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US4256560A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable resinous compositions useful in coating applications

Assignee: PPG Industries Inc
•
Filing: 1979-09-19
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Granted: 1981-03-17
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Expires: 1999-09-19
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Abstract

Abstract Curable resinous compositions containing primary and/or secondary amine groups which are non-volatile under curing conditions and containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties which are reacted with a primary and/or secondary amine which are volatile under curing conditions are disclosed. The compositions are depositable on a substrate to form films.

Inventors

  • 👤 Stephen L. Buchwalter
  • 👤 Robert D. Jerabek
  • 👤 Lee-Pei H. Chou
  • 👤 Roger M. Christenson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 18:59
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/14; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G59/50; C09D133/24; C09D133/26; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4453; C08L; C08L63/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 102 words
A method of coating an electrically conductive surface serving as a cathode which comprises passing electric current between said cathode and an anode immersed in an aqueous dispersion of an electrodepositable curable resinous composition, comprising as the resinous binder: (A) a polyamine resin containing primary and/or secondary amino groups, said polyamine resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous binder being neutralized with acid to provide cationic salt groups.
Claim 2
Independent Claim 102 words
A method of coating an electrically conductive surface serving as a cathode which comprises passing electric current between said cathode and an anode immersed in an aqueous dispersion of an electrodepositable curable resinous composition, comprising as the resinous binder: (A) a polyamine resin containing primary and/or secondary amino groups, said polyamine resin being stable under curing conditions; and (B) a Michael adduct of an organic material containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties reacted with primary and/or secondary amines, said Michael adduct being unstable under curing conditions; said resinous binder being neutralized with acid to provide cationic salt groups.
Claim 3
Dependent Claim 19 words
The method of claim 1 in which the polyamine resin is a poly(amine-amide) having a terminal primary amine group.
Claim 4
Dependent Claim 23 words
The method of claim 1 in which the polyamine resin is the reaction product of an epoxy-containing resinous material and a primary amine.
Claim 5
Dependent Claim 27 words
The method of claim 1 in which the polyamine resin is the reaction product of an epoxy-containing resinous material and a polyamine containing ketimine-blocked primary amine groups.
Claim 6
Dependent Claim 29 words
The method of claim 1 in which (B) is formed from reacting an organic polyol with acrylic or methacrylic acid followed by reaction with a primary and/or secondary amine.
Claim 7
Dependent Claim 30 words
The method of claim 1 in which (B) is formed from reacting an epoxy-containing resinous material with acrylic or methacrylic acid followed by reaction with a primary and/or secondary amine.
Claim 8
Dependent Claim 30 words
The method of claim 1 in which (B) is formed from reacting a polymeric polyol with an N-alkoxymethyl-containing acrylamide or methacrylamide followed by reaction with a primary and/or secondary amine.
Claim 9
Independent Claim 96 words
A method of coating an electrically conductive surface serving as a cathode which comprises passing electric current between said cathode and an anode immersed in an aqueous dispersion of an electrodepositable curable resinous composition, comprising as the resinous binder a polyamine resin containing: (A) primary and/or secondary amino groups which are non-volatile under curing conditions; and (B) amine groups which are formed by reacting alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties with primary and/or secondary amines which are volatile under curing conditions; said polyamine resin being neutralized with acid to provide cationic salt groups.
Claim 10
Independent Claim 96 words
A method of coating an electrically conductive surface serving as a cathode which comprises passing electric current between said cathode and an anode immersed in an aqueous dispersion of an electrodepositable curable resinous composition, comprising as the resinous binder a polyamine resin containing: (A) primary and/or secondary amino groups which are non-volatile under curing conditions; and (B) amine groups which are formed by reacting alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties with primary and/or secondary amines which are volatile under curing conditions; said polyamine resin being neutralized with acid to provide cationic salt groups.

References Cited (Backward Citations)

US3637597A Cited
US3804786A Cited
US3844916A Cited
US3914165A Cited
US4020123A Cited
US3975251A Cited
US4096105A Cited
DE2753861A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-16 1984-09-15 1985-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-16 1988-09-15 1989-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-16 1992-09-15 1993-03-17 $7700.00 Window Closed / Lapsed

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