Method and apparatus for converting alcohols to hydrocarbons

Claim 1

An apparatus for converting lower alcohols to hydrocarbons including gasoline boiling range hydrocarbons which comprises, in combination, an elongated substantially vertical cylindrical reactor vessel, a horizontal grid means positioned across a bottom cross-sectional portion of the vessel above a bottom semicircular closure member of the vessel, a plurality of vertical heat exchanger tubes positioned within a lower portion of the vessel with the bottom of the tubes spaced vertically above the grid means, a plurality of vertical open end baffle tubes slotted in the wall thereof throughout substantially the entire length thereof positioned interspersed with and adjacent to said heat exchange tubes and spaced horizontally from one another and from said heat exchange tubes to maintain a reactant hydraulic diameter of less than 24 inches during contact with a fluid mass of catalyst particles, the bottoms of said baffle tubes spaced vertically above said grid means, conduit means for withdrawing particles of catalyst from the space intermediate the grid means and the bottom of said tubes, conduit means for adding particles to an upper portion of a bed of fluid catalyst in which said heat exchange means is immersed, a plurality of cyclone separating means located in an upper portion of said vessel provided with dipleg means extending downward through said vessel and terminating in the space above said grid means, a plenum chamber in the upper portion of said vessel in open communication with said cyclone separating means and conduit withdrawal means for reaction products connected to the upper portion of said plenum chamber, an open end conduit means extending from a bottom portion of said vessel beneath said grid means to an upper level of said vessel above said heat exchange and baffle tubes and terminating above the upper interface of a fluid bed of catalyst in the lower portion of the vessel, means for introducing separately controlled gases to the bottom of said open end conduit means, means for charging reactant to said vessel beneath said grid means for flow upwardly through said vessel.

Claim 2

An apparatus for converting lower alcohols to hydrocarbons including gasoline boiling range hydrocarbons which comprises, in combination, an elongated substantially vertical cylindrical reactor vessel, a horizontal grid means positioned across a bottom cross-sectional portion of the vessel above a bottom semicircular closure member of the vessel, a plurality of vertical heat exchanger tubes positioned within a lower portion of the vessel with the bottom of the tubes spaced vertically above the grid means, a plurality of vertical open end baffle tubes slotted in the wall thereof throughout substantially the entire length thereof positioned interspersed with and adjacent to said heat exchange tubes and spaced horizontally from one another and from said heat exchange tubes to maintain a reactant hydraulic diameter of less than 24 inches during contact with a fluid mass of catalyst particles, the bottoms of said baffle tubes spaced vertically above said grid means, conduit means for withdrawing particles of catalyst from the space intermediate the grid means and the bottom of said tubes, conduit means for adding particles to an upper portion of a bed of fluid catalyst in which said heat exchange means is immersed, a plurality of cyclone separating means located in an upper portion of said vessel provided with dipleg means extending downward through said vessel and terminating in the space above said grid means, a plenum chamber in the upper portion of said vessel in open communication with said cyclone separating means and conduit withdrawal means for reaction products connected to the upper portion of said plenum chamber, an open end conduit means extending from a bottom portion of said vessel beneath said grid means to an upper level of said vessel above said heat exchange and baffle tubes and terminating above the upper interface of a fluid bed of catalyst in the lower portion of the vessel, means for introducing separately controlled gases to the bottom of said open end conduit means, means for charging reactant to said vessel beneath said grid means for flow upwardly through said vessel.