxygen or an oxygen-containing gas.
Claim 8
Dependent Claim
38 words
A process for the preparation of 2-bromoethylacetate which comprises thermally decomposing at a temperature of between about 135° C. to 175° C. bis(2-bromoethyl)tellurium dibromide in an acetic acid medium in the absence of oxygen or an oxygen-containing gas.
Claim 9
Dependent Claim
38 words
A process for the preparation of 2-bromoethylacetate which comprises thermally decomposing at a temperature of between about 135° C. to 175° C. bis(2-bromoethyl)tellurium dibromide in an acetic acid medium in the absence of oxygen or an oxygen-containing gas.
References Cited (Backward Citations)
US3668239A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-23 | 1984-09-22 | 1985-03-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-23 | 1988-09-22 | 1989-03-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-23 | 1992-09-22 | 1993-03-24 | $7700.00 | Window Closed / Lapsed |