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US4253929A
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Method for denitration of tobacco employing electrodialysis
Assignee: Philip Morris USA Inc
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Filing: 1980-03-05
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Granted: 1981-03-03
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Expires: 2000-03-05
Abstract
Abstract A process for denitrating tobacco with minimal losses of desirable tobacco solubles employing electrodialysis is disclosed. The process comprises subjecting an aqueous tobacco extract to membrane electrodialysis such that nitrate salts are extracted, without substantial loss of desirable tobacco solubles. The denitrated extract when combined with denitrated insoluble fibrous tobacco materials may be employed to produce tobacco products having reduced nirogen oxide delivery.
Inventors
- 👤 Gus D. Keritsis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 15:30
CPC Classifications
B; B01; B01D; B01D61/00; B01D61/42; B01D61/44; A; A24; A24B; A24B15/00; A24B15/18; A24B15/24
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
89 words
A method for denitrating aqueous tobacco extracts which comprises circulating an acidic tobacco extract having a solids content of about 5-50% and a resistivity of about 8-50 ohm-cm through the alternate cells of an electrodialysis unit having an anion permeable membrane toward the anode spaced no more than about 0.04 inches from an anion impermeable membrane toward the cathode, said membranes having a tightness sufficient to minimize transfer of nonelectrolyte substances, while circulating brine through the remaining cells and applying about 0.5 to 2.0 volts/cell pair to the unit.
Claim 2
Independent Claim
89 words
A method for denitrating aqueous tobacco extracts which comprises circulating an acidic tobacco extract having a solids content of about 5-50% and a resistivity of about 8-50 ohm-cm through the alternate cells of an electrodialysis unit having an anion permeable membrane toward the anode spaced no more than about 0.04 inches from an anion impermeable membrane toward the cathode, said membranes having a tightness sufficient to minimize transfer of nonelectrolyte substances, while circulating brine through the remaining cells and applying about 0.5 to 2.0 volts/cell pair to the unit.
Claim 3
Dependent Claim
26 words
The method of claim 1 wherein the tobacco extract cells contain mixed beds of resins selected from the group consisting of ion exchange and ionic resins.
Claim 4
Dependent Claim
24 words
The method of claim 1 wherein the aqueous tobacco extract has a solids content of about 10-30% and a resistivity of about 10-30 ohm-cm.
Claim 5
Dependent Claim
15 words
The method of claim 1 wherein an electrolyte comprising an acetic acid/acetate solution is employed.
Claim 6
Dependent Claim
15 words
The method of claim 1 wherein an electrolyte comprising a sulfuric acid/sulfate solution is employed.
Claim 7
Dependent Claim
22 words
The method of claim 4 which further comprises bleeding the electrolyte into the tobacco extract as it exits from the electrodialysis unit.
Claim 8
Dependent Claim
22 words
The method of claim 5 which further comprises bleeding the electrolyte into the tobacco extract as it exits from the electrodialysis unit.
Claim 9
Dependent Claim
16 words
The method of claim 1 wherein the pH of the circulating tobacco extract is about 5-6.5.
Claim 10
Dependent Claim
18 words
The method of claim 1 wherein the brine solution contains up to about 0.1 weight percent ionic material.
Claim 11
Dependent Claim
17 words
The method of claim 1 wherein the electrolyte has a pH between about 2 and about 5.
Claim 12
Independent Claim
109 words
A method for denitration of tobacco which comprises: (a) forming an aqueous tobacco extract having a solids content of about 5-50% and a resistivity of about 8-50 ohm-cm; (b) denitrating the extract by circulation through those cells in an electrodialysis apparatus which comprises an anion permeable membrane having at least intermediate tightness toward the anode spaced no more than about 0.04 inches from an anion impermeable membrane having at least intermediate tightness toward the cathode and which alternate with brine cells in an electrodialysis stack while applying about 0.5 to 2.0 volts/cell pair; and (c) combining the denitrated extract with insoluble tobacco residue from which solubles have been extracted.
Claim 13
Independent Claim
109 words
A method for denitration of tobacco which comprises: (a) forming an aqueous tobacco extract having a solids content of about 5-50% and a resistivity of about 8-50 ohm-cm; (b) denitrating the extract by circulation through those cells in an electrodialysis apparatus which comprises an anion permeable membrane having at least intermediate tightness toward the anode spaced no more than about 0.04 inches from an anion impermeable membrane having at least intermediate tightness toward the cathode and which alternate with brine cells in an electrodialysis stack while applying about 0.5 to 2.0 volts/cell pair; and (c) combining the denitrated extract with insoluble tobacco residue from which solubles have been extracted.
Claim 14
Dependent Claim
36 words
The method of claim 11 wherein the aqueous tobacco extract is formed by contacting a tobacco material with a denitrated aqueous tobacco extract containing tobacco solubles and separating the aqueous extract from the insoluble tobacco residue.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-02 | 1984-09-01 | 1985-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-02 | 1988-09-01 | 1989-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-02 | 1992-09-01 | 1993-03-03 | $7700.00 | Window Closed / Lapsed |