Hydrocarbon/ethylene oxide random graft copolymers

Claim 2

A random graft copolymer which comprises an essentially linear hydrocarbon base polymer having a number average molecular weight of 1000 to 500,000, said base polymer having grafted thereto, at intervals of 100 to 100,000 units of number average molecular weight, at least three hydroxyl-terminated ethylene oxide polymer chains each having a molecular weight of 100 to 5,000,000 selected from the group consisting of ethylene oxide polymer chains terminally located on the base polymer and ethylene oxide polymer chains randomly located on the base polymer, at least one of the ethylene oxide polymer chains being randomly located on the base polymer.

Claim 3

The random graft copolymer of claim 1 in which the base polymer has a number average molecular weight of 25,000 to 200,000, and the ethylene oxide polymer chains each have a molecular weight of 500 to 500,000, grafted to the base polymer at intervals of 500 to 50,000 units of number average molecular weight.

Claim 4

The random graft copolymer of claim 2 in which the base polymer is polyisoprene.

Claim 5

The random graft copolymer of claim 1 which is a block-random graft copolymer of the formula ##STR4## wherein B is the base polymer A 1 is an hydroxyl-terminated ethylene oxide block polymer chain attached to the end of the base polymer, A 2 is an hydroxyl-terminated ethylene oxide graft polymer chain randomly located on the base polymer, and n is a whole number from 1 to 1000, representing the number of hydroxyl-terminated ethylene oxide graft polymer chains randomly located on the base polymer.

Claim 6

The block-random graft copolymer of claim 4 in which the base polymer has a number average molecular weight of 25,000 to 200,000, the ethylene oxide polymer chains each have a molecular weight of 500 to 500,000, and n is 5 to 500.

Claim 7

The block-random graft copolymer of claim 5 in which the base polymer is polyisoprene.

Claim 8

Method of preparing a random graft copolymer which comprises (a) contacting (1) an essentially linear hydrocarbon base polymer having a number average molecular weight of 1,000 to 500,000 and containing at least three active sites selected from the group consisting of terminal lithium atoms and randomly located lithiatable hydrogen atoms, at least one of the active sites being a randomly located lithiatable hydrogen atom with (2) a hydrocarbyllithium selected from the group consisting of alkyllithiums, cycloalkyllithiums and aralkyllithiums in the presence of a tertiary aliphatic diamine, thereby replacing the lithiatable hydrogen atoms with lithium atoms to form lithiated base polymer containing at least three lithium atoms, at least one of which is randomly located, (b) contacting the lithiated base polymer with ethylene oxide followed by protonation with acid, thereby forming hydroxyethylated base polymer containing at least three hydroxyethyl groups, at least one of which is randomly located, (c) contacting the hydroxyethylated base polymer with sufficient hydrocarbylpotassium to provide 0.1 to 1 mole of potassium per mole of hydroxyethyl group, thereby forming potassium oxyethylated base polymer containing at least three potassium oxyethyl groups located at intervals of 100 to 100,000 units of number average molecular weight on the base polymer, at least one of the potassium oxyethyl groups being randomly located on the base polymer, (d) contacting the potassium oxyethylated base polymer with ethylene oxide in an amount sufficient to provide at least three ethylene oxide polymer chains having a molecular weight of 100 to 5,000,000 selected from the group consisting of terminal ethylene oxide polymer chains and randomly located ethylene oxide polymer chains, at least one of the ethylene oxide polymer chains being randomly located, and (e) contacting the resulting polymer with a protonating agent thereby forming at least three hydroxyl-terminated ethylene oxide polymer chains.

Claim 9

Method of preparing a random graft copolymer which comprises (a) contacting (1) an essentially linear hydrocarbon base polymer having a number average molecular weight of 1,000 to 500,000 and containing at least three active sites selected from the group consisting of terminal lithium atoms and randomly located lithiatable hydrogen atoms, at least one of the active sites being a randomly located lithiatable hydrogen atom with (2) a hydrocarbyllithium selected from the group consisting of alkyllithiums, cycloalkyllithiums and aralkyllithiums in the presence of a tertiary aliphatic diamine, thereby replacing the lithiatable hydrogen atoms with lithium atoms to form lithiated base polymer containing at least three lithium atoms, at least one of which is randomly located, (b) contacting the lithiated base polymer with ethylene oxide followed by protonation with acid, thereby forming hydroxyethylated base polymer containing at least three hydroxyethyl groups, at least one of which is randomly located, (c) contacting the hydroxyethylated base polymer with sufficient hydrocarbylpotassium to provide 0.1 to 1 mole of potassium per mole of hydroxyethyl group, thereby forming potassium oxyethylated base polymer containing at least three potassium oxyethyl groups located at intervals of 100 to 100,000 units of number average molecular weight on the base polymer, at least one of the potassium oxyethyl groups being randomly located on the base polymer, (d) contacting the potassium oxyethylated base polymer with ethylene oxide in an amount sufficient to provide at least three ethylene oxide polymer chains having a molecular weight of 100 to 5,000,000 selected from the group consisting of terminal ethylene oxide polymer chains and randomly located ethylene oxide polymer chains, at least one of the ethylene oxide polymer chains being randomly located, and (e) contacting the resulting polymer with a protonating agent thereby forming at least three hydroxyl-terminated ethylene oxide polymer chains.

Claim 10

The method of claim 7 in which the base polymer has a molecular weight of 25,000 to 200,000, has terminal lithium atoms at both ends, and has at least 5 randomly located lithiatable hydrogen atoms, the potassium oxyethyl groups are located at intervals of 500 to 50,000 units of number average molecular weight, and the ethylene oxide polymer chains have a molecular weight of 500 to 500,000.

Claim 11

The method of claim 8 in which the base polymer is polyisoprene.