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US4246234A Expired / Lapsed US ⏱️ 0.0 years remaining

Method and apparatus for reducing nitric oxide

Assignee: New England Power Service Co
•
Filing: 1978-05-26
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Granted: 1981-01-20
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Expires: 1998-05-26
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Abstract

Abstract A method and apparatus for reducing nitric oxide in a gas with ammonia in the presence of a base metal catalyst pretreated with sulfur, selenium or a sulfur compound positioned in a reactor. The catalyst is deposited on a substrate or confined between gas-permeable walls and arranged to form open channels through which the nitric oxide-containing gas thereby effects low pressure drop through the reactor.

Inventors

  • 👤 James R. Kittrell
  • 👤 Donald L. Herman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 06:59
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8631; Y; Y02; Y02C; Y02C20/00; Y02C20/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 128 words
Apparatus for reducing nitric oxide by contact of a gaseous mixture containing nitric oxide and ammonia with a catalyst selected from the group consisting of copper, vanadium, iron, molybdenum and mixtures thereof, which catalyst has been pretreated with a compound selected from the group consisting of sulfur, dimethyl sulfide, hydrogen sulfide, carbon disulfide, selenium and mixtures thereof at a temperature between about 400° F.-900° F. to form a pretreated catalyst which comprises a reactor shell, a plurality of elongated solid supports within said shell coated with said pretreated catalyst, said supports being arranged within said shell and being separated from each other to provide open passages comprising a substantial portion of the cross-sectional area of said shell, and gas inlet and gas outlet means attached to said shell.
Claim 2
Dependent Claim 128 words
Apparatus for reducing nitric oxide by contact of a gaseous mixture containing nitric oxide and ammonia with a catalyst selected from the group consisting of copper, vanadium, iron, molybdenum and mixtures thereof, which catalyst has been pretreated with a compound selected from the group consisting of sulfur, dimethyl sulfide, hydrogen sulfide, carbon disulfide, selenium and mixtures thereof at a temperature between about 400° F.-900° F. to form a pretreated catalyst which comprises a reactor shell, a plurality of elongated solid supports within said shell coated with said pretreated catalyst, said supports being arranged within said shell and being separated from each other to provide open passages comprising a substantial portion of the cross-sectional area of said shell, and gas inlet and gas outlet means attached to said shell.
Claim 3
Dependent Claim 24 words
The apparatus of claim 1 wherein said supports comprise metal tubes arranged to extend parallel to the direction of gas flow within said shell.
Claim 4
Dependent Claim 11 words
The apparatus of claim 1 wherein said supports comprise metal rods.
Claim 5
Dependent Claim 26 words
The apparatus of claim 3 wherein said rods are arranged to extend in a direction substantially perpendicular to the direction of gas flow within said shell.
Claim 6
Dependent Claim 25 words
The apparatus of claim 1 wherein said pretreated catalyst is in particulate form and is confined into a shaped structure by a porous mesh screen.
Claim 7
Dependent Claim 15 words
The apparatus of claim 5 wherein said pretreated catalyst is confined into a rod-like shape.
Claim 8
Dependent Claim 15 words
The apparatus of claim 5 wherein said pretreated catalyst is confined into a tube-like shape.
Claim 9
Dependent Claim 32 words
The apparatus of claim 1 wherein a plurality of said supports are secured to common second support means to form a module and wherein said shell contains a plurality of said modules.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-20 1984-07-21 1985-01-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-20 1988-07-21 1989-01-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-20 1992-07-21 1993-01-20 $7700.00 Window Closed / Lapsed

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