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US4247655A Expired / Lapsed US ⏱️ 0.0 years remaining

Rigid and semiflexible polyurethane foams produced with phenol-aldehyde-amine resins

Assignee: Lyondell Chemical Technology LP
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Filing: 1979-09-18
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Granted: 1981-01-27
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Expires: 1999-09-18
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Abstract

Abstract Rigid and semiflexible polyurethane foams having superior flame retardant properties are produced by incorporating into the pre-foam formulation the reaction product of a phenol, an aldehyde, and an aromatic amine.

Inventors

  • 👤 Raymond A. Dunleavy
  • 👤 James A. McClanahan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:30
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/4009; C08G18/4027; C08G18/54; C08G18/544

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 112 words
A process for producing a rigid or semiflexible polyurethane foam which comprises forming and curing reaction mixture consisting essentially of (a) a polyether polyol, or blend of polyether polyols, having a hydroxyl number of greater than 100 and a functionality of at least 3 and less than 8, (b) the reaction product of: (I) a phenol which has at least one unsubstituted reactive position on the aromatic nucleus, (II) an aldehyde, and (III) an aromatic amine, (c) an aromatic polyisocyanate in an amount which provides from 0.8 to 1.6 isocyanate groups per active hydrogen group in the reaction mixture, (d) a blowing agent, (e) a surfactant, and (f) a flame retardant additive.
Claim 2
Dependent Claim 112 words
A process for producing a rigid or semiflexible polyurethane foam which comprises forming and curing reaction mixture consisting essentially of (a) a polyether polyol, or blend of polyether polyols, having a hydroxyl number of greater than 100 and a functionality of at least 3 and less than 8, (b) the reaction product of: (I) a phenol which has at least one unsubstituted reactive position on the aromatic nucleus, (II) an aldehyde, and (III) an aromatic amine, (c) an aromatic polyisocyanate in an amount which provides from 0.8 to 1.6 isocyanate groups per active hydrogen group in the reaction mixture, (d) a blowing agent, (e) a surfactant, and (f) a flame retardant additive.
Claim 3
Dependent Claim 13 words
A rigid or semiflexible polyurethane foam produced by the process of claim 1.
Claim 4
Dependent Claim 56 words
A process as in claim 1 wherein component (b) of the formulation is the reaction of: (I) phenol, (II) formaldehyde, and (III) aniline, wherein the molar ratio of (I) to (III) ranges from about 6:1 to about 1:6 and wherein the molar ratio of (I) plus (III) to (II) ranges from about 6:1 to about 1.2:1.
Claim 5
Dependent Claim 13 words
A rigid or semiflexible polyurethane foam produced by the process of claim 3.
Claim 6
Dependent Claim 19 words
A process as in any one of claims 1, or 3 wherein the product is a rigid polyurethane foam.
Claim 7
Dependent Claim 11 words
A rigid polyurethane foam produced by the process of claim 5.

References Cited (Backward Citations)

US3493257A Cited
US3558529A Cited
US3514144A Cited
US3586649A Cited
US3580869A Cited
US4107106A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-27 1984-07-28 1985-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-27 1988-07-28 1989-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-27 1992-07-28 1993-01-27 $7700.00 Window Closed / Lapsed

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