Patent US4256624A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4256624A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester of 6-hydroxy-2-naphthoic acid, aromatic diol, and aromatic diacid capable of undergoing melt processing

Assignee: Celanese Corp
•
Filing: 1979-07-02
•
Granted: 1981-03-17
•
Expires: 1999-07-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A novel polyester is provided which has been found to exhibit an optically anisotropic melt phase which enables it readily to undergo melt processing to form quality fibers, films, molded articles, etc. The polyester of the present invention contains recurring 6-oxy-2-naphthoyl moieties in addition to moieties derived from at least one aromatic diol and at least one aromatic diacid in the proportions indicated. The hydrogen atoms present upon the aromatic rings of these moieties optionally may be at least partially substituted (as described). The wholly aromatic polyester is capable of forming the desired anisotropic melt at a temperature below approximately 400° C., and in a particularly preferred embodiment at a temperature below approximately 320° C.

Inventors

  • 👤 Gordon W. Calundann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 10:37
CPC Classifications
D; D01; D01F; D01F6/00; D01F6/78; D01F6/84; C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/605

Claims Analysis

Total Claims: 38
Claim 1
Independent Claim 169 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is ##STR12## II is a dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula ##STR13## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III.
Claim 2
Dependent Claim 169 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 400° C. consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is ##STR12## II is a dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxy aryl moiety of the formula ##STR13## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III.
Claim 3
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 350° C.
Claim 4
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 320° C.
Claim 5
Dependent Claim 25 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety II and said dicarboxy aryl moiety III are symmetrically disposed.
Claim 6
Dependent Claim 26 words
A melt processable wholly aromatic polyester according to claim 1 wherein said dioxy aryl moiety II is ##STR14## and said dicarboxy aryl moiety III is ##STR15##
Claim 7
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 1 wherein each moiety is substantially free of ring substitution.
Claim 8
Dependent Claim 40 words
A melt processable wholly aromatic polyester according to claim 1 which comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.
Claim 9
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 10
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 11
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 1 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 12
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 1.
Claim 13
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 1.
Claim 14
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 1.
Claim 15
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 16
Dependent Claim 171 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is ##STR16## II is a symmetrical dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a symmetrical dicarboxy aryl moiety of the formula ##STR17## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.
Claim 17
Dependent Claim 171 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is ##STR16## II is a symmetrical dioxy aryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, and III is a symmetrical dicarboxy aryl moiety of the formula ##STR17## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.
Claim 18
Dependent Claim 30 words
A melt processable wholly aromatic polyester according to claim 15 wherein said symmetrical dioxy aryl moiety II is selected from the group consisting of: ##STR18## and mixtures of the foregoing.
Claim 19
Dependent Claim 30 words
A melt processable wholly aromatic polyester according to claim 15 wherein said symmetrical dicarboxy aryl moiety III is selected from the group consisting of: ##STR19## and mixtures of the foregoing.
Claim 20
Dependent Claim 19 words
A melt processable wholly aromatic polyester according to claim 15 wherein each moiety is substantially free of ring substitution.
Claim 21
Dependent Claim 40 words
A melt processable wholly aromatic polyester according to claim 15 which comprises approximately 60 to 80 mole percent of moiety I, approximately 10 to 20 mole percent of moiety II, and approximately 10 to 20 mole percent of moiety III.
Claim 22
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 15 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 23
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 15 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 24
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 15 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 25
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 15.
Claim 26
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 15.
Claim 27
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 15.
Claim 28
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 15 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 29
Dependent Claim 73 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, and III wherein: ##STR20## said moieties being substantially free of ring substitution, and wherein said polyester comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.
Claim 30
Dependent Claim 73 words
A melt processable wholly aromatic polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, and III wherein: ##STR20## said moieties being substantially free of ring substitution, and wherein said polyester comprises approximately 20 to 80 mole percent of moiety I, approximately 10 to 40 mole percent of moiety II, and approximately 10 to 40 mole percent of moiety III.
Claim 31
Dependent Claim 40 words
A melt processable wholly aromatic polyester according to claim 27 which comprises approximately 60 to 80 mole percent of moiety I, approximately 10 to 20 mole percent of moiety II, and approximately 10 to 20 mole percent of moiety III.
Claim 32
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 27 which exhibits an inherent viscosity of at least 2.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 33
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 27 which exhibits an inherent viscosity of at least 3.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 34
Dependent Claim 34 words
A melt processable wholly aromatic polyester according to claim 27 which exhibits an inherent viscosity of 3.5 to 7.5 when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 35
Dependent Claim 15 words
A fiber which has been melt spun from the wholly aromatic polyester of claim 27.
Claim 36
Dependent Claim 15 words
A film which has been melt extruded from the wholly aromatic polyester of claim 27.
Claim 37
Dependent Claim 13 words
A molded article comprising the melt processable wholly aromatic polyester of claim 27.
Claim 38
Dependent Claim 29 words
A molding compound comprising the melt processable wholly aromatic polyester of claim 27 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.

References Cited (Backward Citations)

US3778410A Cited
US4067852A Cited
US4083829A Cited
US4169933A Cited
US4161470A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-16 1984-09-15 1985-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-16 1988-09-15 1989-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-16 1992-09-15 1993-03-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag