Catalysts

Claim 2

In a method of making a catalyst comprising providing a hydroxyl-containing solid refractory support material and contacting the support material with a solution of a substance providing catalytically active material, the improvement comprising activating the support material by providing surfaces of the support material having a deficiency of hydroxyl groups to form activated support material surfaces, and contacting the activated support material surfaces with said solution before said activated support material surfaces are deactivated.

Claim 3

A method according to claim 1 in which the activated surfaces are generated by heating the support material under conditions such as to create a deficiency of hydroxyl groups.

Claim 4

A method according to claim 1 in which the catalytically active material is present in the said substance in anionic form and is physically adsorbed onto the support material.

Claim 5

A method according to claim 1 in which the solution of the said substance is a solution in a mixture of water and an organic liquid that reduces the surface tension of the solution.

Claim 6

A method according to claim 4 in which the organic liquid is methanol.

Claim 7

A method according to claim 1 in which the catalytically active material is subsequently reduced by treatment with carbon monoxide.

Claim 8

A method according to claim 1 in which the catalytically active material is selected from platinum, palladium and rhodium.

Claim 9

A method according to claim 1 in which the support material comprises alumina.

Claim 10

A method according to claim 1 in which the support material comprises a zeolite.

Claim 11

A method according to claim 9 in which the zeolite is zeolite 13X.

Claim 12

A method according to claim 9 in which the zeolite is zeolite 4A or 5A.

Claim 13

A method according to claim 8 in which the support material comprises alumina on a refractory macroporous support.

Claim 14

In a method of making a catalyst comprising providing a hydroxyl-containing solid refractory support material and contacting the support material with a solution of a substance providing catalytically active material, wherein said solid support material is originally in the form of pellets, the improvement comprising activating the support material by crushing said pellets to provide activated support material surfaces, and thereafter contacting the activated support material surfaces with said solution before said activated support material surfaces are deactivated.

Claim 15

In a method of making a catalyst comprising providing a hydroxyl-containing solid refractory support material and contacting the support material with a solution of a substance providing catalytically active material, wherein said solid support material is originally in the form of pellets, the improvement comprising activating the support material by crushing said pellets to provide activated support material surfaces, and thereafter contacting the activated support material surfaces with said solution before said activated support material surfaces are deactivated.

Claim 16

In a method of making a catalyst comprising providing a hydroxyl-containing solid refractory support material and contacting the support material with a solution of a substance providing catalytically active material, the improvement comprising activating the support material by heating the support material to a temperature of at least 20° C. above the temperature at which expulsion of chemisorbed water is substantially completed but below the temperature at which substantial degradation of the support material occurs to form activated support material surfaces, and contacting the activated support material surfaces with said solution before said activated support material surfaces are deactivated.

Claim 17

In a method of making a catalyst comprising providing a hydroxyl-containing solid refractory support material and contacting the support material with a solution of a substance providing catalytically active material, the improvement comprising activating the support material by heating the support material to a temperature of at least 20° C. above the temperature at which expulsion of chemisorbed water is substantially completed but below the temperature at which substantial degradation of the support material occurs to form activated support material surfaces, and contacting the activated support material surfaces with said solution before said activated support material surfaces are deactivated.

Claim 18

A method according to claim 14 in which the support material that is heated is in the form of powder having a particle size of less than 50 microns and the contact with the said solution is conducted substantially immediately thereafter.

Claim 19

A method according to claim 14 in which the heating is conducted substantially immediately prior to or during the manufacture of pellets of support material, and the activated surfaces are generated by crushing the pellets.

Claim 20

A method according to claim 1 in which the activated surfaces are generated by heating the support material under conditions such as to create a deficiency of hydroxyl groups at a temperature of 300° to 800° C.

Claim 21

A method according to claim 17 in which the support material is a zeolite or alumina and the heating is at a temperature of 400° to 650° C.

Claim 22

A catalyst made by a method according to claim 1.

Claim 23

A method according to claim 1, wherein said support material is a porous refractory material.

Claim 24

A method according to claim 1, wherein said support material is selected from the group consisting of alumina, silica, titania, magnesium, zirconia, silico-aluminate and zeolite materials.

Claim 25

A method according to claim 1, wherein said activated surfaces have Lewis acid sites therein.

Claim 26

A method according to claim 1, wherein the catalytic active material is present in said surfaces in anionic form, and is physically adsorbed onto the support material, and said catalytic active material is selected from the group consisting of platinum, palladium and rhodium.

Claim 27

A method according to claim 1, wherein said activated support material surfaces are activated to the extent that when subjected to differential thermal analysis no large temperature difference due to physically absorbed water will be noted, and a gradual increase in temperature difference will be noted.

Claim 28

A method according to claim 1, wherein said activated support material surfaces when subjected to iodine titration exhibits a titre decrease which cannot substantially be further decreased upon heating.