Patent US4247301A successfully refreshed from Google Patents.
US4247301A
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Deposit control and dispersant additives
Assignee: Chevron USA Inc
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Filing: 1978-06-19
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Granted: 1981-01-27
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Expires: 1998-06-19
Abstract
Abstract Additives for internal combustion engines are provided which in fuels maintain cleanliness of intake system without contributing to combustion chamber deposits and in lubricating oils act as dispersants. The additives are hydrocarbylpoly(oxyalkylene) polyamines comprising a hydrocarbyl-terminated poly(oxyalkylene) chain of 2-5 carbon oxyalkylene units bonded to a nitrogen atom of a polyamine having from 2 to 12 amine nitrogens and from 2 to 40 carbon atoms with a carbon:nitrogen ratio between 1:1 and 10:1.
Inventors
- 👤 Lewis R. Honnen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:48
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/222; C10L1/2222; C10L1/2225; C08; C08G; C08G65/00; C08G65/02; C08G65/32; C08G65/329; C08G65/333; C08G65/33303; C10L1/232; C10L1/234; C10L1/238; C10L1/2383; C10L1/2387; C10M; C10M133/00; C10M133/02; C10M133/04; C10M133/06; C10M133/08; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/042
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
111 words
A fuel composition comprising a major portion of hydrocarbon boiling in the gasoline range, and from 30 to about 2,000 ppm of a hydrocarbylpoly(oxyalkylene) polyamine of molecular weight from about 500 to about 10,000; wherein said hydrocarbyl group contains from 1 to about 30 carbon atoms, said poly(oxyalkylene) moiety comprises 8-100 oxyalkylene units selected from oxyalkylene units having from 2 to 5 carbon atoms at least a sufficient number of said oxyalkylene units being branched C 3 -C 5 oxyalkylene units to render said hydrocarbylpoly(oxyalkylene) polyamine soluble in said fuel composition, and said polyamine moiety comprises from 2 to about 12 amine nitrogen atoms and from 2 to 40 carbon atoms.
Claim 2
Dependent Claim
111 words
A fuel composition comprising a major portion of hydrocarbon boiling in the gasoline range, and from 30 to about 2,000 ppm of a hydrocarbylpoly(oxyalkylene) polyamine of molecular weight from about 500 to about 10,000; wherein said hydrocarbyl group contains from 1 to about 30 carbon atoms, said poly(oxyalkylene) moiety comprises 8-100 oxyalkylene units selected from oxyalkylene units having from 2 to 5 carbon atoms at least a sufficient number of said oxyalkylene units being branched C 3 -C 5 oxyalkylene units to render said hydrocarbylpoly(oxyalkylene) polyamine soluble in said fuel composition, and said polyamine moiety comprises from 2 to about 12 amine nitrogen atoms and from 2 to 40 carbon atoms.
Claim 3
Dependent Claim
24 words
A fuel composition according to claim 1 in which said oxyalkylene units are selected from oxyalkylene units having from 3 to 4 carbon atoms.
Claim 4
Dependent Claim
22 words
A fuel composition according to claim 1 in which said hydrocarbylpoly(oxyalkylene) polyamine has a molecular weight of about 800 to about 5,000.
Claim 5
Dependent Claim
19 words
A fuel composition according to claim 1 in which said hydrocarbyl group contains from 2 to 20 carbon atoms.
Claim 6
Dependent Claim
19 words
A fuel composition according to claim 1 in which said hydrocarbyl group is selected from butyl and alkylphenyl groups.
Claim 7
Dependent Claim
29 words
A fuel composition according to claim 1 in which said polyamine moiety is derived from lower polyalkylene polyamines and contain at least one primary or secondary amine nitrogen atom.
Claim 8
Dependent Claim
17 words
A fuel composition according to claim 6 in which said lower polyalkylene polyamine is ethylenediamine or diethylenetriamine.
Claim 9
Dependent Claim
246 words
Compounds of the formula ##STR2## wherein two R 3 groups attached to the same nitrogen atom may be taken together to form a 5-6 membered ring heterocyclic radical; wherein R 3 may be the same or different and selected from hydrogen, hydrocarbyl from 1 to 10 carbon atoms, hydrocarbonyl of 2 to 10 carbon atoms and a poly(oxyalkylene) group of the formula R--OC g H 2g -- j in which g is an integer from 2 to 5, j is an integer such that the molecular weight of the poly(oxyalkylene) group is from about 500 to about 5000, and R is a hydrocarbyl group of from 1 to about 30 carbon atoms; R 1 is the same or different alkylene or hydroxy-substituted alkylene group of 2 to 6 carbon atoms, R 2 is carbonyl, alkylene carbonyl or alkylene of 2 to 4 carbon atoms with vicinal linkages; wherein at least one of the R 3 groups is the poly(oxyalkylene) group, and at least a sufficient number of the oxyalkylene units, --OC g H 2g --, are branched-chain C 3 -C 5 units to render the compound soluble in oils of lubricating viscosity or hydrocarbons boiling in the gasoline range; and wherein a is 0 or 1, b is an integer from 0 to 4, c is 0 or 1, d is 0 or 1, f is 0 or 1 and equal to 1 when c is 0, and f+b+2c+e is equal to or greater than 2.
Claim 10
Dependent Claim
246 words
Compounds of the formula ##STR2## wherein two R 3 groups attached to the same nitrogen atom may be taken together to form a 5-6 membered ring heterocyclic radical; wherein R 3 may be the same or different and selected from hydrogen, hydrocarbyl from 1 to 10 carbon atoms, hydrocarbonyl of 2 to 10 carbon atoms and a poly(oxyalkylene) group of the formula R--OC g H 2g -- j in which g is an integer from 2 to 5, j is an integer such that the molecular weight of the poly(oxyalkylene) group is from about 500 to about 5000, and R is a hydrocarbyl group of from 1 to about 30 carbon atoms; R 1 is the same or different alkylene or hydroxy-substituted alkylene group of 2 to 6 carbon atoms, R 2 is carbonyl, alkylene carbonyl or alkylene of 2 to 4 carbon atoms with vicinal linkages; wherein at least one of the R 3 groups is the poly(oxyalkylene) group, and at least a sufficient number of the oxyalkylene units, --OC g H 2g --, are branched-chain C 3 -C 5 units to render the compound soluble in oils of lubricating viscosity or hydrocarbons boiling in the gasoline range; and wherein a is 0 or 1, b is an integer from 0 to 4, c is 0 or 1, d is 0 or 1, f is 0 or 1 and equal to 1 when c is 0, and f+b+2c+e is equal to or greater than 2.
Claim 11
Dependent Claim
13 words
A compound of claim 8 in which R 1 is propylene or ethylene.
Claim 12
Dependent Claim
22 words
Compounds of claim 8 in which c and d are equal to 0 and R 1 is selected from propylene and ethylene.
Claim 13
Dependent Claim
26 words
A fuel composition comprising a major portion of hydrocarbon boiling at the gasoline range and from 30 to 2000 ppm of the compond of claim 8.
Claim 14
Dependent Claim
26 words
A fuel composition comprising a major portion of hydrocarbon boiling in the gasoline range and from 30 to 2,000 ppm of the compound of claim 10.
Claim 15
Dependent Claim
22 words
The fuel composition of claim 1 which also contains from 100 to 5000 ppm of a fuel-soluble poly(oxyalkylene) alcohol, glycol or polyol.
Claim 16
Dependent Claim
12 words
The fuel composition of claim 13 in which the poly(oxyalkylene) is poly(oxypropylene).
Claim 17
Dependent Claim
31 words
A concentrate comprising an inert, stable oleophilic organic solvent boiling in the range from 150° to 400° F. and from 10 to 50 weight percent of the compound of claim 1.
Claim 18
Dependent Claim
23 words
A concentrate according to claim 15 which also contains poly(oxyalkylene) alcohol, glycol or polyol in the amount from 5 to 80 weight percent.
References Cited (Backward Citations)
US3440029A
Cited
US3960515A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-27 | 1984-07-28 | 1985-01-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-27 | 1988-07-28 | 1989-01-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-27 | 1992-07-28 | 1993-01-27 | $7700.00 | Window Closed / Lapsed |