Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
199 words
A continuous process for the catalytic cracking of a hydrocarbon feedstream and the simultaneous generation of a low BTU gas or hydrogen-rich gas from coke which process involves: (1) contacting a hydrocarbon feedstream with an acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support selected from the group consisting of α-alumina η-alumina, γ-alumina, zirconia, boria, thoria, magnesia, zirconium-titanate, titania, chromia, kieselguhr and mixtures thereof, said catalyst being steamed prior to use, at a temperature, pressure and for a time sufficient to effect the desired catalytic change on the hydrocarbon feedstream and yield a coked catalyst; (2) regenerating the coked catalyst at regenerating conditions by contacting same with steam, oxygen-containing gas or mixture thereof to produce a regenerated catalyst and an H 2 rich gas, a low BTU gas rich in CO and a combination thereof; and (3) recirculating the regenerated catalyst of step (2) to the hydrocarbon conversion zone of step (1).
Claim 2
Dependent Claim
199 words
A continuous process for the catalytic cracking of a hydrocarbon feedstream and the simultaneous generation of a low BTU gas or hydrogen-rich gas from coke which process involves: (1) contacting a hydrocarbon feedstream with an acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support selected from the group consisting of α-alumina η-alumina, γ-alumina, zirconia, boria, thoria, magnesia, zirconium-titanate, titania, chromia, kieselguhr and mixtures thereof, said catalyst being steamed prior to use, at a temperature, pressure and for a time sufficient to effect the desired catalytic change on the hydrocarbon feedstream and yield a coked catalyst; (2) regenerating the coked catalyst at regenerating conditions by contacting same with steam, oxygen-containing gas or mixture thereof to produce a regenerated catalyst and an H 2 rich gas, a low BTU gas rich in CO and a combination thereof; and (3) recirculating the regenerated catalyst of step (2) to the hydrocarbon conversion zone of step (1).
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the catalytic component is selected from the group consisting of tungsten oxide, niobium oxide and mixtures thereof.
Claim 4
Dependent Claim
14 words
The process of claim 2 wherein the catalytic component metal oxide is tungsten oxide.
Claim 5
Dependent Claim
43 words
The process of claim 1 wherein the catalyst further comprises a promoter selected from the group consisting of barium oxide, calcium oxide, stontium oxide and cesium oxide present in an amount ranging from 0.01 to 4.0 wt. % based on total catalyst weight.
Claim 6
Dependent Claim
19 words
The process of claim 3 wherein the refractory oxide support is selected from the group consisting of the aluminas.
Claim 7
Dependent Claim
15 words
The process of claim 1 wherein the hydrocarbon feedstream is a 1050° F.+ hydrocarbon feedstream.
Claim 8
Dependent Claim
53 words
The process of claim 1 wherein the contacting of the hydrocarbon feedstream with the catalyst in step (1) is conducted at a temperature of from 300° to 900° C., a pressure of from 0 to 10,000 PSIG, contact time ranging from 1 to 2000 seconds at from 0.1 to 50 weight feed/hour/weight catalyst.
Claim 9
Dependent Claim
26 words
The process of claim 1 wherein step (1) further comprises the use of water at a water to hydrocarbon mole ratio ranging from 0.5:1 to 20:1.
Claim 10
Dependent Claim
24 words
The process of claim 7 wherein the regeneration conditions of step (2) comprise a temperature of from about 1400°-2800° F. and an oxidative atmosphere.
Claim 11
Dependent Claim
24 words
The process of claim 7 wherein the regeneration conditions of step (2) comprise a temperature of from about 1400°-2800° F. and a steam atmosphere.
Claim 12
Dependent Claim
24 words
The process of claim 1 wherein the catalyst comprises from 0.1 to 25 wt. % of the catalytic component based on total catalyst weight.
Claim 13
Dependent Claim
17 words
The process of claim 9, 10 or 11 wherein the catalyst is niobium oxide supported on alumina.
Claim 14
Dependent Claim
17 words
The process of claim 9, 10 or 11 wherein the catalyst is tungsten oxide supported on alumina.