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US4255159A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer combinations useful in fuel oil to improve cold flow properties

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1980-02-11
•
Granted: 1981-03-10
•
Expires: 2000-02-11
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Abstract

Abstract A polymeric substance, i.e. poly(isomerized C12-C50 monoolefin), alone or as the alkylation derivative of an aromatic compound in combination with a lubricating oil pour depressant having pendant alkyl groups of 6 to 32 carbon atoms are useful in improving the cold flow properties of distillate hydrocarbon oils.

Inventors

  • 👤 Harold N. Miller
  • 👤 Max J. Wisotsky
  • 👤 Richard P. Rhodes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 05:52
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/143; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/165; C10L1/1691; C10L1/18; C10L1/192; C10L1/195; C10L1/196; C10L1/1963; C10L1/1966; C10L1/197; C10L1/1973; C10L1/24; C10L1/2462; C10L1/2468

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 233 words
A fuel oil composition comprising a major proportion of a distillate petroleum fraction having an atmospheric boiling range of from about 120° C. to about 400° C. and from about 0.005 to 0.1 wt. % of a synergistic flow and filterability improving combination of the following: (a) from 0.2 to 8 parts by weight of a polymeric substance selected from the group consisting of (i) poly (isomerized C 12 -C 50 alpha monoolefin) wherein said monoolefin contains at least 60% by weight of C 16 to C 32 alpha monoolefin, said poly (isomerized C 12 -C 50 alpha monoolefin) having a number average molecular weight of about 400 to 3000 and (ii) aromatics having 1 to 3 benzene rings alkylated with said poly (isomerized C 12-50 monoolefin); and (b) per part by weight of a lubricating oil pour depressant having a number average moleuclar weight of about 800 to 50,000 and having pendant alkyl groups of 6 to 32 carbons atoms, said pour depressant being selected from the group consisting of (i) the condensation product of chlorinated C 16-40 paraffin containing about 5 to 25 wt. % chlorine and an aromatic hydrocarbon, and (ii) a sulfone copolymer of sulfur dioxide and C 14-20 alpha olefin, wherein said synergistic combinations are combinations selected from the group consisting of (a) (i) with (b) (ii); (a) (ii) with (b) (i); and (a) (ii) with (b) (ii).
Claim 2
Dependent Claim 233 words
A fuel oil composition comprising a major proportion of a distillate petroleum fraction having an atmospheric boiling range of from about 120° C. to about 400° C. and from about 0.005 to 0.1 wt. % of a synergistic flow and filterability improving combination of the following: (a) from 0.2 to 8 parts by weight of a polymeric substance selected from the group consisting of (i) poly (isomerized C 12 -C 50 alpha monoolefin) wherein said monoolefin contains at least 60% by weight of C 16 to C 32 alpha monoolefin, said poly (isomerized C 12 -C 50 alpha monoolefin) having a number average molecular weight of about 400 to 3000 and (ii) aromatics having 1 to 3 benzene rings alkylated with said poly (isomerized C 12-50 monoolefin); and (b) per part by weight of a lubricating oil pour depressant having a number average moleuclar weight of about 800 to 50,000 and having pendant alkyl groups of 6 to 32 carbons atoms, said pour depressant being selected from the group consisting of (i) the condensation product of chlorinated C 16-40 paraffin containing about 5 to 25 wt. % chlorine and an aromatic hydrocarbon, and (ii) a sulfone copolymer of sulfur dioxide and C 14-20 alpha olefin, wherein said synergistic combinations are combinations selected from the group consisting of (a) (i) with (b) (ii); (a) (ii) with (b) (i); and (a) (ii) with (b) (ii).
Claim 3
Dependent Claim 18 words
A fuel oil composition according to claim 1, wherein said lubricating oil pour depressant is said sulfone copolymer.
Claim 4
Dependent Claim 21 words
A fuel oil composition according to claim 1, wherein said polymeric substance is said poly (isomerized C 12 -C 50 α-olefin.
Claim 5
Dependent Claim 24 words
A fuel oil composition according to claim 1, wherein said polymeric substance is said poly (isomerized C 12 -C 50 α-olefin) alkylated aromatic compound.
Claim 6
Dependent Claim 38 words
A fuel oil composition according to claim 4, wherein said polymeric substance is a poly (isomerized C 28 (ave.) α-olefin mixture) alkylated toluene and said lubricating oil pour depressant is the condensation product of chlorinated wax and naphthalene.
Claim 7
Dependent Claim 33 words
A fuel oil composition according to claim 4, wherein said polymeric substance is a poly (isomerized C 28 (ave.) α-olefin mixture) alkylated toluene and said lubricating oil pour depressant is said sulfone copolymer.

References Cited (Backward Citations)

US3245766A Cited
US3442790A Cited
US3926579A Cited
US3762888A Cited
US3767561A Cited
US3999960A Cited
US4019878A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-09 1984-09-08 1985-03-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-09 1988-09-08 1989-03-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-09 1992-09-08 1993-03-10 $7700.00 Window Closed / Lapsed

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