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US4247663A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat shrinkable polyvinyl chloride film with methyl methacrylate polymer additive

Assignee: Mitsubishi Chemical Corp
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Filing: 1979-02-14
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Granted: 1981-01-27
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Expires: 1999-02-14
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Abstract

Abstract A heat shrinkable polyvinyl chloride film which shrinks more than 60% in one direction or more than 75% as an area shrinkage is prepared by stretching a film comprising 5 to 25 wt. parts of a methyl methacrylate type copolymer and 100 wt. parts of polyvinyl chloride at a special high stretch ratio.

Inventors

  • 👤 Norio Yoshiga
  • 👤 Hiroshi Nakamura
  • 👤 Mototaka Ohmura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 12:21
CPC Classifications
C; C08; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L33/00; C08L33/04; C08L33/06; C08L33/10; C08L33/12; Y; Y10; Y10S; Y10S264/00; Y10S264/71; Y10S428/00; Y10S428/91

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 80 words
A highly heat shrinkable polyvinyl chloride film which shrinks more than 60% in one direction prepared by uniaxially stretching a film comprising 5 to 25 wt. parts of a methyl methacrylate copolymer comprising 60 to 85 weight percent of methyl methacrylate component and 100 parts of polyvinyl chloride, wherein said film has been stretched at a stretch ratio of 3.5 to 6 times in one direction and at a stretch ratio of less than 1.5 times in the perpendicular direction.
Claim 2
Dependent Claim 80 words
A highly heat shrinkable polyvinyl chloride film which shrinks more than 60% in one direction prepared by uniaxially stretching a film comprising 5 to 25 wt. parts of a methyl methacrylate copolymer comprising 60 to 85 weight percent of methyl methacrylate component and 100 parts of polyvinyl chloride, wherein said film has been stretched at a stretch ratio of 3.5 to 6 times in one direction and at a stretch ratio of less than 1.5 times in the perpendicular direction.
Claim 3
Dependent Claim 45 words
A highly heat shrinkable polyvinyl chloride film according to claim 1 wherein the methyl methacrylate type copolymer is a copolymer comprising 60 to 85 wt. % of methyl methacrylate component and 40 to 15 wt. % of a C 1 -C 4 alkyl acrylate component.
Claim 4
Dependent Claim 40 words
A highly heat shrinkable polyvinyl chloride film according to claim 1 wherein the methyl methacrylate type copolymer is a copolymer comprising 60 to 85 wt. % of methyl methacrylate component and 40 to 15 wt. % of butyl acrylate component.
Claim 5
Dependent Claim 25 words
A highly heat shrinkable polyvinyl chloride film according to claim 1 wherein has been stretched in a stretching zone at 60° C. to 100° C.
Claim 6
Dependent Claim 87 words
A highly heat shrinkable polyvinyl chloride film which film shrinks more than 75% as an area shrinkage prepared by biaxially stretching a film comprising 5 to 25 wt. parts of a methyl methacrylate copolymer comprising 60 to 85 weight percent of methyl methacrylate component and 100 parts of polyvinyl chloride, wherein said film has been stretched at a total of stretch ratios in logitudinal direction in and transverse direction of 5 to 7.5 times and at a stretch ratio of more than 1.5 times in each direction.
Claim 7
Dependent Claim 87 words
A highly heat shrinkable polyvinyl chloride film which film shrinks more than 75% as an area shrinkage prepared by biaxially stretching a film comprising 5 to 25 wt. parts of a methyl methacrylate copolymer comprising 60 to 85 weight percent of methyl methacrylate component and 100 parts of polyvinyl chloride, wherein said film has been stretched at a total of stretch ratios in logitudinal direction in and transverse direction of 5 to 7.5 times and at a stretch ratio of more than 1.5 times in each direction.
Claim 8
Dependent Claim 31 words
A film according to claim 5, which gives an area shrinkage of more than 80% attained by stretching the film at a total of stretch ratios of more than about 6.0.
Claim 9
Dependent Claim 45 words
A highly heat shrinkable polyvinyl chloride film according to claim 5, wherein the methyl methacrylate type copolymer is a copolymer comprising 60 to 85 wt. % of methyl methacrylate component and 40 to 15 wt. % of a C 1 -C 4 alkyl acrylate component.
Claim 10
Dependent Claim 40 words
A highly heat shrinkable polyvinyl chloride film according to claim 5, wherein the methyl methacrylate type copolymer is a copolymer comprising 60 to 85 wt. % of methyl methacrylate component and 40 to 15 wt. % of butyl acrylate component.
Claim 11
Dependent Claim 24 words
A highly heat shrinkable polyvinyl chloride film according to claim 5 which has been stretched in a stretching zone at 60° to 100° C.

References Cited (Backward Citations)

US3254146A Cited
US3570051A Cited
US3969469A Cited
US3957917A Cited
US4003963A Cited
US4115479A Cited
US4113681A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-27 1984-07-28 1985-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-27 1988-07-28 1989-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-27 1992-07-28 1993-01-27 $7700.00 Window Closed / Lapsed

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