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Blends of ethylene-vinyl acetate copolymer rubbers with elastomers

Assignee: Equistar Chemicals LP
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Filing: 1979-04-02
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Granted: 1981-01-06
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Expires: 1999-04-02
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Abstract

Abstract The Mooney viscosity and green strength of ethylene-vinyl acetate (EVA) copolymer gum stock is improved by the addition thereto of a suitable elastomer such as: high viscosity ethylene propylene rubber (EPR); nitrile rubber; polychloroprene; polyacrylate rubber; polyurethane; chlorinated polyethylene; polyester; ethylene-propylene diene monomer (EPDM) terpolymer; and other elastomers such as ethylene-methyl acrylate, ethylene butyl acrylate and acrylonitrile types.

Inventors

  • 👤 Joseph Fischer
  • 👤 John M. Hoyt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 04:09
CPC Classifications
C; C08; C08L; C08L31/00; C08L31/02; C08L31/04; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L21/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 87 words
A polymer blend demonstrating improved Mooney viscosity and green strength comprising from about 90% to about 60% by weight of an amorphous ethylene-vinyl acetate copolymer containing from about 40% to about 60% copolymerized vinyl acetate by weight, and from about 10% to about 40% by weight of a modifying elastomer having a Mooney viscosity of from about 65 to about 115 ML 1+4 at 100° C. wherein the modifying elastomer is selected from the group consisting of high viscosity ethylene propylene rubber and ethylene-propylene diene monomer terpolymer.
Claim 2
Dependent Claim 87 words
A polymer blend demonstrating improved Mooney viscosity and green strength comprising from about 90% to about 60% by weight of an amorphous ethylene-vinyl acetate copolymer containing from about 40% to about 60% copolymerized vinyl acetate by weight, and from about 10% to about 40% by weight of a modifying elastomer having a Mooney viscosity of from about 65 to about 115 ML 1+4 at 100° C. wherein the modifying elastomer is selected from the group consisting of high viscosity ethylene propylene rubber and ethylene-propylene diene monomer terpolymer.
Claim 3
Dependent Claim 39 words
The polymer blend of claim 1 demonstrating in increase in Mooney viscosity of from about 10% up to about 100% as compared to the Mooney viscosity of the ethylene-vinyl acetate copolymer prior to the addition of the modifying elastomer.
Claim 4
Dependent Claim 23 words
The polymer blend of claim 1 wherein the ethylene-vinyl acetate copolymer contains from about 50% to about 70% copolymerized vinyl acetate by weight.
Claim 5
Dependent Claim 29 words
The polymer blend of claim 1 crosslinked by the addition of from 1.0 parts to about 10.0 parts per hundred parts of said blend of a peroxide crosslinking agent.
Claim 6
Dependent Claim 44 words
The polymer blend of claim 5 crosslinked by the addition of from 2.0 parts to about 5 parts of a peroxide crosslinking agent selected from the group consisting of t-butyl perbenzoate, dicumyl peroxide; 2,5-dimethyl-2,5-di(t-butyl peroxy)hexyne-3; 1,3,5-tris[alpha,alpha-dimethyl-alpha-(t-butyl peroxy)]-methyl benzene; alpha,alpha'-bis(t-butyl peroxy)diisopropyl benzene; and, n-butyl-4,4-bis(t-butyl peroxy)valerate.
Claim 7
Dependent Claim 25 words
The polymer blend of claim 1 containing from about 5.0 parts to about 400.0 parts of filler per 100 parts of polymer blend by weight.
Claim 8
Dependent Claim 49 words
The polymer blend of claim 6 containing from about 100.0 parts to about 150.0 parts per 100 parts of polymer blend of a filler selected from the group consisting of talc, surface treated (silane) calcined kaolin clay, antimony oxide, alumina trihydrate, hydrated silica, carbon black and sintered colloidal silica.
Claim 9
Dependent Claim 20 words
The polymer blend of claim 1 containing from about 0.1 parts to about 4.0 parts by weight of an antioxidant.
Claim 10
Dependent Claim 21 words
The polymer blend of claim 8 containing about 1.0 parts per hundred parts of said blend of polymerized trimethyl dihydroquinoline antioxidant.

References Cited (Backward Citations)

US3833689A Cited
US3849333A Cited
US3821333A Cited
US3873494A Cited
US4032600A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-06 1984-07-07 1985-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-06 1988-07-07 1989-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-06 1992-07-07 1993-01-06 $7700.00 Window Closed / Lapsed

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