Patent US4252537A successfully refreshed from Google Patents.
US4252537A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Quantification of the munitions, HMX, RDX, and TNT in waste water by liquid chromatography
Assignee: United States Department of the Army
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Filing: 1979-02-02
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Granted: 1981-02-24
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Expires: 1999-02-02
Abstract
Abstract Disclosed is a liquid chromatography process for the quantitative determination of nitro-amines and nitro-aromatics in liquid samples, which comprises directly injecting a liquid sample containing these compounds onto a liquid chromatography column, separating the compounds on the column by elution, and then monitoring the ultra-violet absorbance of the resulting eluant. The instant process finds particular application in the quantitative detection of munitions, such as HMX, RDX, TNT, and their degradation products, in aqueous effluent streams.
Inventors
- 👤 Doris E. Cattran
- 👤 Thomas B. Stanford
- 👤 Anthony P. Graffeo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 11:15
CPC Classifications
G; G01; G01N; G01N30/00; G01N30/02; G01N33/00; G01N33/0004; G01N33/0009; G01N33/0027; G01N33/0036; G01N33/0047; Y; Y10; Y10T; Y10T436/00; Y10T436/17; Y10T436/173845
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
112 words
A method for the quantitative detection of aliphatic nitro-amine and nitroaromatic munitions selected from the group consisting of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane, 1,3,5-trinitro-1,3,5-triazacyclohexane, 2,4,6-trinitrotoluene, combinations thereof, and the degradation products thereof, in liquid samples, comprising the steps of: (a) directly injecting up to 400 microliters of a non-concentrated liquid sample containing said munitions in trace amounts as low as 25 parts per billion onto a reverse phase, high performance liquid chromatographic column; (b) chromatographically separating said munitions on said column by elution with a mobile phase comprising methanol and water; and, (c) monitoring the absorance of the resulting eluant in the ultra-violet region to provide a quantitative determination of the munitions present in said sample.
Claim 2
Independent Claim
112 words
A method for the quantitative detection of aliphatic nitro-amine and nitroaromatic munitions selected from the group consisting of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane, 1,3,5-trinitro-1,3,5-triazacyclohexane, 2,4,6-trinitrotoluene, combinations thereof, and the degradation products thereof, in liquid samples, comprising the steps of: (a) directly injecting up to 400 microliters of a non-concentrated liquid sample containing said munitions in trace amounts as low as 25 parts per billion onto a reverse phase, high performance liquid chromatographic column; (b) chromatographically separating said munitions on said column by elution with a mobile phase comprising methanol and water; and, (c) monitoring the absorance of the resulting eluant in the ultra-violet region to provide a quantitative determination of the munitions present in said sample.
Claim 3
Dependent Claim
15 words
The process of claim 1, wherein said eluant is monitored at about 230 nm wavelength.
Claim 4
Dependent Claim
15 words
The process of claim 1, wherein said mobile phase comprises approximately 40% methanol in water.
Claim 5
Dependent Claim
20 words
The process of claim 1, wherein a plurality of chromatographic columns connected in series is utilized for separating said munitions.
Claim 6
Dependent Claim
15 words
The process of claim 1, wherein said liquid sample comprises a sample of waste water.
Claim 7
Dependent Claim
46 words
The process of claim 5, further comprising the steps of filtering said liquid sample on a tetrahydrofuran moistened filter to produce a filtrate and a liquid filtrant containing said munitions, and washing said filtrate with tetrahydrofuran to recover any of said munitions remaining on said filtrate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-02-24 | 1984-08-25 | 1985-02-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-02-24 | 1988-08-25 | 1989-02-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-02-24 | 1992-08-25 | 1993-02-24 | $7700.00 | Window Closed / Lapsed |