Light sensitive compositions of polymethyl isopropenyl ketone

Claim 2

A light sensitive composition consisting essentially of (1) polymethyl isopropenyl ketone of a molecular weight of about 10,000-about 1,000,000 and (2) from 0.1 to 50 parts by weight per 100 parts by weight of the polymethyl isopropenyl ketone of a compound having the general formula: ##STR10## wherein X 1 , X 2 and X 3 independently represent hydrogen atom, an alkyl group, hydroxyl group, an alkoxyl group or a halogen atom, Y represents hydrogen atom or a group having the formula --COOR, R being hydrogen atom or an alkyl group; Q represents hydrogen atom, an alkyl group or a lower hydrocarbon chain which may be substituted with hydroxyl group and n represents an integer of at least 1.

Claim 3

A light sensitive composition according to claim (1) wherein X 1 in general formula (I) represents hydrogen atom or an alkyl group, X 2 , X 3 , Y and Q each represent hydrogen atom and n represents 1.

Claim 4

A light sensitive composition according to claim (2) wherein X 1 in general formula (I) represents an alkyl group of 1-8 carbon atoms.

Claim 5

A light sensitive composition according to claim (1) wherein X 1 in general formula (I) represents hydroxyl group, X 2 and X 3 independently represent hydrogen atom or hydroxyl group, Q represents hydrogen atom or an alkyl group, Y represents hydrogen atom and n represents 1.

Claim 6

A light sensitive composition according to claim (4) wherein Q in general formula (I) represents an alkyl group of 1-5 carbon atoms.

Claim 7

A light sensitive composition according to claim (1) wherein X 1 in general formula (I) represents an alkoxyl group, X 2 represents hydrogen atom or an alkoxyl group, X 3 , Y and Q represent hydrogen atom, and n represents 1.

Claim 8

A light sensitive composition according to claim 6 wherein X 1 in general formula (I) represents an alkoxyl group of 1-5 carbon atoms and X 2 represents hydrogen atom or an alkoxyl group of 1-5 carbon atoms.

Claim 9

A light sensitive composition according to claim (1) wherein X 1 in general formula (I) represents a halogen atom, X 2 represents hydrogen atom or a halogen atom, X 3 , Y and Q each represent hydrogen atom and n represents 1.

Claim 10

A light sensitive composition according to claim (8) wherein X 1 in general formula (I) represents chlorine atom or bromine atom.

Claim 11

A light sensitive composition according to claim (9) wherein X 2 in general formula (I) represents chlorine atom or bromine atom.

Claim 12

A light sensitive composition according to claim (1) wherein X 1 , X 2 and X 3 in general formula (I) each represent hydrogen atom, Y represents --COOR, Q and R independently represent hydrogen atom or an alkyl group and n represents 1.

Claim 13

A light sensitive composition according to claim (11) wherein X 1 , X 2 and X 3 each represent hydrogen atom, Y represents --COOR group and R and Q independently represent an alkyl group of 1-8 carbon atoms.

Claim 14

A light sensitive composition according to claim (1) wherin X 1 in general formula (I) represents an alkyl group, and X 2 , X 3 and Y represents hydrogen atom.

Claim 15

A light sensitive composition according to claim (13) wherein X 1 in general formula (I) represents an alkyl group of 1-8 carbon atoms.

Claim 16

A light sensitive composition according to claim (14) wherein Q in general formula (I) represents an alkyl group of 1-12 carbon atoms.

Claim 17

A light sensitive composition according to claim (14) wherein Q in general formula (I) represents a hydrocarbon chain of 2-5 carbon atoms which may be substituted with hydroxyl group and n represents an integer of 2-4.

Claim 18

A light sensitive composition according to claim (1) wherein X 1 and X 2 in general formula (I) independently represent an alkoxyl group, and X 3 and Y represent hydrogen atom.

Claim 19

A light sensitive composition according to claim (17) wherein X 1 and X 2 in general formula (I) independently represent an alkoxyl group of 1-5 carbon atoms.

Claim 20

A light sensitive composition according to claim (18) wherein Q in general formula (I) represents an alkyl group of 1-12 carbon atoms.

Claim 21

A light sensitive composition according to claim (18) wherein Q in general formula (I) represents a hydrocarbon chain of 2-5 carbon atoms which may be substituted with hydroxyl group, and n represents an integer of 2-4.

Claim 22

A composition according to claim (1) wherein the compound of general formula (I) is selected from the group consisting of benzoic acid, o-methylbenzoic acid, m-methylbenzoic acid, p-methylbenzoic acid, p-isopropylbenzoic acid, p-n-butylbenzoic acid, p-tert.-butylbenzoic acid, p-n-amylbenzoic acid, p-n-octylbenzoic acid, p-hydroxybenzoic acid, methyl p-hydroxybenzoate, dodecyl p-hydroxybenzoate, 2,4-dihydroxybenzoic acid, 3,4-dihydroxybenzoic acid, 3,4-dihydroxybenzoic acid, ethyl gallate, propyl gallate, isoamyl gallate, o-methoxybenzoic acid, p-methoxybenzoic acid, 3,4-dimethoxybenzoic acid, p-ethoxybenzoic acid, p-n-amyloxybenzoic acid, p-chlorobenzoic acid, 2,4-dichlorobenzoic acid, 3,4-dichlorobenzoic acid, p-bromobenzoic acid, terephthalic acid, dimethyl terephthalate, dodecyl p-tert.-butylbenzoate, ethylene glycol diester of p-tert.-butylbenzoic acid, propylene glycol diester of the same acid, 1,4-butanediol diester of the same acid, glycerol diester and triester of the same acid, pentaerythritol diester, triester and tetraester of the same acid, dodecyl ester of 3,4-dimethoxybenzoic acid, ethylene glycol diester of the same acid, propylene glycol diester of the same acid, 1,4-butanediol diester of the same acid, glycerol diester and triester of the same acid, and pentaerythritol diester, triester and tetraester of the same acid.

Claim 23

A light sensitive composition according to any of claims 1 to 21 wherein the amount of the compound of general formula (I) is from 1 to 25 parts by weight.