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US4244811A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalytic cracking process with simultaneous production of a low BTU fuel gas and catalyst regeneration

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1978-07-25
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Granted: 1981-01-13
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Expires: 1998-07-25
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Abstract

Abstract A process is described for the catalytic cracking of a hydrocarbon feedstream involving the use of an acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on supports, wherein (1) the feedstream is catalytically cracked by being contacted with said catalyst at a temperature and for a time (optionally, in combination with H2O), sufficient to crack the hydrocarbon yielding a cracked product and a deactivated catalyst and (2) subjecting the deactivated catalyst to gasification conditions consisting of (A) partial oxidative combustion to produce a low BTU gas rich in CO or, (B) the addition of steam to produce a gas rich in H2, or both, with the recirculation of the decoked catalyst back to the first step.

Inventors

  • 👤 Dane C. Grenoble
  • 👤 Walter Weissman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 15:12
CPC Classifications
C; C01; C01B; C01B3/00; C01B3/02; C01B3/32; C01B3/34; C01B3/38; C01B3/386; C01B3/36; C01B3/363; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C01B2203/00; C01B2203/02; C01B2203/0205; C01B2203/0227; C01B2203/0233; C01B2203/025; C01B2203/0261; C01B2203/0283; C01B2203/08; C01B2203/0805; C01B2203/0811; C01B2203/10; C01B2203/1041; C01B2203/1082; C01B2203/1094; C01B2203/12; C01B2203/1205; C01B2203/1211; C01B2203/1235; C01B2203/1247; C01B2203/1258; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/584

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 199 words
A continuous process for the catalytic cracking of a hydrocarbon feedstream and the simultaneous generation of a low BTU gas or hydrogen-rich gas from coke which process involves: (1) contacting a hydrocarbon feedstream with an acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support selected from the group consisting of α-alumina η-alumina, γ-alumina, zirconia, boria, thoria, magnesia, zirconium-titanate, titania, chromia, kieselguhr and mixtures thereof, said catalyst being steamed prior to use, at a temperature, pressure and for a time sufficient to effect the desired catalytic change on the hydrocarbon feedstream and yield a coked catalyst; (2) regenerating the coked catalyst at regenerating conditions by contacting same with steam, oxygen-containing gas or mixture thereof to produce a regenerated catalyst and an H 2 rich gas, a low BTU gas rich in CO and a combination thereof; and (3) recirculating the regenerated catalyst of step (2) to the hydrocarbon conversion zone of step (1).
Claim 2
Dependent Claim 199 words
A continuous process for the catalytic cracking of a hydrocarbon feedstream and the simultaneous generation of a low BTU gas or hydrogen-rich gas from coke which process involves: (1) contacting a hydrocarbon feedstream with an acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support selected from the group consisting of α-alumina η-alumina, γ-alumina, zirconia, boria, thoria, magnesia, zirconium-titanate, titania, chromia, kieselguhr and mixtures thereof, said catalyst being steamed prior to use, at a temperature, pressure and for a time sufficient to effect the desired catalytic change on the hydrocarbon feedstream and yield a coked catalyst; (2) regenerating the coked catalyst at regenerating conditions by contacting same with steam, oxygen-containing gas or mixture thereof to produce a regenerated catalyst and an H 2 rich gas, a low BTU gas rich in CO and a combination thereof; and (3) recirculating the regenerated catalyst of step (2) to the hydrocarbon conversion zone of step (1).
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein the catalytic component is selected from the group consisting of tungsten oxide, niobium oxide and mixtures thereof.
Claim 4
Dependent Claim 14 words
The process of claim 2 wherein the catalytic component metal oxide is tungsten oxide.
Claim 5
Dependent Claim 43 words
The process of claim 1 wherein the catalyst further comprises a promoter selected from the group consisting of barium oxide, calcium oxide, stontium oxide and cesium oxide present in an amount ranging from 0.01 to 4.0 wt. % based on total catalyst weight.
Claim 6
Dependent Claim 19 words
The process of claim 3 wherein the refractory oxide support is selected from the group consisting of the aluminas.
Claim 7
Dependent Claim 15 words
The process of claim 1 wherein the hydrocarbon feedstream is a 1050° F.+ hydrocarbon feedstream.
Claim 8
Dependent Claim 53 words
The process of claim 1 wherein the contacting of the hydrocarbon feedstream with the catalyst in step (1) is conducted at a temperature of from 300° to 900° C., a pressure of from 0 to 10,000 PSIG, contact time ranging from 1 to 2000 seconds at from 0.1 to 50 weight feed/hour/weight catalyst.
Claim 9
Dependent Claim 26 words
The process of claim 1 wherein step (1) further comprises the use of water at a water to hydrocarbon mole ratio ranging from 0.5:1 to 20:1.
Claim 10
Dependent Claim 24 words
The process of claim 7 wherein the regeneration conditions of step (2) comprise a temperature of from about 1400°-2800° F. and an oxidative atmosphere.
Claim 11
Dependent Claim 24 words
The process of claim 7 wherein the regeneration conditions of step (2) comprise a temperature of from about 1400°-2800° F. and a steam atmosphere.
Claim 12
Dependent Claim 24 words
The process of claim 1 wherein the catalyst comprises from 0.1 to 25 wt. % of the catalytic component based on total catalyst weight.
Claim 13
Dependent Claim 17 words
The process of claim 9, 10 or 11 wherein the catalyst is niobium oxide supported on alumina.
Claim 14
Dependent Claim 17 words
The process of claim 9, 10 or 11 wherein the catalyst is tungsten oxide supported on alumina.

References Cited (Backward Citations)

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US2396641A Cited
US2513022A Cited
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US2572734A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-13 1984-07-14 1985-01-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-13 1988-07-14 1989-01-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-13 1992-07-14 1993-01-13 $7700.00 Window Closed / Lapsed

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