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US4243422A Expired / Lapsed US ⏱️ 0.0 years remaining

Granular quartz glass product

Assignee: Dynamit Nobel AG
•
Filing: 1977-12-14
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Granted: 1981-01-06
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Expires: 1997-12-14
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Abstract

Abstract Method of preparing granular quartz glass which comprises heating a porous granulated silica gel having an alkoxy group content equal to or less than 1 weight percent and a total impurity content of less than 1 part per million, the porous granulated silica gel obtained by hydrolysis of an orthosilicic acid ester of an aliphatic alcohol at a temperature up to 1400° C.

Inventors

  • 👤 Arnold Lenz
  • 👤 Gerhard Kreuzburg
  • 👤 Rainer Haase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 04:30
CPC Classifications
C; C03; C03B; C03B19/00; C03B19/10; C03B19/1005; C03B19/106; C03B19/1065; C03B19/06; C03B19/066; C03B20/00; C03C; C03C3/00; C03C3/04; C03C3/06; C03C2201/00; C03C2201/02; C03C2203/00; C03C2203/20; C03C2203/26; Y; Y10; Y10S; Y10S65/00; Y10S65/06; Y10S65/08; Y10S65/901

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 202 words
A quartz glass consisting essentially of silica, said quartz glass containing alkoxy groups, said alkoxy groups present in an amount of less than 1 weight percent, said quartz glass having a total impurity content of less than 1 part per million, said quartz glass having a surface area, measured in accordance with BET, of approximately 400 to 800 square meters per gram prepared by a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 -C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; and D. Drying said gel by heating it at increasing temperatures up to 300° C. until the silica gel achieves a free flowing state.
Claim 2
Dependent Claim 202 words
A quartz glass consisting essentially of silica, said quartz glass containing alkoxy groups, said alkoxy groups present in an amount of less than 1 weight percent, said quartz glass having a total impurity content of less than 1 part per million, said quartz glass having a surface area, measured in accordance with BET, of approximately 400 to 800 square meters per gram prepared by a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 -C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; and D. Drying said gel by heating it at increasing temperatures up to 300° C. until the silica gel achieves a free flowing state.
Claim 3
Dependent Claim 195 words
A quartz glass prepared according to a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silicon sol by subjecting it to an elevated temperature up to 100° C.; D. Drying said gel by heating at increasing temperatures up to 300° C.; E. Comminuting the so-dried gel; and F. Heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C., said quartz glass characterized by the presence of hydroxy groups, said quartz glass containing hydroxy groups in an amount of less than 100 ppm, said quartz glass having a total impurity content of less than 1 ppm.
Claim 4
Dependent Claim 195 words
A quartz glass prepared according to a process consisting essentially of: A. Forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. Hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica gel; C. Gelling said silicon sol by subjecting it to an elevated temperature up to 100° C.; D. Drying said gel by heating at increasing temperatures up to 300° C.; E. Comminuting the so-dried gel; and F. Heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C., said quartz glass characterized by the presence of hydroxy groups, said quartz glass containing hydroxy groups in an amount of less than 100 ppm, said quartz glass having a total impurity content of less than 1 ppm.
Claim 5
Dependent Claim 13 words
Formed articles prepared by melting granular quartz glass prepared according to claim 2.
Claim 6
Dependent Claim 13 words
Formed articles prepared by sintering granular quartz glass prepared according to claim 2.

References Cited (Backward Citations)

US3314772A Cited
US3597252A Cited
FR1562495A Cited
US3827893A Cited
US3811918A Cited
US3782915A Cited
US3929439A Cited
US4098595A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-01-06 1984-07-07 1985-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-01-06 1988-07-07 1989-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-01-06 1992-07-07 1993-01-06 $7700.00 Window Closed / Lapsed

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