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US4098595A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of granular quartz glass

Assignee: Dynamit Nobel AG
•
Filing: 1976-12-20
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Granted: 1978-07-04
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Expires: 1996-12-20
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Abstract

Abstract Method of preparing granular quartz glass which comprises heating a porous granulated silica gel having an alkoxy group content equal to or less than 1 weight percent and a total impurity content of less than 1 part per million, the porous granulated silica gel obtained by hydrolysis of an orthosilicic acid ester of an aliphatic alcohol at a temperature up to 1400° C.

Inventors

  • 👤 Arnold Lenz
  • 👤 Gerhard Kreuzburg
  • 👤 Rainer Haase

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:32
CPC Classifications
C; C03; C03B; C03B19/00; C03B19/10; C03B19/1005; C03B19/106; C03B19/1065; C03B19/06; C03B19/066; C03B20/00; C03C; C03C3/00; C03C3/04; C03C3/06; C03C2201/00; C03C2201/02; C03C2203/00; C03C2203/20; C03C2203/26; Y; Y10; Y10S; Y10S65/00; Y10S65/06; Y10S65/08; Y10S65/901

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 158 words
A process for preparing quartz glass which consists essentially of: A. forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica sol; C. gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; D. drying said gel by heating at increasing temperatures up to 300° C.; E. comminuting the so dried gel; and F. heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C.
Claim 2
Dependent Claim 158 words
A process for preparing quartz glass which consists essentially of: A. forming a silicic acid ester of an alcohol selected from the group consisting of a C 1 -C 5 aliphatic alcohol, a C 2 -C 8 alkanol wherein the carbon chain of the alkyl group can be interrupted by one or more oxygen atoms and a C 2 to C 5 glycol by reacting silicon or ferrosilicon with said alcohol; B. hydrolyzing said silicic acid ester by contacting the same with 105-500 percent of the stoichiometrically necessary amount of water, said water having a pH of 2-5 to thereby form a silica sol; C. gelling said silica sol by subjecting it to an elevated temperature up to 100° C.; D. drying said gel by heating at increasing temperatures up to 300° C.; E. comminuting the so dried gel; and F. heating the so-comminuted gel at increasing temperatures which can be up to a temperature of 1400° C.
Claim 3
Dependent Claim 20 words
A method according to claim 1 wherein said silica gel has a total impurity content of less than 1 ppm.
Claim 4
Dependent Claim 19 words
A method according to claim 1 wherein said silica gel has a given size of up to 10,000 μm.
Claim 5
Dependent Claim 28 words
A method according to claim 1 wherein said porous silica gel has a specific surface area, determined by the BET method, of 400 to 800 m 2 /g.
Claim 6
Dependent Claim 28 words
A method according to claim 4 wherein said porous silica gel has a specific surface area, determined by the BET method, of 500 to 700 m 2 /g.
Claim 7
Dependent Claim 21 words
A method according to claim 1 wherein the silica gel is comminuted to particles of grain size 70 to 800 μm.
Claim 8
Dependent Claim 19 words
A method according to claim 1 wherein the gelation and drying are carried out under a protective gas shield.
Claim 9
Dependent Claim 19 words
A method according to claim 1 wherein the hydrolysis is performed with constant stirring until the sol is prepared.
Claim 10
Dependent Claim 35 words
A method according to claim 1 wherein said silicic acid gel is treated, after drying, with pure water at atmospheric pressure, comminuted in the presence of said pure water and thereafter freed of adherent water.
Claim 11
Dependent Claim 27 words
A method according to claim 1 wherein following said drying said gel is heated at stepwise or continuous increasing temperatures which can be up to 1400° C.
Claim 12
Dependent Claim 24 words
A method according to claim 1 wherein said gel is heated at stepwise or continuous increasing temperatures which can be up to 1200° C.
Claim 13
Dependent Claim 32 words
A method according to claim 1 wherein after said drying and prior to heating stepwise or continuous to 1400° C. said gel is presintered at a temperature of 500° to 800° C.
Claim 14
Dependent Claim 20 words
A method according to claim 1 wherein said orthosilicic acid ester is a high purity, chlorine ion-free orthosilicic acid ester.
Claim 15
Dependent Claim 15 words
A method according to claim 1 wherein said ester is an ester of methyl alcohol.
Claim 16
Dependent Claim 20 words
A process according to claim 1 wherein step F is carried out at a temperature of at least 750° C.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-03 1982-01-02 1982-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-03 1986-01-02 1986-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-03 1990-01-02 1990-07-04 $7700.00 Window Closed / Lapsed

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