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US4242258A Expired / Lapsed US ⏱️ 0.0 years remaining

Water-soluble dyestuffs, processes for their manufacture, their use as fiber-reactive dyestuffs for dyeing and printing fiber materials and the fiber materials dyed with these dyestuffs

Assignee: Hoechst AG
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Filing: 1979-02-21
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Granted: 1980-12-30
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Expires: 1999-02-21
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Abstract

Abstract Water-soluble dyestuffs are described which in the acid form possess the formula ##STR1## wherein D is a benzene or naphthalene nucleus, R 1 is linked to D in ortho-position to the azo group and means hydrogen, halogen, lower alkoxy, lower alkyl, carboxy or sulfo, R 2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo and X is the vinyl group or a sulfato-, chloro- or thiosulfatoethyl group, A is a bridging member preferably selected from the diphenylene, diphenylsulfone and diphenylamine series, Z and Z 1 each represent a hydroxy or amino group with the proviso that each Z and each Z 1 have the same meaning. These novel dyestuffs are prepared by diazotization and coupling of the corresponding diazo and coupling components in usual manner known in the art. The novel dyestuffs possess a very valuable fiber-reactivity and are suitable for dyeing natural and regenerated cellulose or natural, regenerated or synthetic polyamide fiber materials. They can easily be applied and fixed by application methods usual and known in the art, and yield on these fiber materials dyeings and prints which possess good fastnesses, especially fastnesses to light, to washing, to perspiration and to cross-dyeing. Their fixation degree on the fiber material and correspondingly their tinctorial strength are outstanding.

Inventors

  • 👤 Walter Noll
  • 👤 Fritz Meininger
  • 👤 Ernst Hoyer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:26
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/44; C09B62/503; C09B62/507; C09B62/513

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 150 words
A water-soluble dyestuff which, in the form of the free acid, has the formula (1) ##STR657## in which D is a benzene nucleus or naphthalene nucleus, R 1 is in the ortho-position relative to the azo group and is hydrogen, halogen, lower alkyl, lower alkoxy, carboxy or sulfo, R 2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo, R 1 and R 2 being identical or different from one another, X is β-thiosulfatoethyl, β-chloroethyl, β-sulfatoethyl or vinyl, A is ##STR658## in which the benzene nuclei may be substituted and D 1 is a direct covalent bond or a bridge member and E is a member of the formula --O--, --S--, --NH--, or --SO 2 --, Z is the grouping --(OH) n-1 or --(NH 2 ) 2-n , and Z 1 is the grouping --(OH) 2-n or --(NH 2 ) n-1 in which n is the number 1 or 2.
Claim 2
Dependent Claim 150 words
A water-soluble dyestuff which, in the form of the free acid, has the formula (1) ##STR657## in which D is a benzene nucleus or naphthalene nucleus, R 1 is in the ortho-position relative to the azo group and is hydrogen, halogen, lower alkyl, lower alkoxy, carboxy or sulfo, R 2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo, R 1 and R 2 being identical or different from one another, X is β-thiosulfatoethyl, β-chloroethyl, β-sulfatoethyl or vinyl, A is ##STR658## in which the benzene nuclei may be substituted and D 1 is a direct covalent bond or a bridge member and E is a member of the formula --O--, --S--, --NH--, or --SO 2 --, Z is the grouping --(OH) n-1 or --(NH 2 ) 2-n , and Z 1 is the grouping --(OH) 2-n or --(NH 2 ) n-1 in which n is the number 1 or 2.
Claim 3
Dependent Claim 182 words
A water-soluble dyestuff which, in the form of the free acid, has the formula ##STR659## in which D is a benzene or naphthalene nucleus; R 1 is in the ortho-position relative to the azo group and is hydrogen, halogen, lower alkyl, lower alkoxy, carboxy or sulfo; R 2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo, R 1 and R 2 being identical or different from one another; X is β-thiosulfatoethyl, β-chloroethyl, β-sulfatoethyl or vinyl; A is ##STR660## in which the benzene nuclei may be substituted by one or more members of the group consisting of lower alkyl, lower alkoxy, sulfo, carboxy, nitro and chlorine; D 1 is a direct covalent bond or a bridge member of the formula --CH 2 --, --CH 2 CH 2 --, --CH═CH--, --NH--, --SO 2 --, --CONH--, --NHCO--, ##STR661## in which Y is Cl, F or Br; E is --O--, --S--, --NH-- or --SO 2 --; Z is --(OH) n-1 or --(NH 2 ) 2-n ; Z 1 is --(OH) 2-n or --(NH 2 ) n-1 ; and n is the number 1 or 2.
Claim 4
Dependent Claim 182 words
A water-soluble dyestuff which, in the form of the free acid, has the formula ##STR659## in which D is a benzene or naphthalene nucleus; R 1 is in the ortho-position relative to the azo group and is hydrogen, halogen, lower alkyl, lower alkoxy, carboxy or sulfo; R 2 is hydrogen, halogen, lower alkyl, lower alkoxy or sulfo, R 1 and R 2 being identical or different from one another; X is β-thiosulfatoethyl, β-chloroethyl, β-sulfatoethyl or vinyl; A is ##STR660## in which the benzene nuclei may be substituted by one or more members of the group consisting of lower alkyl, lower alkoxy, sulfo, carboxy, nitro and chlorine; D 1 is a direct covalent bond or a bridge member of the formula --CH 2 --, --CH 2 CH 2 --, --CH═CH--, --NH--, --SO 2 --, --CONH--, --NHCO--, ##STR661## in which Y is Cl, F or Br; E is --O--, --S--, --NH-- or --SO 2 --; Z is --(OH) n-1 or --(NH 2 ) 2-n ; Z 1 is --(OH) 2-n or --(NH 2 ) n-1 ; and n is the number 1 or 2.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-30 1984-06-30 1984-12-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-30 1988-06-30 1988-12-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-30 1992-06-30 1992-12-30 $7700.00 Window Closed / Lapsed

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