Patent US4253714A successfully refreshed from Google Patents.
US4253714A
Expired / Lapsed
US
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High temperature low friction surface coating and method of application
Assignee: Soluna Holdings Inc
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Filing: 1980-02-27
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Granted: 1981-03-03
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Expires: 2000-02-27
Abstract
Abstract A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65° C. to remove the water and wetting agent, and baked for an additional eight hours at about 150° C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.
Inventors
- 👤 Bharat Bhushan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 07:21
CPC Classifications
F; F16; F16C; F16C17/00; F16C17/02; F16C17/024; F16C33/00; F16C33/02; F16C33/04; F16C33/16; Y; Y10; Y10T; Y10T29/00; Y10T29/49; Y10T29/49636; Y10T29/49702; Y10T29/49703; Y10T29/4998; Y10T29/49982; Y10T29/49986
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
208 words
A thin flexible bearing sheet coating with a low friction coating for high temperature applications, produced by a process comprising the steps of: electroetching one surface of said bearing sheet to remove oxides and roughen said surface; mechanically and chemically cleaning said surface to remove loose particulate matter and chemically clean said surface of the electroetch solution and other chemicals that could interfere with the bond of said coating; mixing CdO and graphite powders in proportions of about 1:3 by weight in water to form a water suspension; agitating said water suspension until said powders are uniformly dispersed in said water; mixing about 28%-32% by weight sodium silicate in water solution and about 1 drop of wetting agent for every 250 cc by volume with said water suspension to produce a spray solution; spraying said spray solution in a layer about 12-17 microns thick onto said cleaned and roughened surface; baking said layer at about 65° C. to evaporate said water and said wetting agent, about two hours; baking said layer above about 140° C. until said sodium silicate is fused and said layer is bonded to said surface in a thin, flexible coating; and burnishing said coating smooth and to a thickness of less than 12 microns.
Claim 2
Dependent Claim
208 words
A thin flexible bearing sheet coating with a low friction coating for high temperature applications, produced by a process comprising the steps of: electroetching one surface of said bearing sheet to remove oxides and roughen said surface; mechanically and chemically cleaning said surface to remove loose particulate matter and chemically clean said surface of the electroetch solution and other chemicals that could interfere with the bond of said coating; mixing CdO and graphite powders in proportions of about 1:3 by weight in water to form a water suspension; agitating said water suspension until said powders are uniformly dispersed in said water; mixing about 28%-32% by weight sodium silicate in water solution and about 1 drop of wetting agent for every 250 cc by volume with said water suspension to produce a spray solution; spraying said spray solution in a layer about 12-17 microns thick onto said cleaned and roughened surface; baking said layer at about 65° C. to evaporate said water and said wetting agent, about two hours; baking said layer above about 140° C. until said sodium silicate is fused and said layer is bonded to said surface in a thin, flexible coating; and burnishing said coating smooth and to a thickness of less than 12 microns.
Claim 3
Dependent Claim
37 words
The bearing sheet defined in claim 1, wherein said bearing sheet is high temperature nickel-based material, also containing chromium, iron and titanium, between 50 and 200 microns thick, which has been treated for hardness, resilience and strength.
Claim 4
Independent Claim
176 words
A method of applying a low friction coating for high temperature applications to a thin, flexible metal substrate, comprising: cleaning and roughening one surface of said substrate; mixing CdO and graphite powders in proportions of about 1:3 by weight in water to form a water suspension; agitating said water suspension until said powders are uniformly dispersed in said water; mixing about 28%-32% by weight sodium silicate in water solution and about 1 drop of wetting agent per about 250 cc of solution with said water suspension to produce a spray solution; spraying said spray solution in a layer about 12-16 microns thick onto said cleaned and roughened surface; baking said layer at about 65° C. to evaporate said water and said wetting agent, about two hours; baking said layer above about 140° C. until said sodium silicate is fused and said layer is bonded to said surface in a thin, flexible coating; and burnishing said coating smooth and to a thickness of less than 12 microns and a smoothness of less than about 0.15 microns rms.
Claim 5
Independent Claim
176 words
A method of applying a low friction coating for high temperature applications to a thin, flexible metal substrate, comprising: cleaning and roughening one surface of said substrate; mixing CdO and graphite powders in proportions of about 1:3 by weight in water to form a water suspension; agitating said water suspension until said powders are uniformly dispersed in said water; mixing about 28%-32% by weight sodium silicate in water solution and about 1 drop of wetting agent per about 250 cc of solution with said water suspension to produce a spray solution; spraying said spray solution in a layer about 12-16 microns thick onto said cleaned and roughened surface; baking said layer at about 65° C. to evaporate said water and said wetting agent, about two hours; baking said layer above about 140° C. until said sodium silicate is fused and said layer is bonded to said surface in a thin, flexible coating; and burnishing said coating smooth and to a thickness of less than 12 microns and a smoothness of less than about 0.15 microns rms.
Claim 6
Dependent Claim
17 words
The method defined in claim 3, wherein said agitation is in a ball mill for four hours.
Claim 7
Dependent Claim
55 words
The method defined in claim 3, wherein said cleaning and roughening steps includes: masking one surface of said substrate; immersing said substrate in an electroetch solution; applying a DC current for about two minutes at a density of about 2325 amp/m 2 ; and washing said substrate clean of electroetch solution and loose particulate materials.
Claim 8
Dependent Claim
35 words
The method defined in claim 5, wherein said electroetch solution includes the following materials in the following proportions: 25 grams of NaF; 95 cc of H 2 SO 4 ; and 1 liter of water.
Claim 9
Dependent Claim
32 words
The method defined in claim 5, wherein said washing step includes: immersion in water in an ultrasonic cleaner to remove loose particulate matter; and cleaning with alcohol to chemically clean said substrate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-03-02 | 1984-09-01 | 1985-03-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-03-02 | 1988-09-01 | 1989-03-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-03-02 | 1992-09-01 | 1993-03-03 | $7700.00 | Window Closed / Lapsed |