Patent FR2417293A1 successfully refreshed from Google Patents.
US4243422A
Expired / Lapsed
US
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Granular quartz glass product
Assignee: Dynamit Nobel AG
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Filing: 1977-12-14
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Granted: 1981-01-06
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Expires: 1997-12-14
Abstract
Abstract Method of preparing granular quartz glass which comprises heating a porous granulated silica gel having an alkoxy group content equal to or less than 1 weight percent and a total impurity content of less than 1 part per million, the porous granulated silica gel obtained by hydrolysis of an orthosilicic acid ester of an aliphatic alcohol at a temperature up to 1400° C.
Inventors
- 👤 Arnold Lenz
- 👤 Gerhard Kreuzburg
- 👤 Rainer Haase
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 04:30
CPC Classifications
C; C03; C03B; C03B19/00; C03B19/10; C03B19/1005; C03B19/106; C03B19/1065; C03B19/06; C03B19/066; C03B20/00; C03C; C03C3/00; C03C3/04; C03C3/06; C03C2201/00; C03C2201/02; C03C2203/00; C03C2203/20; C03C2203/26; Y; Y10; Y10S; Y10S65/00; Y10S65/06; Y10S65/08; Y10S65/901
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
202 words
A quartz glass consisting essentially of silica, said quartz glass containing alkoxy groups, said alkoxy groups present in an amount of less than 1 weight percent, said quartz glass having a total impurity content of less than 1 part per million, said quartz glass having a surface area, measured in accordance with BET, of approximately 400 to 800 square meters per gram prepared by a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 -C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; and D. Drying said gel by heating it at increasing temperatures up to 300° C. until the silica gel achieves a free flowing state.
Claim 2
Dependent Claim
202 words
A quartz glass consisting essentially of silica, said quartz glass containing alkoxy groups, said alkoxy groups present in an amount of less than 1 weight percent, said quartz glass having a total impurity content of less than 1 part per million, said quartz glass having a surface area, measured in accordance with BET, of approximately 400 to 800 square meters per gram prepared by a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 -C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; and D. Drying said gel by heating it at increasing temperatures up to 300° C. until the silica gel achieves a free flowing state.
Claim 3
Dependent Claim
195 words
A quartz glass prepared according to a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silicon sol by subjecting it to an elevated temperature up to 100° C.; D. Drying said gel by heating at increasing temperatures up to 300° C.; E. Comminuting the so-dried gel; and F. Heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C., said quartz glass characterized by the presence of hydroxy groups, said quartz glass containing hydroxy groups in an amount of less than 100 ppm, said quartz glass having a total impurity content of less than 1 ppm.
Claim 4
Dependent Claim
195 words
A quartz glass prepared according to a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silicon sol by subjecting it to an elevated temperature up to 100° C.; D. Drying said gel by heating at increasing temperatures up to 300° C.; E. Comminuting the so-dried gel; and F. Heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C., said quartz glass characterized by the presence of hydroxy groups, said quartz glass containing hydroxy groups in an amount of less than 100 ppm, said quartz glass having a total impurity content of less than 1 ppm.
Claim 5
Dependent Claim
13 words
Formed articles prepared by melting granular quartz glass prepared according to claim 2.
Claim 6
Dependent Claim
13 words
Formed articles prepared by sintering granular quartz glass prepared according to claim 2.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-06 | 1984-07-07 | 1985-01-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-06 | 1988-07-07 | 1989-01-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-06 | 1992-07-07 | 1993-01-06 | $7700.00 | Window Closed / Lapsed |