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Hydrocarbon-soluble epoxidized fatty acid esters as lubricity modifiers for lubricating oils

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-03-07
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Granted: 1981-01-13
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Expires: 1998-03-07
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Abstract

Abstract Hydrocarbon-soluble epoxidized fatty acid esters prepared by the epoxidation of unsaturated carboxylic acid esters are useful hydrocarbon additives. Their incorporation into a suitable hydrocarbon functional fluid such as a lubricating oil gives improved antiwear and antifriction properties.

Inventors

  • 👤 Keith Coupland
  • 👤 Clinton R. Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 13:03
CPC Classifications
C; C10; C10L; C10L10/00; C10L10/08; C10L1/00; C10L1/10; C10L1/14; C10L1/18; C10L1/19; C10M; C10M129/00; C10M129/02; C10M129/66; C10M2203/00; C10M2203/06; C10M2205/00; C10M2205/02; C10M2205/026; C10M2205/06; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/027; C10M2207/028; C10M2207/10; C10M2207/14; C10M2207/144; C10M2207/146; C10M2207/16; C10M2207/26; C10M2207/262; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/287; C10M2207/289; C10M2207/40; C10M2207/404; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/086; C10M2209/10; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/24; C10M2215/26; C10M2217/00; C10M2217/02; C10M2217/022; C10M2217/024; C10M2217/028; C10M2217/04; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/046; C10M2219/08; C10M2219/082; C10M2219/087; C10M2219/088; C10M2219/089; C10M2219/10; C10M2219/104; C10M2219/108; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/045; C10M2225/00; C10M2225/04; C10M2225/041; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/02; C10N2070/00; C10N2070/02

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 103 words
In a lubricating motor oil composition comprising a major amount of a mineral lubricating oil and minor amounts of ashless dispersant, metal-containing detergent, viscosity index improver and zinc dihydrocarbyl phosphorodithioate additives, the improvement which comprises including in said composition as a fuel economy additive, a minot but at least friction-reducing amount in the range of about 0.2 to about 3 wt. % of an oil-soluble friction reducing polyepoxidized fatty acid ester selected from the group consisting of: methyl ester of soya bean fatty acids, C 1 to C 12 monohydric alcohol ester of linseed oil fatty acids, soya bean oil and linseed oil.
Claim 2
Dependent Claim 103 words
In a lubricating motor oil composition comprising a major amount of a mineral lubricating oil and minor amounts of ashless dispersant, metal-containing detergent, viscosity index improver and zinc dihydrocarbyl phosphorodithioate additives, the improvement which comprises including in said composition as a fuel economy additive, a minot but at least friction-reducing amount in the range of about 0.2 to about 3 wt. % of an oil-soluble friction reducing polyepoxidized fatty acid ester selected from the group consisting of: methyl ester of soya bean fatty acids, C 1 to C 12 monohydric alcohol ester of linseed oil fatty acids, soya bean oil and linseed oil.
Claim 3
Dependent Claim 51 words
In a lubricating composition according to claim 1 wherein said oil has a viscosity (as measured by ASTM D-445) of from about 2 to 40 centistokes at 99° C. and said fatty acid ester is present in amount which provides between 0.01 to 1.00 percent of oxirane oxygen in said composition.
Claim 4
Dependent Claim 21 words
In a lubricating composition according to claim 1 wherein said ester is said methyl ester of soya bean oil fatty acids.
Claim 5
Dependent Claim 19 words
In a lubricating composition according to claim 1 wherein said ester is said ester of linseed oil fatty acids.
Claim 6
Dependent Claim 14 words
In a lubricating composition according to claim 2 wherein said R 2 is methyl.
Claim 7
Dependent Claim 75 words
An automotive SAE 10W/30 lubricating oil composition for gasoline engines comprising a major amount of mineral lubricating oil and containing an ashless dispersant, a metal-containing detergent, a viscosity index improver, and zinc dihydrocarbyl phosphorodithioate, which oil has been improved so as to give increased fuel economy when used in a gasoline engine, by the addition of about 0.5 weight percent of epoxidized methyl ester of linseed oil fatty acid having about 9 wt% oxirane oxygen.
Claim 8
Dependent Claim 75 words
An automotive SAE 10W/30 lubricating oil composition for gasoline engines comprising a major amount of mineral lubricating oil and containing an ashless dispersant, a metal-containing detergent, a viscosity index improver, and zinc dihydrocarbyl phosphorodithioate, which oil has been improved so as to give increased fuel economy when used in a gasoline engine, by the addition of about 0.5 weight percent of epoxidized methyl ester of linseed oil fatty acid having about 9 wt% oxirane oxygen.
Claim 9
Independent Claim 67 words
A method of improving the operation of an automotive gasoline engine having a lubricating system by using as the lubricant a motor oil comprising a major amount of mineral lubricating oil, an ashless dispersant, a metal-containing detergent, a viscosity index improver and zinc dihydrocarbyl phosphorodithioate, and containing as a fuel economy additive epoxidized methyl ester of linseed oil fatty acid having about 9 wt% of ozirane oxygen.
Claim 10
Independent Claim 67 words
A method of improving the operation of an automotive gasoline engine having a lubricating system by using as the lubricant a motor oil comprising a major amount of mineral lubricating oil, an ashless dispersant, a metal-containing detergent, a viscosity index improver and zinc dihydrocarbyl phosphorodithioate, and containing as a fuel economy additive epoxidized methyl ester of linseed oil fatty acid having about 9 wt% of ozirane oxygen.
Claim 11
Dependent Claim 15 words
In a lubricating composition according to claim 1, wherein said ester is soya bean oil.
Claim 12
Dependent Claim 14 words
In a lubricating composition according to claim 1, wherein said ester is linseed oil.

References Cited (Backward Citations)

US2992237A Cited
US2900342A Cited
US2897070A Cited
US3294499A Cited
US3287273A Cited
DE1954452A1 Cited
GB1284512A Cited
US4105571A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-13 1984-07-14 1985-01-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-13 1988-07-14 1989-01-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-13 1992-07-14 1993-01-13 $7700.00 Window Closed / Lapsed

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