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US4247443A
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Aromatic polyimide resin composition
Assignee: Ube Corp
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Filing: 1979-08-16
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Granted: 1981-01-27
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Expires: 1999-08-16
Abstract
Abstract An aromatic polyimide resin composition useful for producing a film or sheet, comprises 2% by weight or more of an imide polymer having at least 90 molar % of a recurring unit of the formula (I): ##STR1## wherein R' is a divalent aromatic radical, and dissolved in an organic polar solvent consisting essentially of one or more halogenated phenol compounds of the formulae (II) or (III): ##STR2## wherein R 2 is a hydrogen atom of a C 1-3 alkyl radical and is a halogen atom, the halogenated phenol compound having a melting point of 100° C. or less and a boiling point of 300° C. or less.
Inventors
- 👤 Ichiro Sasaki
- 👤 Hiroshi Itatani
- 👤 Mikito Kashima
- 👤 Hataaki Yoshimoto
- 👤 Shuji Yamamoto
- 👤 Yoshikazu Sasaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 12:41
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/09; C08J3/091; C08J3/095; C08J2379/00; C08J2379/04; C08J2379/08
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
130 words
An aromatic polyimide resin composition comprising: at least 2% by weight of at least one imide polymer having at least 90 molar % of a recurring unit of the formula (I): ##STR8## wherein R' represents a divalent aromatic radical, and; the balance consisting of an organic polar solvent consisting essentially of at least one halogenated phenol compound having a melting point of 100° C. or less and a boiling point of 300° C. or less, and selected from the group consisting of those of the formulae (II) and (III): ##STR9## wherein R 2 represents a member selected from the group consisting of a hydrogen atom and alkyl radicals having 1 to 3 carbon atoms, and X represents a halogen atom, said imide polymer being dissolved in said organic polar solvent.
Claim 2
Dependent Claim
130 words
An aromatic polyimide resin composition comprising: at least 2% by weight of at least one imide polymer having at least 90 molar % of a recurring unit of the formula (I): ##STR8## wherein R' represents a divalent aromatic radical, and; the balance consisting of an organic polar solvent consisting essentially of at least one halogenated phenol compound having a melting point of 100° C. or less and a boiling point of 300° C. or less, and selected from the group consisting of those of the formulae (II) and (III): ##STR9## wherein R 2 represents a member selected from the group consisting of a hydrogen atom and alkyl radicals having 1 to 3 carbon atoms, and X represents a halogen atom, said imide polymer being dissolved in said organic polar solvent.
Claim 3
Dependent Claim
40 words
An aromatic polyimide resin composition as claimed in claim 1, wherein said imide polymer exhibits a logarithmic viscosity of from 0.5 to 6.0, determined at a concentration of 0.5 g/100 ml, in 4-chloro phenol, at a temperature of 50° C.
Claim 4
Dependent Claim
31 words
An aromatic polyimide resin composition as claimed in claim 1, wherein the content of said recurring unit of the formula (I) in said imide polymer is 95 molar % or more.
Claim 5
Dependent Claim
80 words
An aromatic polyimide resin composition as claimed in claim 1, wherein said imide polymer is prepared by the polycondensation and the imide ring cyclization of a tetracarboxylic acid component comprising 90 molar % or more of 3,3',4,4'-biphenyl tetracarboxylic acid or its anhydride, salt or ester with a diamine component consisting essentially of at least one aromatic diamine selected from the group consisting of those of the formula (IV): H.sub.2 N--R'--NH.sub.2 (IV) where R' is the same as that defined above.
Claim 6
Dependent Claim
64 words
An aromatic polyimide resin composition as claimed in claim 4, wherein said tetracarboxylic acid component contains 10 molar % or less of at least one additional tetracarboxylic acid selected from the group consisting of pyromellitic acid, 2,3,6,7-naphthalene tetracarboxylic acid, 2,3,3',4'-biphenyl tetracarboxylic acid, 2,2',3,3'-biphenyl tetracarboxylic acid, 3,3',4,4'-benzophenone tetracarboxylic acid, 2,2-bis(3,4-dicarboxyphenyl)propane, bis(3,4-dicarboxyphenyl)sulfone, bis(3,4-dicarboxyphenyl)ether, and butane tetracarboxylic acid, and anhydrides, salts and esters of the above-named acids.
Claim 7
Dependent Claim
100 words
An aromatic polyimide resin composition as claimed in claim 4, wherein said aromatic diamine of the formula (IV) is selected from the group consisting of those of the formula (V) and (VI): ##STR10## wherein R 3 and R 4 respectively, independently from each other, represent a member selected from the group consisting of a hydrogen atom, lower alkyl radicals and lower alkoxy radicals, n represents an integer of from 1 to 4, and A represents a divalent radical selected from the group consisting of --O--, --S--, --CO--, --SO 2 --, --SO--, --CH 2 -- and --C(CH 3 ) 2 --.
Claim 8
Dependent Claim
35 words
An aromatic polyimide resin composition as claimed in claim 1, wherein said halogenated phenol compound is selected from the group consisting of m-chlorophenol, p-chlorophenol, m-bromophenol, p-bromophenol, 2-chloro-4-hydroxytoluene, 2-chloro-5-hydroxytoluene, 3-choloro-6-hydroxytoluene, 4-chloro-2-hydroxytoluene, 2-bromo-4-hydroxytoluene, 2-bromo-5-hydroxytoluene, 3-bromo-5-hydroxy-toluene, 3-bromo-6-hydroxytoluene, 4-bromo-2-hydroxytoluene.
Claim 9
Dependent Claim
65 words
An aromatic polyimide resin composition as claimed in claim 1, wherein said organic polar solvent contains at least one additional compound selected from the group consisting of phenol, o-, m-, and p-cresols, 2,4-dichlorophenol, nitrophenols, nitrobenzene, toluene, pyridine, aniline, N-methyl pyrrolidone, N,N-dimenthyl acetamide, N,N-dimethyl formamide, dimethyl sulfoxide and 2-methyl pyrrolidone, in an amount of 10% or less based on the weight of said halogenated phenol compound.
Claim 10
Dependent Claim
28 words
An aromatic polyimide resin composition as claimed in claim 1, wherein the content of said imide polymer is in a range of from 3 to 30% by weight.
Claim 11
Dependent Claim
27 words
A film made by shaping said aromatic polyimide resin composition of claim 1 into a film and by removing said organic polar solvent from said film-shaped composition.
Claim 12
Dependent Claim
13 words
Coating material comprising said aromatic polyimide resin composition as claimed in claim 1.
Claim 13
Dependent Claim
13 words
Bonding material comprising said aromatic polyimide resin composition as claimed in claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-27 | 1984-07-28 | 1985-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-27 | 1988-07-28 | 1989-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-27 | 1992-07-28 | 1993-01-27 | $7700.00 | Window Closed / Lapsed |